Development of PLA/PBAT/TPS-based Active Modified Atmosphere Packaging Films for Preserving Green Color in Perfume Lemons

ZHANG Chen, LU Xinyu, LIU Xiaofang, YANG Dingyan, FAN Min, Wang Daode, LI Li

Packaging Engineering ›› 2026, Vol. 47 ›› Issue (7) : 92-102.

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Packaging Engineering ›› 2026, Vol. 47 ›› Issue (7) : 92-102. DOI: 10.19554/j.cnki.1001-3563.2026.07.011
Agro-products Preservation and Food Packaging

Development of PLA/PBAT/TPS-based Active Modified Atmosphere Packaging Films for Preserving Green Color in Perfume Lemons

  • ZHANG Chen1, LU Xinyu1, LIU Xiaofang1, YANG Dingyan1, FAN Min1, Wang Daode2, LI Li1,*
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Abstract

The gas permeability of packaging films is crucial for regulating the post-harvest micro-environment of fruits and vegetables. The work aims to extend the freshness preservation period of perfume lemon by designing the gas permeability of the films to regulate the dynamic balance of O2 and CO2 inside the packaging, thereby inhibiting respiration, maintaining green color, and delaying physiological senescence. Composite films with different gradients of polylactic acid (PLA) and poly (butylene adipate-co-terephthalate) (PBAT) were prepared via melt extrusion to investigate the barrier properties and mechanical performance of the composite films. Then, the films were subsequently applied in the preservation experiment of perfume lemon. The ability of the films to maintain fruit appearance was evaluated through physicochemical indicators, including analysis of gas composition inside the package, weight loss rate, and chlorophyll content. The 3PLA-7PBAT composite film (PLA/PBAT/thermoplastic starch ratio of 16/64/20) demonstrated excellent gas regulation capability, with an O2 transmission rate of (221.02±58.74) cm3/(m2·24 h·0.1 MPa). This combination of properties enabled it to maintain an ideal gas atmosphere inside the packaging during room-temperature preservation experiments, effectively suppressing chlorophyll degradation and preserving the characteristic color of fragrance lemon. Consequently, the green-retention period was prolonged by 250% compared with that of the untreated group. In conclusion, this research confirms that the ratio of PLA to PBAT is key to regulating the properties of PLA/PBAT/TPS composite films and their green-keeping effect on perfume lemons. The 3PLA-7PBAT composite film exhibits the best green-keeping performance by precisely adjusting gas permeability and optimizing the packaging micro-environment. This research provides new insights for the green and functional design of bio-based packaging materials.

Key words

biodegradable film / gas permeability / perfume lemon / shelf life

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ZHANG Chen, LU Xinyu, LIU Xiaofang, YANG Dingyan, FAN Min, Wang Daode, LI Li. Development of PLA/PBAT/TPS-based Active Modified Atmosphere Packaging Films for Preserving Green Color in Perfume Lemons[J]. Packaging Engineering. 2026, 47(7): 92-102 https://doi.org/10.19554/j.cnki.1001-3563.2026.07.011

