木质素纳米颗粒的制备及其在食品包装中的应用研究进展

崔堂武; 贾琪; 常承林; 朱爱新; 李国峰; 胡礼珍

doi:10.19554/j.cnki.1001-3563.2026.11.006

PDF(1319 KB)

包装工程（技术栏目） ›› 2026, Vol. 47 ›› Issue (11) : 53-60. DOI: 10.19554/j.cnki.1001-3563.2026.11.006

功能性生物质材料

木质素纳米颗粒的制备及其在食品包装中的应用研究进展

崔堂武¹, 贾琪¹, 常承林², 朱爱新¹, 李国峰¹, 胡礼珍^3*

作者信息 +

Recent Advance in Preparation of Lignin Nanoparticles and Their Applications in Food Packaging

CUI Tangwu¹, JIA Qi¹, CHANG Chenglin², ZHU Aixin¹, LI Guofeng¹, HU Lizhen^3*

Author information +

文章历史 +

摘要

目的应对传统石油基包装造成的环境污染困境,开发绿色可持续的生物基替代材料,推动功能生物基薄膜的发展应用。方法本文基于国内外最新研究动态,对比梳理木质素纳米颗粒（LNPs）的多元化制备工艺（涵盖自组装技术、物理机械法、溶剂置换以及绿色深共晶溶剂体系等）,深入剖析LNPs与多糖类或可降解聚酯类基质共混后,复合薄膜微观结构的变化及其改性机制。结果木质素经纳米化处理后,不仅有效克服了其在基质中易团聚的缺陷,更依托庞大的比表面积显著放大了其天然的抑菌、抗氧化及抗紫外线效能。将LNPs引入多糖或生物降解聚酯网络中所构建的复合膜,能够实现材料力学强度、水分阻隔效果与综合保鲜功能的协同跃升,表明该类纳米复合材料在替代传统食品塑料包装方面具备极其广阔的开发前景。

Abstract

The work aims to develop green and sustainable bio-based alternative materials and advance the development and application of functional bio-based films, so as to address the environmental pollution challenges caused by conventional petroleum-based packaging. Drawing upon recent global research advancements, this paper systematically reviewed and compared the diverse preparation techniques for lignin nanoparticles (LNPs), including self-assembly, physical-mechanical methods, solvent exchange, and green deep eutectic solvent (DES) systems. Furthermore, it provided an in-depth analysis of the microstructural evolution and modification mechanisms of composite films when LNPs were blended with polysaccharide or biodegradable polyester matrices. Following nanoscale processing, lignin not only effectively overcomed its inherent tendency to agglomerate within matrices, but also leveraged its massive specific surface area to significantly enhance its natural antibacterial, antioxidant, and ultraviolet (UV)-shielding properties. The composite films formulated by incorporating LNPs into polysaccharide or biodegradable polyester networks achieve a synergistic enhancement in mechanical strength, moisture barrier performance, and comprehensive food preservation capabilities. This indicates that such nanocomposites possess immense potential for replacing traditional plastics in food packaging applications.

导出引用

崔堂武, 贾琪, 常承林, 朱爱新, 李国峰, 胡礼珍. 木质素纳米颗粒的制备及其在食品包装中的应用研究进展[J]. 包装工程. 2026, 47(11): 53-60 https://doi.org/10.19554/j.cnki.1001-3563.2026.11.006

CUI Tangwu, JIA Qi, CHANG Chenglin, ZHU Aixin, LI Guofeng, HU Lizhen. Recent Advance in Preparation of Lignin Nanoparticles and Their Applications in Food Packaging[J]. Packaging Engineering. 2026, 47(11): 53-60 https://doi.org/10.19554/j.cnki.1001-3563.2026.11.006

