Optimization of the P&#x00026;T-GC-MS Analysis Method for Cigarette Paper Pollutants Based on the Response Surface Methodology

ZHANG Junsong; XIANG Keyu; HOU Shicong; WANG Guangyao; YANG Chengcheng; WANG Jiaqi; LIANG Miao; WANG Yangxun

doi:10.19554/j.cnki.1001-3563.2026.03.019

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Packaging Engineering ›› 2026, Vol. 47 ›› Issue (3) : 178-188. DOI: 10.19554/j.cnki.1001-3563.2026.03.019

Automatic and Intelligent Technology

Optimization of the P&T-GC-MS Analysis Method for Cigarette Paper Pollutants Based on the Response Surface Methodology

ZHANG Junsong¹, XIANG Keyu¹, HOU Shicong², WANG Guangyao^2,*, YANG Chengcheng², WANG Jiaqi¹, LIANG Miao¹, WANG Yangxun^2,*

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Abstract

The work aims to optimize the Purge and Trap Gas Chromatography-Mass Spectrometry (P&T-GC-MS) analysis method for determining volatile components in pollutants present as spots on cigarette paper. Single-factor experiment, Plackett-Burman design and Box-Behnken response surface optimization were used to study the effect of purge and trap method on the enrichment and analysis of volatile components. The optimal level was determined by single-factor experiments on extraction liquid volume, purging flow, sample cup temperature, purging temperature and decomposition temperature. The Plackett-Burman experiment was carried out to identify three significant factors that affected the enrichment effect of spot components, namely purging temperature (B), decomposition temperature (C), and purging flow (E). Through the steepest ascent experiment coupled with response surface optimization analysis, a model relating three primary factors to the total peak area detected for volatile components was identified. The optimal levels for each factor were as follows: a purging temperature of 24.286 ℃, a decomposition temperature of 228.576 ℃, and a purging flow of 43.196 mL/min. Confirmatory experiments demonstrated that the detection of volatile components in cigarette paper spots yielded better results under optimal conditions. The P&T-GC-MS analysis method, optimized through the response surface methodology, enables efficient enrichment and identification of volatile components in spot pollutants on cigarette paper, offering a valuable methodological reference for the identification and tracing of pollution sources in cigarette paper.

Key words

cigarette paper spots / purge and trap / Plackett-Burman experiment / response surface optimization

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ZHANG Junsong, XIANG Keyu, HOU Shicong, WANG Guangyao, YANG Chengcheng, WANG Jiaqi, LIANG Miao, WANG Yangxun. Optimization of the P&T-GC-MS Analysis Method for Cigarette Paper Pollutants Based on the Response Surface Methodology[J]. Packaging Engineering. 2026, 47(3): 178-188 https://doi.org/10.19554/j.cnki.1001-3563.2026.03.019

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