References

[1] YE Z Y, ZHAO K, DAI Z S, et al.Whole-Fruit Utilization of ‘Xiangshui’ Lemon (Citrus × Limon ‘Rosso’): Albedo Valorization for Aroma Complexity and Waste Reduction[J]. Food Chemistry: X, 2026, 33: 103509.
[2] LI C X, LI X L, LIANG G L, et al.Volatile Composition Changes in Lemon during Fruit Maturation by HS-SPME-GC-MS[J]. Journal of the Science of Food and Agriculture, 2022, 102(9): 3599-3606.
[3] ZHOU X Y, ZHANG B R, DUAN M X, et al.Integrated Transcriptomics and Metabolomics Reveal the Mechanisms of Postharvest Uneven Degreening of Green Lemon[J]. Postharvest Biology and Technology, 2024, 216: 113072.
[4] YENARE R R, SONAWANE C R, SUR A, et al.A Comprehensive Review of Portable Cold Storage: Technologies, Applications, and Future Trends[J]. Alexandria Engineering Journal, 2024, 94: 23-33.
[5] YOU Y L, ZHOU Y N, DUAN X W, et al.Research Progress on the Application of Different Preservation Methods for Controlling Fungi and Toxins in Fruit and Vegetable[J]. Critical Reviews in Food Science and Nutrition, 2023, 63(33): 12441-12452.
[6] LIU X F, YI J X, MA W Y, et al.Regulating the Permeability of Poly(lactic acid)/Poly(3-Hydroxybutyrate-Co-4- Hydroxybutyrate) Composite Films for Peach Preservation[J]. International Journal of Biological Macromolecules, 2025, 334: 149090.
[7] SWETHA T A, BORA A, MOHANRASU K, et al.A Comprehensive Review on Polylactic Acid (PLA) - Synthesis, Processing and Application in Food Packaging[J]. International Journal of Biological Macromolecules, 2023, 234: 123715.
[8] LIU T Y, ZHEN Z C, ZANG X L, et al.Fluorescence Tracing the Degradation Process of Biodegradable PBAT: Visualization and High Sensitivity[J]. Journal of Hazardous Materials, 2023, 454: 131572.
[9] WANG X, PENG S X, CHEN H, et al.Mechanical Properties, Rheological Behaviors, and Phase Morphologies of High-Toughness PLA/PBAT Blends by In-Situ Reactive Compatibilization[J]. Composites Part B: Engineering, 2019, 173: 107028.
[10] MA J T, ZHOU Y T, OU P Z, et al.Preparation, Performance and Application - Current Status and Trends in Thermoplastic Starch[J]. Carbohydrate Polymers, 2026, 373: 124655.
[11] CHENG Y, WANG W T, ZHANG R, et al.Effect of Gelatin Bloom Values on the Physicochemical Properties of Starch/Gelatin-Beeswax Composite Films Fabricated by Extrusion Blowing[J]. Food Hydrocolloids, 2021, 113: 106466.
[12] GAO S, ZHANG Y Z, WANG J Y, et al.Influence of Starch Content on the Physicochemical and Antimicrobial Properties of Starch/PBAT/ε-Polylysine Hydrochloride Blown Films[J]. Food Packaging and Shelf Life, 2022, 34: 101005.
[13] WENG Y X, JIN Y J, MENG Q Y, et al.Biodegradation Behavior of Poly(butylene adipate-co-terephthalate) (PBAT), Poly(lactic acid) (PLA), and Their Blend under Soil Conditions[J]. Polymer Testing, 2013, 32(5): 918-926.
[14] MAO S F, REN Y M, WEI C Q, et al.Development of Novel EGCG/Fe Loaded Sodium Alginate-Based Packaging Films with Antibacterial and Slow-Release Properties[J]. Food Hydrocolloids, 2023, 145: 109032.
[15] YOKESAHACHART C, YOKSAN R, KHANOONKON N, et al.Effect of Jute Fibers on Morphological Characteristics and Properties of Thermoplastic Starch/Biodegradable Polyester Blend[J]. Cellulose, 2021, 28(9): 5513-5530.
[16] WANG Y N, YANG H C, LI B J, et al.Poly(butylene adipate/terephthalate-co-glycolate) Copolyester Synthesis Based on Methyl Glycolate with Improved Barrier Properties: From Synthesis to Structure-Property[J]. International Journal of Molecular Sciences, 2022, 23(19): 11074.
[17] LIU X F, LIU Y, FAN M, et al.Development of Antibacterial Starch-Based PLA/PBAT Active Packaging Films for Enhanced Beef Preservation[J]. Food Chemistry, 2025, 493: 145804.
