Research Progress and Market Application Analysis of Degradable Packaging Materials

LYU Fengxiang, SU Yanqun, LIU Sen, LIU Zhongwei, SANG Lijun

Packaging Engineering ›› 2026, Vol. 47 ›› Issue (3) : 10-18.

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PDF(14488 KB)
Packaging Engineering ›› 2026, Vol. 47 ›› Issue (3) : 10-18. DOI: 10.19554/j.cnki.1001-3563.2026.03.002
Advanced Materials

Research Progress and Market Application Analysis of Degradable Packaging Materials

  • LYU Fengxiang1, SU Yanqun2, LIU Sen1, LIU Zhongwei1, SANG Lijun1,*
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Abstract

The work aims to review and analyze the research progress and market application status of four types of degradable packaging materials, namely biodegradable plastics, photodegradable plastics, water-degradable plastics, and paper-based eco-friendly materials, so as to comprehensively outline the research directions, application prospects, and challenges faced by degradable packaging materials, and promote the green, safe, and market-oriented development of degradable packaging materials. Research reports on degradable packaging materials published in domestic and international journals from 2021 to 2025 were collected and examined. The latest developments, technical characteristics, and application statuses of biodegradable plastics, photodegradable plastics, water-degradable plastics, and paper-based eco-friendly materials were outlined. The costs, performance, degradation conditions, and life cycles of various biodegradable packaging materials were compared, and the main challenges in their application were analyzed. In recent years, significant breakthroughs have been made in the research and development of biodegradable packaging materials. However, high costs remain an issue. Compared with photodegradable plastics, water-degradable plastics, and paper-based materials, biodegradable plastics offer greater advantages in terms of renewable raw materials and material properties; nevertheless, their cost and degradation conditions still require optimization. Paper-based environmental protection materials have high market acceptance, but their development is hindered by limitations in material properties. While the market for water-degradable plastics is experiencing rapid growth, their poor physical properties limit their suitability for specific applications. Currently, photodegradable plastics depend heavily on light conditions, limiting their practical applications.

Key words

degradable materials / packaging materials / research progress / market status / application challenges

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LYU Fengxiang, SU Yanqun, LIU Sen, LIU Zhongwei, SANG Lijun. Research Progress and Market Application Analysis of Degradable Packaging Materials[J]. Packaging Engineering. 2026, 47(3): 10-18 https://doi.org/10.19554/j.cnki.1001-3563.2026.03.002

