相变蓄冷材料在冷链物流中的性能提升策略研究进展

王宇琪, 熊光权, 汪兰, 石柳, 陈胜, 吴文锦, 沈汪洋, 郭晓嘉

包装工程(技术栏目) ›› 2026, Vol. 47 ›› Issue (11) : 116-128.

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包装工程(技术栏目) ›› 2026, Vol. 47 ›› Issue (11) : 116-128. DOI: 10.19554/j.cnki.1001-3563.2026.11.012
先进材料

相变蓄冷材料在冷链物流中的性能提升策略研究进展

  • 王宇琪1,2,3,4, 熊光权1,2,3, 汪兰1,2,3, 石柳1,2,3, 陈胜1,2,3, 吴文锦1,2,3, 沈汪洋4, 郭晓嘉1,2,3*
作者信息 +

Research Progress on Performance Enhancement Strategies of Phase Change Cold Storage Materials in Cold Chain Logistics

  • WANG Yuqi1,2,3,4, XIONG Guangquan1,2,3, WANG Lan1,2,3, SHI Liu1,2,3, CHEN Sheng1,2,3, WU Wenjin1,2,3, SHEN Wangyang4, GUO Xiaojia1,2,3*
Author information +
文章历史 +

摘要

为降低冷链物流对主动制冷系统的依赖,减少温度波动导致的运输产品品质损失,系统梳理了相变蓄冷材料的关键性能缺陷及其性能提升策略,为开发高效、稳定、适用于不同温区的蓄冷材料提供理论依据。首先分类综述了有机、无机及复合相变材料的基本特性,围绕相变蓄冷材料在储冷、传热、防泄漏、过冷及相分离等方面的缺陷,着重分析了通过添加纳米粒子、共晶体系设计、凝胶网络构建、微胶囊化、多孔载体负载、成核剂添加和增稠剂复合等性能提升方法及其作用机理。最后得出单一相变材料难以同时满足高潜热、高导热、防泄漏、低过冷和长期循环稳定等要求,通过复合化设计可显著改善相变蓄冷材料综合性能的结论。

Abstract

To reduce the reliance of cold chain logistics on active refrigeration systems and mitigate the quality loss of transported products caused by temperature fluctuations, the work aims to systematically review the key performance defects of phase change cold storage materials and the corresponding performance enhancement strategies, providing a theoretical basis for the development of efficient, stable cold storage materials suitable for different temperature zones. The basic characteristics of organic, inorganic and composite phase change materials were firstly classified and reviewed. Focusing on the shortcomings of phase change cold storage materials in cold energy storage, heat transfer, leakage prevention, supercooling and phase separation, the performance enhancement methods and their mechanisms were emphatically analyzed, including the addition of nanoparticles, eutectic system design, gel network construction, microencapsulation, porous carrier loading, nucleating agent addition, and thickening agent compounding. It is concluded that a single phase change material can hardly meet the requirements of high latent heat, high thermal conductivity, leakage prevention, low supercooling and long-term cycling stability simultaneously, while composite design can significantly improve the overall performance of phase change cold storage materials.

关键词

相变蓄冷材料 / 冷链物流 / 相变潜热 / 热导率 / 过冷 / 循环稳定性

Key words

phase change cold storage material / cold chain logistics / latent heat of phase change / thermal conductivity / supercooling / cycling stability

引用本文

导出引用
王宇琪, 熊光权, 汪兰, 石柳, 陈胜, 吴文锦, 沈汪洋, 郭晓嘉. 相变蓄冷材料在冷链物流中的性能提升策略研究进展[J]. 包装工程. 2026, 47(11): 116-128 https://doi.org/10.19554/j.cnki.1001-3563.2026.11.012
WANG Yuqi, XIONG Guangquan, WANG Lan, SHI Liu, CHEN Sheng, WU Wenjin, SHEN Wangyang, GUO Xiaojia. Research Progress on Performance Enhancement Strategies of Phase Change Cold Storage Materials in Cold Chain Logistics[J]. Packaging Engineering. 2026, 47(11): 116-128 https://doi.org/10.19554/j.cnki.1001-3563.2026.11.012
中图分类号: TB34   