中图分类号： TB33

参考文献

[1] 陈炳洁, 刘汝宽, 肖志红, 等. 木质素纳米颗粒的制备及其复合薄膜在食品包装中的应用研究进展[J]. 现代化工, 2024, 44(8):22-26.
CHEN B J, LIU R K, XIAO Z H, et al.Research Progress on Preparation of Lignin Nanoparticles and Application of Their Composite Film in Food Packaging[J]. Modern Chemical Industry, 2024, 44(8):22-26.
[2] 吴怡颖, 解明昱, 邱展英, 等. 油茶果壳木质素纳米颗粒/壳聚糖复合膜的制备及性能研究[J]. 生物质化学工程, 2024, 58(6):14-22.
WU Y Y, XIE M Y, QIU Z Y, et al.Preparation and Properties of Camellia Oleifera Shell Lignin Nanoparticles/Chitosan Composite Films[J]. Biomass Chemical Engineering, 2024, 58(6):14-22.
[3] 欧金芬, 陈振东, 张涵. 木质素结构对其纳米化的影响及木质素纳米颗粒的功能性应用[J]. 中国造纸学报, 2024, 39(2):61-72.
OU J F, CHEN Z D, ZHANG H.Structural Influence on Lignin Nanoparticle Fabrication and Its Functional Application[J]. Transactions of China Pulp and Paper, 2024, 39(2):61-72.
[4] 侯龙龙, 李琼仙, 宁微微, 等. 木质素纳米颗粒在紫外防护领域的应用研究进展[J]. 中国造纸, 2025, 44(3):19-27.
HOU L L, LI Q X, NING W W, et al.Research Progress on Application of Lignin Nanoparticles in UV Protection[J]. China Pulp & Paper, 2025, 44(3):19-27.
[5] 智崇科, 王雪, 姚利宏. 木质素纳米颗粒的制备与应用研究进展[J]. 林产工业, 2024, 61(9):61-64.
ZHI C K, WANG X, YAO L H.Research Progress in the Preparation and Application of Lignin Nanoparticles[J]. China Forest Products Industry, 2024, 61(9):61-64.
[6] 吴丽冉, 王营超, 刘姗姗. 木质素纳米颗粒的可控制备及应用进展[J]. 中国造纸, 2021, 40(4):73-84.
WU L R, WANG Y C, LIU S S.Controllable Preparation of Lignin Nanoparticle and Its Application[J]. China Pulp & Paper, 2021, 40(4)::73-84.
[7] ZUBAIR M, RAUF Z, FATIMA S, et al.Lignin-Derived Bionanocomposites as Functional Food Packaging Materials[J]. Sustainable Food Technology, 2024, 2(4):945-966.
[8] 杜光武, 郑涛, 林宝凤. 不同粒径的LNPs对淀粉基包装膜性能的影响[J]. 包装与食品机械, 2025, 43(1):63-70.
DU G W, ZHENG T, LIN B F.The Influence of LNPS with Different Particle Sizes on the Properties of Starch-Based Packaging Films[J]. Packaging and Food Machinery, 2025, 43(1):63-70.
[9] 王雨婷, 魏缘鸿, 盖竣铭, 等. 木质素纳米颗粒的制备方法及其在复合薄膜材料中的应用研究进展[J]. 中国造纸, 2026, 45(1):20-26.
WANG Y T, WEI Y H, GAI J M, et al.Research Progress on the Preparation Method of Lignin Nanoparticles and Their Application in Composite Film Materials[J]. China Pulp & Paper, 2026, 45(1):20-26.
[10] 叶志雄, 余静, 邓超, 等. 纳米木质素/壳聚糖复合膜的制备及其光热抗菌性能研究[J]. 包装工程, 2024, 45(23):38-46.
YE Z X, YU J, DENG C, et al.Preparation of Lignin/Chitosan Nanocomposite Film and Its Photothermal Antimicrobial Properties[J]. Packaging Engineering, 2024, 45(23):38-46.
[11] 张伟, 安兴业, 刘利琴, 等. 木质素纳米颗粒/天然纤维基活性碳纤维材料的制备及其电化学性能[J]. 化工进展, 2022, 41(7):3770-3783.
ZHANG W, AN X Y, LIU L Q, et al.Preparation and Electrochemical Performance of Lignin Nanoparticles/Natural Fiber Based Activated Carbon Fiber Materials[J]. Chemical Industry and Engineering Progress, 2022, 41(7):3770-3783.