References

[1] LANDRIGAN P J, RAPS H, CROPPER M, et al.The Minderoo-Monaco Commission on Plastics and Human Health[J]. Annals of Global Health, 2023, 89(1): 23.
[2] FAUVELLE V, GAREL M, TAMBURINI C, et al.Organic Additive Release from Plastic to Seawater Is Lower under Deep-Sea Conditions[J]. Nature Communications, 2021, 12: 4426.
[3] 袁晓宝, 刘雅婷, 陈妮, 等. 绿色包装材料研究进展[J]. 包装工程, 2022, 43(7): 87-94.
YUAN X B, LIU Y T, CHEN N, et al.Research Progress on Green Packaging Materials[J]. Packaging Engineering, 2022, 43(7): 87-94.
[4] NAGY L B, NAYGA R M, TEMESI Á.Nudging Consumers about the Issue of Microplastics: An Experimental Auction Study on Valuation for Sustainable Food Packaging[J]. Scientific Reports, 2024, 14: 18993.
[5] LIU Y Y, DOU Q.Enhanced Toughness of Poly(lactic acid) and Poly(butylene adipate-co-terephthalate) Blends by Incorporating an ADR Chain-Extending Agent and a Bio-Resourced Plasticizer[J]. International Journal of Biological Macromolecules, 2025, 293: 139344.
[6] CHEN C H, WANG L P, LIU F, et al.Biodegradable Thermoplastic Elastomers Achieved by Unchaining Intrinsic Entropic Elasticity[J]. Advanced Functional Materials, 2026, 36(5): e15241.
[7] SUN J S, HUANG H Z, WANG W, et al.Ultratough, Processable Bioplastics Enabled by Triple Interlocking of Lignin and Cellulose[J]. ACS Nano, 2025, 19(32): 29360-29371.
[8] XU T, MITRA R, TAN D, et al.Utilization of Gene Manipulation System for Advancing the Biotechnological Potential of Halophiles: A Review[J]. Biotechnology Advances, 2024, 70: 108302.
[9] PAN L J, KHAN W H, LI J, et al.Metabolic Mechanism in Biosynthesis of Polyhydroxyalkanoate from Terephthalic Acid by Mixed Microbial Consortium[J]. Chemical Engineering Journal, 2025, 515: 163695.
[10] WANG W Y, TAO J P, PANG R R, et al.Effect of Alkaline-Thermal Pretreatment on Biodegradable Plastics Degradation and Dissemination of Antibiotic Resistance Genes in Co-Compost System[J]. Journal of Hazardous Materials, 2025, 489: 137644.
[11] TANG C W, WANG L, SUN J, et al.Degradable Living Plastics Programmed by Engineered Spores[J]. Nature Chemical Biology, 2025, 21(7): 1006-1011.
[12] KIM M S, CHANG H, ZHENG L, et al.A Review of Biodegradable Plastics: Chemistry, Applications, Properties, and Future Research Needs[J]. Chemical Reviews, 2023, 123(16): 9915-9939.
[13] NIZAMUDDIN S, CHEN C R.Biobased, Biodegradable and Compostable Plastics: Chemical Nature, Biodegradation Pathways and Environmental Strategy[J]. Environmental Science and Pollution Research, 2024, 31(6): 8387-8399.
[14] BAO L, CUI X J, ZENG T, et al.Incorporation of Polylactic Acid Microplastics into the Carbon Cycle as a Carbon Source to Remodel the Endogenous Metabolism of the Gut[J]. PNAS, 2025, 122(19): 241-256.
[15] DREILING R J, HUYNH K, FORS B P.Degradable Thermosets via Orthogonal Polymerizations of a Single Monomer[J]. Nature, 2025, 638(8049): 120-125.
[16] LING C, QIAO G Q, SHUAI B W, et al.Engineering NADH/NAD+ Ratio in Halomonas Bluephagenesis for Enhanced Production of Polyhydroxyalkanoates (PHA)[J]. Metabolic Engineering, 2018, 49: 275-286.
[17] CHENG Y R, HIRANO E, WANG H, et al.Mechanically Strong yet Metabolizable Supramolecular Plastics by Desalting Upon Phase Separation[J]. Science, 2024, 386(6724): 875-881.
[18] 韦伯咨询. 2025年中国生物降解塑料行业专题调研与深度分析报告[R]. 深圳: 韦伯(深圳)咨询服务有限公司, 2025: 8.
