黑加仑花青素基pH响应智能膜制备及在水产品保鲜中的应用研究进展

孙涛; 石文慧; 李实迪; 柴琰; 范荣亮; 程锦春; 齐燕姣; 陈丽华; 赵娅敏

doi:10.19554/j.cnki.1001-3563.2026.17.020

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包装工程（技术栏目） ›› 2026, Vol. 47 ›› Issue (17) : 186-199. DOI: 10.19554/j.cnki.1001-3563.2026.17.020

农产品保鲜与食品包装

黑加仑花青素基pH响应智能膜制备及在水产品保鲜中的应用研究进展

孙涛^1a,b,c,d, 石文慧^1a,b,c,d, 李实迪², 柴琰^1a,b,c,d, 范荣亮^1a,b,c,d, 程锦春^1a,b,c,d, 齐燕姣^1a,b,c,d, 陈丽华^1a,b,c,d, 赵娅敏^1a,b,c,d*

作者信息 +

Preparation of Ribes nigrum Anthocyanin-based pH-responsive Intelligent Films and Research Progress on Their Application in Aquatic Product Preservation

SUN Tao^1a,b,c,d, SHI Wenhui^1a,b,c,d, LI Shidi², CHAI Yan^1a,b,c,d, FAN Rongliang^1a,b,c,d, CHENG Jinchun^1a,b,c,d, QI Yanjiao^1a,b,c,d, CHEN Lihua^1a,b,c,d, ZHAO Yamin^1a,b,c,d*

Author information +

文章历史 +

摘要

目的阐述黑加仑花青素（Ribes nigrum anthocyanins,RNLA）基pH响应智能膜在水产品保鲜领域的应用研究进展,进一步明确天然色素基智能包装的性能优化方向,其不仅能降低水产品产后流通损耗,而且能提高生鲜食品包装安全性与功能性。方法从原料的结构特性与制膜技术、环境稳定性调控策略、保鲜-指示协同机理与应用成效双方系统综述,阐明黑加仑花青素的pH响应机制、产业适配优势,总结溶液浇铸、微胶囊包埋等主流制备技术的调控规律。进一步分析pH、温度、光照等贮藏环境对膜性能的影响机制,阐释抗氧化与抑菌协同的作用路径,剖析该领域现有瓶颈问题并展望未来发展。结果在水产品腐败核心pH处于6.5~8.5时,黑加仑花青素的色值与pH的线性相关系数达0.991,在60 ℃的制备条件下色素的留存率可达85%~90%,可以适配工业的化成膜工艺。通过溶液浇铸法制备魔芋葡甘露聚糖（Konjac glucomannan,KGM）/羧甲基纤维素（Carboxymethyl cellulose,CMC）复合膜,在0.15%花青素添加量下综合性能最优,微胶囊包埋与静电纺丝技术可分别将色素热稳定性提升30%、pH响应速度提升42%;经柠檬酸复配、紫外屏蔽等改性策略可显著改善膜在弱碱性、光照环境下的稳定性。结论黑加仑花青素凭借精准的pH响应区间、良好的热稳定性与生物活性,是水产品保鲜极具潜力的天然功能组分。

Abstract

The work aims to elaborate the research progress of Ribes nigrum anthocyanin (RNLA)-based pH-responsive intelligent films in the field of aquatic product preservation, so as to clarify the performance optimization direction of natural pigment-based intelligent packaging, which should not only reduce the post-production circulation loss of aquatic products, but also enhance the safety and functionality of fresh food packaging. Three dimensions including the structural properties of raw materials and film-forming technologies, environmental stability regulation strategies, and preservation-indication synergy mechanisms with application effects were systematically reviewed. The pH response mechanism and industrial adaptation advantages of RNLA were elucidated, and the regulation rules of mainstream preparation technologies such as solution casting and microencapsulation were summarized. Furthermore, the influence mechanisms of storage environments involving pH, temperature and light on film performance were analyzed, the action pathways of antioxidant and antibacterial synergy were interpreted, the existing bottlenecks in this field were dissected and future development prospects were proposed. Results demonstrated that the linear correlation coefficient between the color value of RNLA and pH reached 0.991 within the core pH range of 6.5-8.5 corresponding to aquatic product spoilage, and the pigment retention rate could reach 85%-90% under the preparation temperature of 60 ℃, which was compatible with industrial film-forming processes. When konjac glucomannan (KGM)/carboxymethyl cellulose (CMC) composite films were fabricated via solution casting, the optimal comprehensive performance was obtained at an anthocyanin dosage of 0.15%. Microencapsulation and electrospinning technologies could enhance the thermal stability of pigments by 30% and accelerate the pH response speed by 42%, respectively. In addition, modification strategies including citric acid compounding and UV shielding could significantly improve the stability of the films under weakly alkaline and light exposure conditions. In conclusion, with its precise pH response range, favorable thermal stability and excellent biological activity, RNLA is recognized as a highly promising natural functional component for aquatic product preservation.

导出引用

孙涛, 石文慧, 李实迪, 柴琰, 范荣亮, 程锦春, 齐燕姣, 陈丽华, 赵娅敏. 黑加仑花青素基pH响应智能膜制备及在水产品保鲜中的应用研究进展[J]. 包装工程. 2026, 47(17): 186-199 https://doi.org/10.19554/j.cnki.1001-3563.2026.17.020

SUN Tao, SHI Wenhui, LI Shidi, CHAI Yan, FAN Rongliang, CHENG Jinchun, QI Yanjiao, CHEN Lihua, ZHAO Yamin. Preparation of Ribes nigrum Anthocyanin-based pH-responsive Intelligent Films and Research Progress on Their Application in Aquatic Product Preservation[J]. Packaging Engineering. 2026, 47(17): 186-199 https://doi.org/10.19554/j.cnki.1001-3563.2026.17.020

中图分类号： TB34 TB487

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