[12] PANG Y X, SUN Y N, LUO Y L, et al.Preparation of Novel All-Lignin Microcapsules via Interfacial Cross-Linking of Pickering Emulsion[J]. Industrial Crops and Products, 2021, 167:113468.
[13] LIANG W L, ZHANG J D, WURM F R, et al.Lignin-Based Non-Crosslinked Nanocarriers:A Promising Delivery System of Pesticide for Development of Sustainable Agriculture[J]. International Journal of Biological Macromolecules, 2022, 220:472-481.
[14] 夏梦瑶, 姜炜坤, 马占松. 木质素基纳米颗粒的制备及应用研究进展[J]. 大连工业大学学报, 2023, 42(3):181-189.
XIA M Y, JIANG W K, MA Z S.Review of Preparation and Application of Lignin-Based Nanoparticles[J]. Journal of Dalian Polytechnic University, 2023, 42(3):181-189.
[15] MARUTHAPANDI M, GUPTA A, SARAVANAN A, et al.Ultrasonic-Assisted Synthesis of Lignin-Capped Cu₂O Nanocomposite with Antibiofilm Properties[J]. Ultrasonics Sonochemistry, 2023, 92:106241.
[16] ZHANG Y, CHENG G.Lignin-Containing Hydrogels:Transforming a Low-Value Byproduct to Absorbents, Wound Dressings and Strain Sensors[J]. Chemical Engineering Journal, 2023, 475:146460.
[17] PANG T R, WANG G H, SUN H, et al.Lignin Fractionation for Reduced Heterogeneity in Self-Assembly Nanosizing:Toward Targeted Preparation of Uniform Lignin Nanoparticles with Small Size[J]. ACS Sustainable Chemistry & Engineering, 2020, 8(24):9174-9183.
[18] 梅赞, 王兵, 平清伟, 等. 玉米秸秆和撑篙竹乙醇精炼废液制备木质素纳米颗粒的研究[J]. 中国造纸学报, 2025, 40(1):74-82.
MEI Z, WANG B, PING Q W, et al.Direct Preparation of Lignin Nanoparticles from Ethanol Refining Waste Liquor of Corn Straw and Bambusa Pervariabilis[J]. Transactions of China Pulp and Paper, 2025, 40(1):74-82.
[19] SCHNEIDER W D H, DILLON A J P, CAMASSOLA M. Lignin Nanoparticles Enter the Scene:A Promising Versatile Green Tool for Multiple Applications[J]. Biotechnology Advances, 2021, 47:107685.
[20] JUIKAR S J, VIGNESHWARAN N.Extraction of Nanolignin from Coconut Fibers by Controlled Microbial Hydrolysis[J]. Industrial Crops and Products, 2017, 109:420-425.
[21] AGUSTIN M B, LAHTINEN M H, KEMELL M, et al.Enzymatic Crosslinking of Lignin Nanoparticles and Nanocellulose in Cryogels Improves Adsorption of Pharmaceutical Pollutants[J]. International Journal of Biological Macromolecules, 2024, 266:131168.
[22] SILVA M N B, SCOPEL E, REZENDE C A. From Black Liquor to Tinted Sunscreens:Washing out Kraft Lignin Unpleasant Odor and Improving Its Properties by Lignin Nanoparticle Preparation[J]. Industrial Crops and Products, 2024, 218:118910.
[23] SAPOUNA I, ALEXAKIS A E, MALMSTRÖM E, et al. Structure-Property Relationship of Native-Like Lignin Nanoparticles from Softwood and Hardwood[J]. Industrial Crops and Products, 2023, 206:117660.
[24] LUO Y D, LIANG L L, LUO H Y, et al.Green Extraction of Polyphenolic Lignin Using FeCl₃-Mediated Tartaric Acid-DES and Its Derived Lignin Nanoparticles for Enhancing the Application Performance of PVA Film in Green Agriculture[J]. Green Chemistry, 2025, 27(9):2538-2553.