WEBER Consulting.Special Survey and In-depth Analysis Report on China's Biodegradable Plastics Industry in 2025[R]. Shenzhen: Weber (Shenzhen) Consulting Service Co., Ltd., 2025: 8.
[19] CAO Y, MA W Y, CHEN S Q, et al.Immobilization of Proteinase K into PLA for Self-Biodegradable[J]. International Journal of Biological Macromolecules, 2025, 304(2): 140873.
[20] BABY M G, GERRITSE J, BELTRAN-SANAHUJA A, et al.Aging of Plastics and Microplastics in the Environment: A Review on Influencing Factors, Quantification Methods, Challenges, and Future Perspectives[J]. Environmental Science and Pollution Research, 2025, 32(3): 1009-1042.
[21] WANG K, MA S L, LI Z H, et al.New Insights into the Long-Term Leaching Process of Dissolved Organic Matter from Microplastics: Dynamic Formation and Transformation Mechanism[J]. Environmental Science & Technology, 2025, 59(41): 22180-22191.
[22] PALOYAN A, TADEVOSYAN M, GHEVONDYAN D, et al.Biodegradation of Polyhydroxyalkanoates: Current State and Future Prospects[J]. Frontiers in Microbiology, 2025, 16: 1542468.
[23] HARDY C, KOCIOK-KÖHN G, BUCHARD A. UV Degradation of Poly(lactic acid) Materials through Copolymerisation with a Sugar-Derived Cyclic Xanthate[J]. Chemical Communications, 2022, 58(36): 5463-5466.
[24] ZHANG S J, WANG J X, SU D W, et al.Facile Visible-Light Upcycling of Diverse Waste Plastics Using a Single Organocatalyst with Minimal Loadings[J]. Nature Communications, 2025, 16: 4188.
[25] MENG J L, ZHOU Y L, LI D J, et al.Degradation of Plastic Wastes to Commercial Chemicals and Monomers under Visible Light[J]. Science Bulletin, 2023, 68(14): 1522-1530.
[26] XU S Y, LIU S X, SONG W Z, et al.Metal-Free Upcycling of Plastic Waste: Photo-Induced Oxidative Degradation of Polystyrene in Air[J]. Green Chemistry, 2024, 26(3): 1363-1369.
[27] DENG S M, CAO R Z, WANG X J, et al.Upconversion Phosphor-Driven Photodegradation of Plastics[J]. Nano Letters, 2024, 24(44): 14082-14090.
[28] DE ABREU A L, TATON D, BASSANI D M. Reassessing the Photochemical Upcycling of Polystyrene Using Acridinium Salts[J]. Angewandte Chemie International Edition, 2025, 64(6): e202418680.
[29] ZHANG H Y, GAO J W, CHEN S B, et al.Photodegradation of Plastic Blends in Seawater and Its Risk to the Marine Environment[J]. Huanjing Kexue, 2023, 44(11): 6172-6180.
[30] XIAO X Y, ZHENG H D, GAO H, et al.Recent Advances in Synthesis of Non-Alternating Polyketone Generated by Copolymerization of Carbon Monoxide and Ethylene[J]. International Journal of Molecular Sciences, 2024, 25(2): 1348-1367.
[31] 王艳霞. 新型添加型光敏剂芳基三唑制备光降解塑料及性能研究[J]. 塑料科技, 2021, 49(2): 48-50.
WANG Y X.Study on Properties of Photodegradable Plastic Prepared by LDPE Doped with New Photosensitizer Aryltriazole[J]. Plastics Science and Technology, 2021, 49(2): 48-50.
[32] CHENG Z J, GUAN B Y, WANG J L, et al.Application of Photocatalytic Technology in the Treatment and Disposal of Waste Plastics: A Review[J]. Progress in Reaction Kinetics and Mechanism, 2025, 50(1): e002.
[33] OH S, STACHE E E.Recent Advances in Oxidative Degradation of Plastics[J]. Chemical Society Reviews, 2024, 53(14): 7309-7327.
[34] JIANG M P, LI J J, WAN X Y, et al.Floatable Organic-Inorganic Hybrid-TiO2 Unlocks Superoxide Radicals for Plastic Photoreforming in Neutral Solution[J]. Nature Communications, 2025, 16: 4136.
