Preparation and Performance Study of Two Dimensional Nanofiller/Polyvinyl Alcohol Novel Moisture Blocking Coating Solution

YANG Fang; TIAN Xiao; GONG Jiahao; CAO Wen; GE Chang; WANG Haiying; CHENG Youliang; FANG Changqing

doi:10.19554/j.cnki.1001-3563.2025.17.011

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Packaging Engineering ›› 2025, Vol. 46 ›› Issue (17) : 96-105. DOI: 10.19554/j.cnki.1001-3563.2025.17.011

Preparation and Performance Study of Two Dimensional Nanofiller/Polyvinyl Alcohol Novel Moisture Blocking Coating Solution

YANG Fang¹, TIAN Xiao², GONG Jiahao¹, CAO Wen¹, GE Chang^1,*, WANG Haiying¹, CHENG Youliang^2,*, FANG Changqing²

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Abstract

The work aims to prepare a coating solution of modified montmorillonite (OMMT) and modified hexagonal boron nitride (M-h-BN) mixed with polyvinyl alcohol (PVA) using cocoamidopropyl betaine (CAB), and to investigate the influence of two-dimensional nanofiller types and ratios on properties of the composite coating solution. Modern analytical techniques such as X-ray diffractometer, Fourier transform infrared spectrophotometer, and scanning electron microscope were used to characterize and test the properties of two-dimensional filler, composite coating solution, and coated paper. After modification with MMT and h-BN, the interlayer spacing increased, and the resulting OMMT and M-h-BN exhibited good dispersibility in PVA solution. The tensile strength and elongation at break of coated paper showed a trend of first increasing and then decreasing with the increase of filler content. When the content of OMMT/M-h-BN composite filler was 4 wt.%, the maximum tensile strength and elongation at break of the coated paper were 35.35 MPa and 108.03%. The 24 h moisture permeability of 4 wt.% OMMT/M-h-BN/PVA coated paper was only 22 g/(m²·d), which was 63% lower than that of pure PVA. The moisture absorption and release rates of OMMT/ M-h-BN/PVA coated paper remained stable at 3.77% and 2.71%, respectively, while they were 48% and 54.5% lower than those of pure PVA. In conclusion, the appropriate addition of OMMT and M-h-BN can significantly improve the tensile strength, elongation at break, and moisture resistance of coated paper. At the same time, composite filler, due to the synergistic effect of OMMT and M-h-BN, can more effectively enhance the comprehensive performance of coated paper compared with single filler.

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cocoamide propyl betaine / organic montmorillonite / hexagonal boron nitride / composite filler

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YANG Fang, TIAN Xiao, GONG Jiahao, CAO Wen, GE Chang, WANG Haiying, CHENG Youliang, FANG Changqing. Preparation and Performance Study of Two Dimensional Nanofiller/Polyvinyl Alcohol Novel Moisture Blocking Coating Solution[J]. Packaging Engineering. 2025, 46(17): 96-105 https://doi.org/10.19554/j.cnki.1001-3563.2025.17.011