参考文献

[1] WU Q, ZHANG X L, WU H L.Research Progress on Cold Store Technology in the Context of Dual Carbon[J]. Journal of Energy Storage, 2024, 86:111291.
[2] GAO J W, CUI Z L, LI H J, et al.Optimization and Coordination of the Fresh Agricultural Product Supply Chain Considering the Freshness-Keeping Effort and Information Sharing[J]. Mathematics, 2023, 11(8):1922.
[3] ZHAO Y, ZHANG X L, XU X F, et al.Research Progress of Phase Change Cold Storage Materials Used in Cold Chain Transportation and Their Different Cold Storage Packaging Structures[J]. Journal of Molecular Liquids, 2020, 319:114360.
[4] TONG S H, NIE B J, LI Z X, et al.A Phase Change Material (PCM) Based Passively Cooled Container for Integrated Road-Rail Cold Chain Transportation—An Experimental Study[J]. Applied Thermal Engineering, 2021, 195:117204.
[5] YADAV M, PASARKAR N, NAIKWADI A, et al.A Review on Microencapsulation, Thermal Energy Storage Applications, Thermal Conductivity and Modification of Polymeric Phase Change Material for Thermal Energy Storage Applications[J]. Polymer Bulletin, 2023, 80(6):5897-5927.
[6] MENG B B, ZHANG X L, HUA W S, et al.Development and Application of Phase Change Material in Fresh E-Commerce Cold Chain Logistics:A Review[J]. Journal of Energy Storage, 2022, 55:105373.
[7] OUAOUJA Z, HAVET M, ROUAUD O, et al.Thermal Properties and Performance of Glycerol-Water-NaCl Phase Change Material for Cold Chain Applications[J]. Journal of Energy Storage, 2025, 126:117045.
[8] YANG T Y, KING W P, MILJKOVIC N.Phase Change Material-Based Thermal Energy Storage[J]. Cell Reports Physical Science, 2021, 2(8):100540.
[9] YADAV A, VERMA A, KUMAR A, et al.Recent Advances on Enhanced Thermal Conduction in Phase Change Materials Using Carbon Nanomaterials[J]. Journal of Energy Storage, 2021, 43:103173.
[10] FENG T P, JI J, ZHANG X L.Research Progress of Phase Change Cold Energy Storage Materials Used in Cold Chain Logistics of Aquatic Products[J]. Journal of Energy Storage, 2023, 60:106568.
[11] SINGH P, SHARMA R K, ANSU A K, et al.A Comprehensive Review on Development of Eutectic Organic Phase Change Materials and Their Composites for Low and Medium Range Thermal Energy Storage Applications[J]. Solar Energy Materials and Solar Cells, 2021, 223:110955.
[12] SONG Y L, ZHANG N, JING Y G, et al.Experimental and Numerical Investigation on Dodecane/Expanded Graphite Shape-Stabilized Phase Change Material for Cold Energy Storage[J]. Energy, 2019, 189:116175.
[13] ORÓ E, DE GRACIA A, CASTELL A, et al.Review on Phase Change Materials (PCMS) for Cold Thermal Energy Storage Applications[J]. Applied Energy, 2012, 99:513-533.
[14] XIE N, HUANG Z W, LUO Z G, et al.Inorganic Salt Hydrate for Thermal Energy Storage[J]. Applied Sciences, 2017, 7(12):1317.
[15] SHAIKH S, LAFDI K, HALLINAN K.Carbon Nanoadditives to Enhance Latent Energy Storage of Phase Change Materials[J]. Journal of Applied Physics, 2008, 103(9):094302.
[16] LIU Y S, YANG Y Z.Investigation of Specific Heat and Latent Heat Enhancement in Hydrate Salt Based TiO2 Nanofluid Phase Change Material[J]. Applied Thermal Engineering, 2017, 124:533-538.
[17] LI J F, LU W, ZENG Y B, et al.Simultaneous Enhancement of Latent Heat and Thermal Conductivity of Docosane-Based Phase Change Material in the Presence of Spongy Graphene[J]. Solar Energy Materials and Solar Cells, 2014, 128:48-51.