[35] NÚÑEZ M Y N, REHLAENDER M Á, MARTÍNEZ-DE LA CRUZ A, et al. Enhancing Visible Light Photocatalytic Degradation of Bisphenol a Using BiOI/Bi2MoO6 Heterostructures[J]. Nanomaterials, 2023, 13(9): 1503.
[36] OH S, STACHE E E.Chemical Upcycling of Commercial Polystyrene via Catalyst-Controlled Photooxidation[J]. Journal of the American Chemical Society, 2022, 144(13): 5745-5749.
[37] DAHER E A, HAMMOUD Y, ROBERT C L, et al.Natural Sunlight-Driven Photocatalytic Degradation of Polypropylene Microplastics over ZnO Nanorods[J]. Environmental Research, 2025, 279: 121836.
[38] ZHAO X, BORUAH B, CHIN K F, et al.Upcycling to Sustainably Reuse Plastics[J]. Advanced Materials, 2022, 34(25): 2100843.
[39] SURANA M, PATTANAYAK D S, YADAV V, et al.An Insight Decipher on Photocatalytic Degradation of Microplastics: Mechanism, Limitations, and Future Outlook[J]. Environmental Research, 2024, 247: 118268.
[40] VAN LE D, NGUYEN M B, DANG P T, et al.Synthesis of a UiO-66/g-C3N4 Composite Using Terephthalic Acid Obtained from Waste Plastic for the Photocatalytic Degradation of the Chemical Warfare Agent Simulant, Methyl Paraoxon[J]. RSC Advances, 2022, 12(35): 22367-22376.
[41] YUAN R Z, ZHANG Z J, BU F K, et al.Solar-Driven Plastic Waste Conversion: A Mini-Review on Photoreforming for Co-Producing Hydrogen and Chemical Feedstocks[J]. Frontiers in Energy, 2025, 19(5): 568-585.
[42] 曹晓庆, 李璐, 张锋伟, 等. 五种常见可降解地膜的研究应用现状和展望[J]. 核农学报, 2023, 37(5): 1076-1087.
CAO X Q, LI L, ZHANG F W, et al.Research and Application Status of Five Common Types of Degradable Mulching Films[J]. Journal of Nuclear Agricultural Sciences, 2023, 37(5): 1076-1087.
[43] LI M, ZHANG S B.Tandem Chemical Depolymerization and Photoreforming of Waste PET Plastic to High-Value-Added Chemicals[J]. ACS Catalysis, 2024, 14(5): 2949-2958.
[44] NIU L H, SHEN J Y, LI Y, et al.Plastic Additives Alter the Influence of Photodegradation on Biodegradation of Polyethylene/Polypropylene Polymers in Natural Rivers[J]. Journal of Hazardous Materials, 2025, 489: 137542.
[45] YANG Z X, WANG H, LI Y, et al.Efficient Photocatalytic Degradation of Polystyrene Microplastics in Water over Core-Shell BiO2-x/CuBi2O4 Heterojunction with Full Spectrum Light Response[J]. Journal of Colloid and Interface Science, 2025, 686: 327-335.
[46] 张静, 赵艳, 陈思宝, 等. 可降解共混塑料在海水中的光降解研究[J]. 环境科学学报, 2023, 43(7): 81-89.
ZHANG J, ZHAO Y, CHEN S B, et al.Study on Photodegradation of Degradable Plastic Blends in Seawater[J]. Acta Scientiae Circumstantiae, 2023, 43(7): 81-89.
[47] GARNER J, PARK K.Nuplon: New Synthetic Polymers Fully Degradable in Water[J]. Journal of Controlled Release, 2025, 377: 744-755.
[48] LI A N, SHENG Y J, CUI H Y, et al.Discovery and Mechanism-Guided Engineering of BHET Hydrolases for Improved PET Recycling and Upcycling[J]. Nature Communications, 2023, 14: 4169.
[49] ALI R, ZHANG Y F.Machine Learning Meets Enzyme Engineering: Examples in the Design of Polyethylene Terephthalate Hydrolases[J]. Frontiers of Chemical Science and Engineering, 2024, 18(12): 149.
[50] CONG L, LI Z S, ZHENG Z R, et al.Crystal Structure of a Novel PU Plastic Degradation Urethanase UMG-SP2 Mutant from Uncultured Bacterium in Complex with Ligand[J]. ACS Catalysis, 2025, 30(15):16019.
[51] CAO Z H, KIM C, LI Z H, et al.Comparing Environmental Fate and Ecotoxicity of Conventional and Biodegradable Plastics: A Critical Review[J]. Science of the Total Environment, 2024, 951: 175735.
