Analysis Method of Volatile/Semi-volatile Odor Markers in Raw and Auxiliary Paper Printing Materials

ZHU Xiang; WANG Xuan; XU Jijun; HU Zheng; XU Wenjun

doi:10.19554/j.cnki.1001-3563.2025.23.028

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Packaging Engineering ›› 2025, Vol. 46 ›› Issue (23) : 264-271. DOI: 10.19554/j.cnki.1001-3563.2025.23.028

Automatic and Intelligent Technology

Analysis Method of Volatile/Semi-volatile Odor Markers in Raw and Auxiliary Paper Printing Materials

ZHU Xiang, WANG Xuan^*, XU Jijun, HU Zheng, XU Wenjun

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Abstract

To investigate the effect of volatile and semi-volatile constituents in raw and auxiliary paper printing materials on the odor quality of paper-based printed products, the work aims to develop an analytical method to identify odor-active components and ultimately establish key odor markers with traceability value by analyzing the correlation between characteristic odor components in raw and auxiliary materials and products. To solve the problem of inaccurate qualitative analysis in complex matrices, a triple confirmation mechanism based on deconvolution, matching degree, and retention index method was utilized to qualitatively analyze the data obtained by headspace solid-phase microextraction gas chromatography/mass spectrometry (HS-SPME-GC/MS). In semi quantitative analysis, compounds with different polarities were used as internal standards to optimize calibration strategies based on the polarity differences of the target substance. Based on the rOAV as evaluation principles, a total of 154 components were identified in three products. These compounds encompassed hydrocarbons, aldehydes, ketones, alcohols, aromatic hydrocarbons, heterocyclic compounds, esters, ethers, amines, carboxylic acids, phenols, and halogenated hydrocarbons. Subsequent intersection analysis (upset plot) highlighted benzaldehyde, nonanal, acetophenone, 2-ethyl-1-hexanol, and dodecanol as characteristic odour markers. The volatile and semi-volatile odor markers detected will provide a theoretical foundation and technical support for the odor-quality control of paper-based printed products and the selection of their raw and auxiliary materials.

Key words

raw and auxiliary paper printing materials / volatile/semi-volatile components / triple confirmation qualitative analysis / relative odor activity value / odor markers

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ZHU Xiang, WANG Xuan, XU Jijun, HU Zheng, XU Wenjun. Analysis Method of Volatile/Semi-volatile Odor Markers in Raw and Auxiliary Paper Printing Materials[J]. Packaging Engineering. 2025, 46(23): 264-271 https://doi.org/10.19554/j.cnki.1001-3563.2025.23.028

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