[18] SUN M Y, LIU T, SHA H N, et al.A Review on Thermal Energy Storage with Eutectic Phase Change Materials:Fundamentals and Applications[J]. Journal of Energy Storage, 2023, 68:107713.
[19] LI Y X, LI C C, HE Y L.Advanced Phase Change Gel Featuring Tunable Low-Temperature Transition for Cold Energy Storage[J]. Journal of Energy Storage, 2025, 130:117467.
[20] LIU Y S, YANG Y Z, LI S X.Graphene Oxide Modified Hydrate Salt Hydrogels:Form-Stable Phase Change Materials for Smart Thermal Management[J]. Journal of Materials Chemistry A, 2016, 4(46):18134-18143.
[21] NIE B J, PALACIOS A, ZOU B Y, et al.Review on Phase Change Materials for Cold Thermal Energy Storage Applications[J]. Renewable and Sustainable Energy Reviews, 2020, 134:110340.
[22] WU S F, YAN T, KUAI Z H, et al.Thermal Conductivity Enhancement on Phase Change Materials for Thermal Energy Storage:A Review[J]. Energy Storage Materials, 2020, 25:251-295.
[23] LI J X, MO S P, ZHOU Z C, et al.Nanoparticle-Enhanced Phase Change Materials for Thermal Energy Storage:A Critical Review[J]. Renewable and Sustainable Energy Reviews, 2025, 223:116040.
[24] JI W, CHENG X M, CHEN S H, et al.Self-Assembly Fabrication of GO/TiO2@paraffin Microcapsules for Enhancement of Thermal Energy Storage[J]. Powder Technology, 2021, 385:546-556.
[25] FAUZI M, KURNIAWAN B, FACHREDZY A, et al.Paraffin-Based Phase Change Materials (PCM) with Enhanced Thermal Conductivity through Particle Addition and Encapsulation Techniques for Thermal Energy Storage:A Critical Review of Materials Science[J]. Trends in Sciences, 2025, 22(9):10308.
[26] ZHOU S X, ZHANG X L, LIU S, et al.Performance Study on Expand Graphite/Organic Composite Phase Change Material for Cold Thermal Energy Storage[J]. Energy Procedia, 2019, 158:5305-5310.
[27] HAN X, KONG T T, ZHU P G, et al.Microfluidic Encapsulation of Phase-Change Materials for High Thermal Performance[J]. Langmuir, 2020, 36(28):8165-8173.
[28] KARAIPEKLI A, BIÇER A, SARı A, et al. Thermal Characteristics of Expanded Perlite/Paraffin Composite Phase Change Material with Enhanced Thermal Conductivity Using Carbon Nanotubes[J]. Energy Conversion and Management, 2017, 134:373-381.
[29] GAO L, CUI Y X, LI J Y, et al.Thermal Conductivity Enhanced N-hexadecane@PUA/Cu Phase Change Microcapsules for Temperature-Regulating Energy Storage Mortar[J]. Journal of Energy Storage, 2026, 150:120417.
[30] LIU Z F, CHEN Z H, YU F.Enhanced Thermal Conductivity of Microencapsulated Phase Change Materials Based on Graphene Oxide and Carbon Nanotube Hybrid Filler[J]. Solar Energy Materials and Solar Cells, 2019, 192:72-80.
[31] YU S Y, WANG X D, WU D Z.Microencapsulation of N-Octadecane Phase Change Material with Calcium Carbonate Shell for Enhancement of Thermal Conductivity and Serving Durability:Synthesis, Microstructure, and Performance Evaluation[J]. Applied Energy, 2014, 114:632-643.
[32] WANG T Y, WANG S F, GENG L X, et al.Enhancement on Thermal Properties of Paraffin/Calcium Carbonate Phase Change Microcapsules with Carbon Network[J]. Applied Energy, 2016, 179:601-608.
[33] YANG X M, LI C B, MA Y F, et al.High Thermal Conductivity of Porous Graphite/Paraffin Composite Phase Change Material with 3D Porous Graphite Foam[J]. Chemical Engineering Journal, 2023, 473:145364.
[34] AN Z J, PEA H J M, DU X Z, et al. Preparation and Characteristics Optimization of Octadecanoic Acid/Octadecanol/Expanded Graphite Based Composite Phase Change Materials for Energy Storage[J]. Journal of Energy Storage, 2022, 55:105598.
