CHEN Zhirong, DENG Chao, WU Wanhui, FENG Aijun, OU Rongxian, HAO Xiaolong, SHUAI Heping, LIU Tao, WANG Qingwen
The work aims to investigate the synergistic flame-retardant mechanism of camellia oleifera shell (COS) combined with aluminum diethylphosphinate (ADP) and ammonium polyphosphate (APP) for the preparation of halogen-free flame-retardant wood-plastic composites (WPCs). Using polypropylene (PP) as the matrix, COS as the filler, and ADP and APP as synergistic flame retardants, flame-retardant COS/PP composites (PCDP) were fabricated by melt extrusion and injection molding. The flame retardancy, thermal degradation behavior, and mechanical properties of each formulation were evaluated by LOI, UL-94 vertical burning test, CONE, scanning electron microscopy with SEM-EDS, and TG-FTIR. The optimal formulation PCDP-5 achieved an LOI of 28.4% and a UL-94 V-0 rating. Compared with PCDP-1, pHRR, THR, and pSPR decreased by 34.4%, 24.5%, and 15%, respectively, while the tensile modulus, flexural modulus, and notched impact strength increased by 27.4%, 17.6%, and 9.2%, respectively. In conclusion, the lignin contained in COS provides aromatic char-forming sources. Together with ADP and APP, it establishes a multi-component flame-retardant system in which condensed-phase catalytic charring and gas-phase radical trapping act synergistically to deliver effective flame retardancy without appreciable loss of mechanical performance. These findings offer guidance for the application of flame-retardant WPCs in packaging and for the utilization of camellia oleifera shells.