References

[1] ZHANG S S, SUN P H, LIN X Y, et al.Strong, High Barrier, Water- and Oil-Resistant Cellulose Paper-Based Packaging Material Enabled by Polyvinyl Alcohol-Bentonite Coordination Interactions[J]. International Journal of Biological Macromolecules, 2025, 285: 138076.
[2] SHAH Y A, BHATIA S, AL-HARRASI A, et al.Insights into Recent Innovations in Barrier Resistance of Edible Films for Food Packaging Applications[J]. International Journal of Biological Macromolecules, 2024, 271: 132354.
[3] ANSARI J R, PARK K, SEO J.Improving the Oxygen Barrier Properties of Composite Films Using Green Tea Extracted CQDS and PVA for Active Packaging Applications[J]. Food Packaging and Shelf Life, 2025, 48: 101460.
[4] KWON H J, HONG S M, PARK S M, et al.Characterization of Acid-Modified Polyvinyl Alcohol and Its Application to Barrier-Coated Paper for Eco-Friendly Food Packaging[J]. Food Packaging and Shelf Life, 2024, 43: 101271.
[5] ALATEYAH A I, DHAKAL H N, ZHANG Z Y. Processing, Properties,Applications of Polymer Nanocomposites Based on Layer Silicates: A Review[J]. Advances in Polymer Technology, 2013, 32(4): 5153-5162.
[6] 王鑫, 逄增媛, 徐阳. 聚乙烯醇/有机蒙脱土/硼酸气体阻隔复合膜的制备及性能[J]. 高分子材料科学与工程, 2023, 39(12): 64-70.
WANG X, PANG Z Y, XU Y.Preparation and Properties of Polyvinyl Alcohol/Organic Montmorillonite/Boric Acid Modified Gas Barrier Composite Films[J]. Polymer Materials Science & Engineering, 2023, 39(12): 64-70.
[7] 孙艳美, 马海霞, 陈丽莉, 等. 防水卷材用隔离包装膜的制备及应用研究[J]. 化工新型材料, 2024, 52(4): 249-253.
SUN Y M, MA H X, CHEN L L, et al.Study on Preparation and Application of Isolation Packaging Film for Waterproof Roll[J]. New Chemical Materials, 2024, 52(4): 249-253.
[8] DEBELI D K, WU L B, JIE S Y.Sulfonated PBAT/ OMMT Nanocomposite Films with High Transparency, High Oxygen Barrier Performance and Well-Balanced Mechanical Properties at High OMMT Loading[J]. Polymer Degradation and Stability, 2025, 233: 111186.
[9] HUANG H D, REN P G, ZHONG G J, et al.Promising Strategies and New Opportunities for High Barrier Polymer Packaging Films[J]. Progress in Polymer Science, 2023, 144: 101722.
[10] DAI D D, HUANG Y Q, SUN L, et al.Oxygen Barrier Properties of Organic Montmorillonite Modified Polyamide 11/Poly(vinyl alcohol) Films[J]. Polymers for Advanced Technologies, 2021, 32(1): 165-172.
[11] 孙萌萌, 浦敏锋, 曹灿, 等. 蒙脱石有机化对PVA/蒙脱石复合薄膜的性能影响[J]. 广州化工, 2010, 38(12): 100-101.
SUN M M, PU M F, CAO C, et al.Effects of Organic Modification of MMT on the Properties of Poly(vinyl alcohol)/Montmorillonite Nanocomposites Films[J]. Guangzhou Chemical Industry, 2010, 38(12): 100-101.
[12] PUNIA B S, WHITESIDE W S, CHAUDHARY V, et al.Recent Functionality Developments in Montmorillonite as a Nanofiller in Food Packaging[J]. Trends in Food Science & Technology, 2023, 140: 104148.
[13] WANG W, WU L M, CHANG L, et al.Functionality Developments in Montmorillonite Nanosheet: Properties, Preparation, and Applications[J]. Chemical Engineering Journal, 2024, 499: 156186.
[14] 赵冠之, 马睿婕, 殷允杰. 基于羟基化六方氮化硼的导热聚氨酯涂层[J]. 涂料工业, 2024, 54(12): 17-24.
ZHAO G Z, MA R J, YIN Y J.Thermal Conductive Polyurethane Coating Based on Hydroxylated Hexagonal Boron Nitride[J]. Paint & Coatings Industry, 2024, 54(12): 17-24.
[15] CHENG Y K, OBATA S, NISHINA Y.Ball Mill Enhances the Functionalization of Boron Nitride: The Application for Polyimide Fillers[J]. FlatChem, 2023, 39: 100489.
[16] KIM J, KIM Y, NGOME OKELLO O F, et al. Structural Evolution of Hexagonal Boron Nitride Powder by Bead-Milling[J]. Materials Letters, 2021, 300: 130118.
[17] SUGANTHI S, MOHANAPRIYA S, RAJ V, et al.Tunable Physicochemical and Bactericidal Activity of Multicarboxylic-Acids-Crosslinked Polyvinyl Alcohol Membrane for Food Packaging Applications[J]. ChemistrySelect, 2018, 3(40): 11167-11176.
[18] 邓加云, 彭强, 林文龙, 等. 改性氮化硼复合材料涂层制备高阻隔导热内衬纸[J]. 包装工程, 2024, 45(17): 105-110.
DENG J Y, PENG Q, LIN W L, et al.Preparation of High Barrier and Thermal Conductive Lining Paper for Packaging by Modified Boron Nitride[J]. Packaging Engineering, 2024, 45(17): 105-110.
[19] 张勇, 杨福馨, 户帅锋, 等. 聚乙烯醇/蒙脱土纳米复合薄膜的制备与性能研究[J]. 功能材料, 2015, 46(11): 11144-11147.
ZHANG Y, YANG F X, HU S F, et al.Preparation and Properties of Montmorillonoid/Polyvinyl Alcohol Nanocomposite Films[J]. Journal of Functional Materials, 2015, 46(11): 11144-11147.
[20] 李尧, 张雪, 张红杰, 等. 不同多羟基聚合物涂层对涂布纸吸放湿性能和调湿能力的影响研究[J]. 中国造纸, 2024, 43(6): 96-107.
LI Y, ZHANG X, ZHANG H J, et al.Study on the Influence of Different Hydroxy-Based Polymer Coatings on the Moisture Absorption/Desorption Properties and Humidity Control Capability of Coated Paper[J]. China Pulp & Paper, 2024, 43(6): 96-107.