[35] YU X K, TAO Y B, HE Y, et al.Temperature Control Performance of High Thermal Conductivity Metal Foam/Paraffin Composite Phase Change Material:An Experimental Study[J]. Journal of Energy Storage, 2022, 46:103930.
[36] YANG B, XIE L K, CAO Y X, et al.The Role of Porosity Gradient Distribution on the Heat Transfer Characteristics of Copper Foam/Paraffin Composite Phase Change Material[J]. Journal of Energy Storage, 2025, 127:117157.
[37] QIN L Y, ZHONG L Z, QIN F Y, et al.Dual-Functional Phase Change Hydrogels with Boron Nitride Networks:High-Performance Thermal Interface Materials for Electronics Cooling[J]. Composites Science and Technology, 2025, 272:111386.
[38] LIU K, WANG L, HE Z F, et al.Efficient Utilization of Cold Energy Enabled by Phase Change Cold Storage Brine Gels with Superior Thermophysical Properties towards Biochemical Reagent Cold Chain[J]. Applied Energy, 2024, 371:123725.
[39] ZHANG Y, ZHANG G T, YAO J N, et al.Investigation on Thermal Performance of Epoxy Resin Encapsulated Eutectic Hydrated Salt/Expanded Perlite Composite Phase Change Materials for Thermal Energy Storage[J]. Solar Energy Materials and Solar Cells, 2025, 283:113453.
[40] WEN R L, ZHANG X G, HUANG Z H, et al.Preparation and Thermal Properties of Fatty Acid/Diatomite Form-Stable Composite Phase Change Material for Thermal Energy Storage[J]. Solar Energy Materials and Solar Cells, 2018, 178:273-279.
[41] LU X T, QIAN R D, XU X Y, et al.Modifications of Microencapsulated Phase Change Materials:Supercooling Suppression, Thermal Conductivity Enhancement and Stability Improvement[J]. Nano Energy, 2024, 124:109520.
[42] ZHAO J J, LONG J L, DU Y Q, et al.Recyclable Low-Temperature Phase Change Microcapsules for Cold Storage[J]. Journal of Colloid and Interface Science, 2020, 564:286-295.
[43] LI S L, DONG B B, WANG J H, et al.Synthesis and Characterization of Mixed Alkanes Microcapsules with Phase Change Temperature below Ice Point for Cryogenic Thermal Energy Storage[J]. Energy, 2019, 187:115898.
[44] ZHANG Z, ZHANG Z, CHANG T, et al.Phase Change Material Microcapsules with Melamine Resin Shell via Cellulose Nanocrystal Stabilized Pickering Emulsion In-Situ Polymerization[J]. Chemical Engineering Journal, 2022, 428:131164.
[45] CHEN F, LIN R Q, WANG Y K, et al.Study on the Preparation and Thermal Storage Performance of Flexibly Encapsulated Hydrate Salt Phase Change Capsules[J]. Journal of Energy Storage, 2026, 153:120925.
[46] AL-SHANNAQ R, KURDI J, AL-MUHTASEB S, et al.Innovative Method of Metal Coating of Microcapsules Containing Phase Change Materials[J]. Solar Energy, 2016, 129:54-64.
[47] JUNAID M F, REHMAN Z U, ČEKON M, et al.Inorganic Phase Change Materials in Thermal Energy Storage:A Review on Perspectives and Technological Advances in Building Applications[J]. Energy and Buildings, 2021, 252:111443.
[48] ZAHIR M H, MOHAMED S A, SAIDUR R, et al.Supercooling of Phase-Change Materials and the Techniques Used to Mitigate the Phenomenon[J]. Applied Energy, 2019, 240:793-817.
[49] ZHANG X X, FAN Y F, TAO X M, et al.Fabrication and Properties of Microcapsules and Nanocapsules Containing N-Octadecane[J]. Materials Chemistry and Physics, 2004, 88(2/3):300-307.
[50] LIU Y D, LI X, HU P F, et al.Study on the Supercooling Degree and Nucleation Behavior of Water-Based Graphene Oxide Nanofluids PCM[J]. International Journal of Refrigeration, 2015, 50:80-86.
