Determination of Migration of 14 Ultraviolet Absorbers in Olive Oil Simulant

SHI Honglan; WENG Jianglai; GOU Xinlei; ZHU Xiaoyan; ZHANG Mei; TONG Jiaqi

doi:10.19554/j.cnki.1001-3563.2025.15.013

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Packaging Engineering ›› 2025, Vol. 46 ›› Issue (15) : 122-131. DOI: 10.19554/j.cnki.1001-3563.2025.15.013

Special Topic on Safety and Detection of Food Contact Materials

Determination of Migration of 14 Ultraviolet Absorbers in Olive Oil Simulant

SHI Honglan², WENG Jianglai², GOU Xinlei³, ZHU Xiaoyan¹, ZHANG Mei³, TONG Jiaqi^1*

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Abstract

The work aims to determine the migration of 14 ultraviolet absorbers from food contact materials and articles into olive oil simulant based on liquid chromatography-tandem mass spectrometry (LC-MS/MS). UV-71, UV-326, UV-327, UV-328, UV-329 and UV-360 in the olive oil were diluted with tetrahydrofuran. UV-3030, UV-3035, UV-3039, UV-312 and UV-3638 were extracted with acetonitrile and cleaned up by C18 solid-phase extraction column. UV-234, UV-1164 and UV-1577 were extracted with hexane after saponification, and cleaned up by silica solid-phase extraction column. The separation was carried out on a C18 column selected for gradient elution with methanol and aqueous solution containing formic acid and ammonium formate as mobile phases. The analytes were detected by triple quadrupole tandem mass spectrometry and quantified by external standard method. The correlation coefficients of the 14 target compounds reached more than 0.998 in the linear range of 0.005-0.10 mg/L. The limits of detection for eight UV absorbers were up to 0.001 5 mg/kg, and the limits of quantification were up to 0.005 mg/kg and those for six UV absorbers were up to 3 mg/kg and 10 mg/kg, respectively. The recoveries ranged from 85.9% to 108.1% at 3 different concentrations, with the relative standard deviations no more than 9.5%. The method is sensitive, accurate and can be used for the determination of the migration of 14 ultraviolet absorbers in olive oil.

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food contact materials and articles / olive oil / liquid chromatography-tandem mass spectrometry / ultraviolet absorbers / migration

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SHI Honglan, WENG Jianglai, GOU Xinlei, ZHU Xiaoyan, ZHANG Mei, TONG Jiaqi. Determination of Migration of 14 Ultraviolet Absorbers in Olive Oil Simulant[J]. Packaging Engineering. 2025, 46(15): 122-131 https://doi.org/10.19554/j.cnki.1001-3563.2025.15.013

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