[52] WU Y, CHEN S X, WU J, et al.Revivable Self-Assembled Supramolecular Biomass Fibrous Framework for Efficient Microplastic Removal[J]. Science Advances, 2024, 10(48): 8662.
[53] MEZA HUAMAN S M, NICHOLSON J H, BROGAN A P S. A General Route to Retooling Hydrolytic Enzymes Toward Plastic Degradation[J]. Cell Reports Physical Science, 2024, 5(2): 101783.
[54] FENG J, LI X S, TENG X, et al.Harnessing CO2 Fixation and Reducing Power Recycling for Enhanced Polyhydroxyalkanoates Industrial Bioproduction[J]. Metabolic Engineering, 2025, 91: 204-216.
[55] 冯琴霜, 张丽雪, 唐炳然, 等. 聚乳酸塑料在淡水沉积物中的降解过程[J]. 中国环境科学, 2024, 44(11): 6228-6240.
FENG Q S, ZHANG L X, TANG B R, et al.Degradation Process of Polylactic Acid Plastics in Freshwater Sediments[J]. China Environmental Science, 2024, 44(11): 6228-6240.
[56] XIA W, LIN H H, ZHOU X Y, et al.Screening of Polyurethane-Degrading Microbes Using a Quenching Fluorescence Probe by Microfluidic Droplet Sorting[J]. Chemosphere, 2024, 364: 143060.
[57] NILSSON F, ELF P, CAPEZZA A, et al.Environmental Concerns on Water-Soluble and Biodegradable Plastics and Their Applications - a Review[J]. Science of the Total Environment, 2025, 958: 177926.
[58] RODRIGUEZ N, XING F Z, GILLOR O, et al.Methodology Development: Evaluation of Structural, Thermal, and Mechanical Properties of Poly(lactic acid)/Poly(butylene adipate-co-terephthalate) Blends for Biodegradable Mulch[J]. Polymer Bulletin, 2025, 82(9): 3685-3713.
[59] XU T T, YANG J, SHAO Z J, et al.Life Cycle Assessment of Plastic Waste in Suzhou, China: Management Strategies Toward Sustainable Express Delivery[J]. Journal of Environmental Management, 2024, 360: 121201.
[60] 前瞻产业研究院. 中国生物降解塑料行业竞争格局及市场份额[R]. 深圳: 前瞻产业研究院, 2024.
QIANZHAN BUSINESS INFORMATION CO., LTD. Competition Pattern and Market Share of China's Biodegradable Plastics Industry[R]. Shenzhen: Qianzhan Business Information Co., Ltd., 2024.
[61] 黄盛, 韩东梅, 王拴紧, 等. CO2基全生物降解塑料的性能突破及产业化[J]. 同济大学学报(自然科学版), 2023, 51(11): 1663-1666.
HUANG S, HAN D M, WANG S J, et al.Performance Breakthrough and Industrialization of CO2-Based Biodegradable Plastics[J]. Journal of Tongji University (Natural Science), 2023, 51(11): 1663-1666.
[62] 荆鑫鑫, 陈高, 王宁, 等. 聚丙烯塑料在人工湿地中的降解及其对微生物群落结构的影响[J]. 湿地科学, 2024, 22(3): 428-436.
JING X X, CHEN G, WANG N, et al.Degradation of Polypropylene Plastics in Constructed Wetlands and Its Effects on Microbial Community Structure[J]. Wetland Science, 2024, 22(3): 428-436.
[63] 蒋文斌, 姜晨晨, 韦选香, 等. PET微塑料水解再造缺陷铁基金属有机框架及其应用研究[J]. 中国环境科学, 2024, 44(9): 5222-5233.
JIANG W B, JIANG C C, WEI X X, et al.Upcycling PET Microplastics via Alkaline Hydrolysis to Defective Iron Metal-Organic Frameworks for Water Treatment[J]. China Environmental Science, 2024, 44(9): 5222-5233.
[64] HUANG H L, LIU H J, CUI F C, et al.Mannich-Type Polymers: A Versatile Platform for Water-Degradable, Malleable, and Environmentally Responsive Networks[J]. Angewandte Chemie International Edition, 2025, 64(22): e202503555.
[65] LIU R J, WEI G S, YANG Y P, et al.Discovery of Potentially Degrading Microflora of Different Types of Plastics Based on Long-Term In-Situ Incubation in the Deep Sea[J]. Environmental Research, 2025, 268: 120812.
[66] KE Y J, LAN K, WONG J Y, et al.Sustainable DNA-Polysaccharide Hydrogels as Recyclable Bioplastics[J]. Nature Communications, 2025, 16: 7467.
[67] 李雪, 张建栋, 廖宇, 等. 绿色低碳概念在卷烟包装材料中的应用[J]. 包装工程, 2024, 45(5): 109-117.