[18] CASTRO M C R, PEREIRA J, ANDRÉ M P, et al. Tailoring PLA/Gelatin Film Properties for Food Packaging Using Deep Eutectic Solvents[J]. Molecules, 2025, 31(1): 39.
[19] GARCÍA-CARRILLO M, HERNÁNDEZ-LÓPEZ A A, ESPINOZA-MARTÍNEZ A B. Modeling and Optimization of Mechanical, Water Vapor Permeability and Haze Properties of PLA and PBAT Films Reinforced with Montmorillonite, Halloysite Nanotubes and Palygorskite Using Artificial Neural Networks and Genetic Algorithms[J]. Food Packaging and Shelf Life, 2025, 49: 101533.
[20] WANG X Y, CHEN Q F.Optimization of Barrier Properties of PLA/PBAT Polymers in Biodegradable Materials[J]. Starch - Stärke, 2025, 77(3): 2400135.
[21] HUANG Y Q, DAI D D, LI H B, et al.Oxygen Barrier, Free Volume, and Blending Properties of Fully Bio-Based Polyamide 11/Poly(vinyl alcohol) Blends[J]. Journal of Applied Polymer Science, 2020, 137(15): 48562.
[22] KLINMALAI P, SRISA A, LAORENZA Y, et al.Antifungal and Plasticization Effects of Carvacrol in Biodegradable Poly(lactic acid) and Poly(butylene adipate terephthalate) Blend Films for Bakery Packaging[J]. LWT, 2021, 152: 112356.
[23] SUN C, LI C X, LI H Y, et al.Modified Cellulose Nanocrystals Enhanced the Compatibility between PLA and PBAT to Prepare a Multifunctional Composite Film[J]. Journal of Polymers and the Environment, 2022, 30(8): 3139-3149.
[24] ALIOTTA L, CINELLI P, COLTELLI M B, et al.Effect of Nucleating Agents on Crystallinity and Properties of Poly(lactic acid) (PLA)[J]. European Polymer Journal, 2017, 93: 822-832.
[25] DING J, HAO Y, LIU B Q, et al.Development and Application of Poly(lactic acid)/Poly(butylene adipate-co-terephthalate)/Thermoplastic Starch Film Containing Salicylic Acid for Banana Preservation[J]. Foods, 2023, 12(18): 3397.
[26] ZHANG H Z, HAN M M, XIE Y, et al.Application of Ethylene-Regulating Packaging in Post-Harvest Fruits and Vegetables Storage: A Review[J]. Packaging Technology and Science, 2022, 35(6): 461-471.
[27] CHENG Z, LI J L, HE G S, et al.Biodegradable Packaging Paper Derived from Chitosan-Based Composite Barrier Coating for Agricultural Products Preservation[J]. International Journal of Biological Macromolecules, 2024, 280: 136112.
[28] CHEN K, TIAN R M, JIANG J, et al.Moisture Loss Inhibition with Biopolymer Films for Preservation of Fruits and Vegetables: A Review[J]. International Journal of Biological Macromolecules, 2024, 263: 130337.
[29] GIANNAKOUROU M C, TSIRONI T N.Application of Processing and Packaging Hurdles for Fresh-Cut Fruits and Vegetables Preservation[J]. Foods, 2021, 10(4): 830.
[30] CONESA A, MANERA F C, BROTONS J M, et al.Changes in the Content of Chlorophylls and Carotenoids in the Rind of Fino 49 Lemons during Maturation and Their Relationship with Parameters from the CIELAB Color Space[J]. Scientia Horticulturae, 2019, 243: 252-260.
[31] HERBIG A L, MAINGONNAT J F, RENARD C M G C. Oxygen Availability in Model Solutions and Purées during Heat Treatment and the Impact on Vitamin C Degradation[J]. LWT - Food Science and Technology, 2017, 85: 493-499.
[32] DONG W X, GUAN P Y, LIU J G, et al.Preparation and Characterization of Artemisia Argyi Essential Oil Microcapsule and Its Application in Postharvest Preservation of Cherry Tomatoes[J]. Food Chemistry, 2025, 496: 146784.
[33] LIU H, CAO J K, JIANG W B.Changes in Phenolics and Antioxidant Property of Peach Fruit during Ripening and Responses to 1-Methylcyclopropene[J]. Postharvest Biology and Technology, 2015, 108: 111-118.
[34] YANG W H, WANG L, BAN Z J, et al.Efficient Microencapsulation of Syringa Essential Oil; The Valuable Potential on Quality Maintenance and Storage Behavior of Peach[J]. Food Hydrocolloids, 2019, 95: 177-185.
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