[25] SHOMALI Z, FATEHI P.Carboxyalkylated Lignin Nanoparticles with Enhanced Functionality for Oil-Water Pickering Emulsion Systems[J]. ACS Sustainable Chemistry & Engineering, 2022, 10(50):16563-16577.
[26] ORTEGA-SANHUEZA I, GIRARD V, ZIEGLER-DEVIN I, et al.Preparation and Characterization of Lignin Nanoparticles from Different Plant Sources[J]. Polymers, 2024, 16(11):1610.
[27] FIGUEIREDO P, LAHTINEN M H, AGUSTIN M B, et al.Green Fabrication Approaches of Lignin Nanoparticles from Different Technical Lignins:A Comparison Study[J]. ChemSusChem, 2021, 14(21):4718-4730.
[28] ZHANG W, GAO P, JIANG Q X, et al.Green Fabrication of Lignin Nanoparticles/Chitosan Films for Refrigerated Fish Preservation Application[J]. Food Hydrocolloids, 2023, 139:108548.
[29] SUN X W, LI Q Y, WU H J, et al.Sustainable Starch/Lignin Nanoparticle Composites Biofilms for Food Packaging Applications[J]. Polymers, 2023, 15(8):1959.
[30] ZHANG S K, FU Q B, LI H S, et al.Polydopamine-Coated Lignin Nanoparticles in Polysaccharide-Based Films:A Plasticizer, Mechanical Property Enhancer, Anti-Ultraviolet Agent and Bioactive Agent[J]. Food Hydrocolloids, 2024, 147:109325.
[31] ZENG S Y, LIU X G, LI J, et al.Multi-Functional Polyvinyl Alcohol/Tannin Acid Composite Films Incorporated with Lignin Nanoparticles Loaded by Potassium Sorbate[J]. International Journal of Biological Macromolecules, 2024, 264:130474.
[32] YANG W J, DING H, QI G C, et al.Highly Transparent PVA/Nanolignin Composite Films with Excellent UV Shielding, Antibacterial and Antioxidant Performance[J]. Reactive and Functional Polymers, 2021, 162:104873.
[33] BASBASAN A J, HARARAK B, WINOTAPUN C, et al.Lignin Nanoparticles for Enhancing Physicochemical and Antimicrobial Properties of Polybutylene Succinate/Thymol Composite Film for Active Packaging[J]. Polymers, 2023, 15(4):989.
[34] MOE N C, BASBASAN A, WINOTAPUN C, et al.Application of Lignin Nanoparticles in Polybutylene Succinate Based Antifungal Packaging for Extending the Shelf Life of Bread[J]. Food Packaging and Shelf Life, 2023, 39:101127.
[35] 俞张勇, 杨兆昆, 施冬健, 等. PLA/木质素基复合材料的非等温结晶动力学[J]. 塑料, 2021, 50(5):103-107.
YU Z Y, YANG Z K, SHI D J, et al.Non-Isothermal Crystallization Kinetics of PLA/Lignin Based Composite[J]. Plastics, 2021, 50(5):103-107.
[36] TONE A M, HERRANZ SOLANA N, KHAN M R, et al.Study on the Properties of PLA-and PP-Based Films for Food Applications Incorporating Orange Peel Extract from Agricultural By-Products[J]. Polymers, 2024, 16(9):1245.
[37] PENG J Q, WANG Y.Lignin Nanoparticles in Food Packaging:A Sustainable Approach to Material Design and Performance Enhancement[J]. Frontiers in Nutrition, 2025, 12:1659877.