[51] LI J C, HU B, WANG H, et al.Preparation and Properties of NH4Al(SO4)2·12H2O-CH3COONa·3H2O Eutectic Phase Change Materials and Supercooling Modification[J]. Solar Energy, 2025, 302:114041.
[52] ZHANG C, ZHANG Z Y, YE R D, et al.Characterization of MgCl2·6H2O-Based Eutectic/Expanded Perlite Composite Phase Change Material with Low Thermal Conductivity[J]. Materials, 2018, 11(12):2369.
[53] HONCOVA P, PILAR R, DANIELIK V, et al.Suppressing Supercooling in Magnesium Nitrate Hexahydrate and Evaluating Corrosion of Aluminium Alloy Container for Latent Heat Storage Application[J]. Journal of Thermal Analysis and Calorimetry, 2017, 129(3):1573-1581.
[54] XIE N, LUO J M, LI Z P, et al.Salt Hydrate/Expanded Vermiculite Composite as a Form-Stable Phase Change Material for Building Energy Storage[J]. Solar Energy Materials and Solar Cells, 2019, 189:33-42.
[55] ZHOU X C, ZHENG Q Y, WANG R Z.Ammonium Aluminum Sulfate Dodecahydrate Based Composite Phase Change Materials for Thermal Energy Storage and Utilization:Properties, Enhancements, and Applications[J]. Journal of Energy Storage, 2026, 141:119185.
[56] LEI K, BAO J M, ZHAO X Y, et al.Supercooling Suppression of Metal-Based Microencapsulated Phase Change Material (MEPCM) for Thermal Energy Storage[J]. Chemical Engineering Journal, 2022, 446:137020.
[57] LIU K, YUAN Z F, ZHAO H X, et al.Properties and Applications of Shape-Stabilized Phase Change Energy Storage Materials Based on Porous Material Support—A Review[J]. Materials Today Sustainability, 2023, 21:100336.
[58] LIU C Z, LI B H, WANG S W, et al.Synthesis of Alumina Porous Ceramics to Enhance Heat Transfer and Control Supercooling in Sugar Alcohol Phase Change Materials for Thermal Energy Storage[J]. Journal of Energy Storage, 2025, 113:115627.
[59] KI S, SHIN S, CHO S, et al.Sustainable Thermal Regulation of Electronics via Mitigated Supercooling of Porous Gallium-Based Phase Change Materials[J]. Advanced Science, 2024, 11(23):2310185.
[60] CONG L, ZOU B, PALACIOS A, et al.Thickening and Gelling Agents for Formulation of Thermal Energy Storage Materials-a Critical Review[J]. Renewable and Sustainable Energy Reviews, 2022, 155:111906.
[61] LI Y X, LI C C, LIN N Z, et al.Review on Tailored Phase Change Behavior of Hydrated Salt as Phase Change Materials for Energy Storage[J]. Materials Today Energy, 2021, 22:100866.
[62] XING X H, LU W, ZHANG G H, et al.Ternary Composite Phase Change Materials (PCMS) towards Low Phase Separation and Supercooling:Eutectic Behaviors and Application[J]. Energy Reports, 2022, 8:2646-2655.
[63] LIU K, HE Z F, LIN P C, et al.Highly-Efficient Cold Energy Storage Enabled by Brine Phase Change Material Gels towards Smart Cold Chain Logistics[J]. Journal of Energy Storage, 2022, 52:104828.
[64] LIU K, HE Z F, LUO Y Y, et al.Massive Fabrication of Flexible, Form-Stable, and Self-Repairing Brine Phase Change Material Gels Toward Smart Cold Chain Logistics[J]. ACS Applied Materials & Interfaces, 2023, 15(13):17091-17102.
[65] LIANG L, CHEN X.Preparation and Thermal Properties of Eutectic Hydrate Salt Phase Change Thermal Energy Storage Material[J]. International Journal of Photoenergy, 2018, 2018:6432047.
[66] SHAHZAD M, ALI R, LI M.Phase Change Materials for Low-Temperature Cold Chain Logistics:Advances, Challenges, and Eco-Friendly Solutions[J]. Renewable and Sustainable Energy Reviews, 2026, 230:116700.

基金

国家现代农业(特色淡水鱼)产业技术体系建设专项(CARS-46); 湖北省中央引导地方科技发展专项(2025EIA052); 湖北省自然科学基金项目(JCZRYB202501279)

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