LI X, ZHANG J D, LIAO Y, et al.Application of Green and Low Carbon Concept in Cigarette Packaging Materials[J]. Packaging Engineering, 2024, 45(5): 109-117.
[68] 葛林丽, 张钦发. 纸基食品包装材料的制备及其性能研究[J]. 食品科技, 2024, 49(3): 41-47.
GE L L, ZHANG Q F.Preparation and Properties of Paper-Based Food Packaging Materials[J]. Food Science and Technology, 2024, 49(3): 41-47.
[69] SHI J Y, LI T T, WU C E, et al.Paper-Based Material with Hydrophobic and Antimicrobial Properties: Advanced Packaging Materials for Food Applications[J]. Comprehensive Reviews in Food Science and Food Safety, 2024, 23(3): e13373.
[70] OLOYEDE O O, LIGNOU S.Sustainable Paper-Based Packaging: A Consumer’s Perspective[J]. Foods, 2021, 10(5): 1035-1048.
[71] YANG X X, YU L, ZHANG B W, et al.Rapidly Making Biodegradable and Recyclable Paper Plastic Based on Microwave Radiation Driven Dynamic Carbamate Chemistry[J]. Nature Communications, 2025, 16: 6523.
[72] ISOBE N, TANAKA K, ISHII S, et al. Fully Circular Shapable Transparent Paperboard with Closed-Loop Recyclability and Marine Biodegradability across Shallow to Deep Sea[J]. Science Advances, 2025, 11(15): eads2426.
[73] 陈新, 刘俊禧, 方锴, 等. 基于纸包装生物基涂层的研究进展[J]. 塑料包装, 2024, 34(4): 25-29.
CHEN X, LIU J X, FANG K, et al.Research Progress on Biobased Coating for Paper Packaging[J]. Plastics Packaging, 2024, 34(4): 25-29.
[74] TANG Y, BAN S W, XU Z H, et al.Advancements in Superhydrophobic Paper-Based Materials: A Comprehensive Review of Modification Methods and Applications[J]. Nanomaterials, 2025, 15(2): 107.
[75] JIANG M, YAO J J, GUO Q, et al.Recent Advances in Paper Conservation Using Nanocellulose and Its Composites[J]. Molecules, 2025, 30(2): 417.
[76] CHOE S, YOU S, PARK K, et al.Boric Acid-Crosslinked Poly(vinyl alcohol): Biodegradable, Biocompatible, Robust, and High-Barrier Paper Coating[J]. Green Chemistry, 2024, 26(14): 8230-8241.
[77] IWAMIYA Y, KAWAI M, NISHIO-HAMANE D, et al.Modern Alchemy: Making "Plastics" from Paper[J]. Industrial & Engineering Chemistry Research, 2021, 60(1): 355-360.
[78] YUN T T, TAO Y H, LI Q, et al.Superhydrophobic Modification of Cellulosic Paper-Based Materials: Fabrication, Properties, and Versatile Applications[J]. Carbohydrate Polymers, 2023, 305: 120570.
[79] SILVA F A G S, DOURADO F, GAMA M, et al. Nanocellulose Bio-Based Composites for Food Packaging[J]. Nanomaterials, 2020, 10(10): 2041-2056.
[80] XIONG F, ZHOU J W, JIN Y K, et al.Thermal Shock Protection with Scalable Heat-Absorbing Aerogels[J]. Nature Communications, 2024, 15: 7125.
[81] 王凤, 张亚增, 邓松林, 等. 生物基多糖的疏水改性及其在纸基材料中的应用进展[J]. 中国造纸学报, 2024, 39(3): 10-19.
WANG F, ZHANG Y Z, DENG S L, et al.Progress in Hydrophobic Modification of Bio-Based Polysaccharides and Their Application in Paper-Based Materials[J]. Transactions of China Pulp and Paper, 2024, 39(3): 10-19.
[82] 李玉磊, 南慧星, 卢家慧, 等. 纸基超疏水材料制备及应用的研究进展[J]. 包装工程, 2023, 44(1): 23-32.
LI Y L, NAN H X, LU J H, et al.Research Progress on Preparation and Application of Superhydrophobic Paper[J]. Packaging Engineering, 2023, 44(1): 23-32.
[83] 邱格, 陈港, 魏渊, 等. 基于多层涂布工艺的高阻隔透明纸基材料的制备与性能[J]. 复合材料学报, 2023, 40(3): 1484-1493.
QIU G, CHEN G, WEI Y, et al.Preparation and Performance of High-Barrier Transparent Paper-Based Materials via Multi-Coating Technology[J]. Acta Materiae Compositae Sinica, 2023, 40(3): 1484-1493.
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