Hot Pressing Preparation and Properties of Chitosan/Deep Eutectic Solvent Composite Films

GAO Yuying, FAN Min, CHENG Xiaoxiao, LI Li

Packaging Engineering ›› 2025, Vol. 46 ›› Issue (15) : 93-99.

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Packaging Engineering ›› 2025, Vol. 46 ›› Issue (15) : 93-99. DOI: 10.19554/j.cnki.1001-3563.2025.15.010
Special Topic on Sustainable Packaging Technology Innovation and Industrial Development

Hot Pressing Preparation and Properties of Chitosan/Deep Eutectic Solvent Composite Films

  • GAO Yuying, FAN Min, CHENG Xiaoxiao, LI Li*
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Abstract

The work aims to investigate the effect of different DES on film properties by doping chitosan powder with different components of deep eutectic solvent (DES) and preparing heat-sealable chitosan films through hot pressing. Four DES, choline chloride/citric acid, choline chloride/lactic acid, betaine/citric acid, and betaine/lactic acid, were prepared, and four chitosan films were prepared by hot pressing after proportional blending of chitosan with each of the four types of DES. The effects of DES composition on film properties were evaluated in terms of heat sealing properties, mechanical properties, water barrier properties, and optical properties of the films. The properties of the films prepared from different DES and chitosan films varied greatly, with the citrate-based DES films exhibiting higher tensile strength (22.83 MPa) and heat sealing strength ((3.54±0.26)N/15 mm), while the lactate-based DES films were more flexible (elongation at break 75.30%), had higher light transmission, but had weak heat sealing properties. In conclusion, the components of DES affect the performance of the films, and the films prepared by hot pressing of choline chloride-citric acid DES with chitosan show better tensile properties and heat sealing properties, which provides a new strategy for the green and functional design of bio-based packaging materials.

Key words

chitosan / deep eutectic solvent / hot pressing / heat sealing property

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GAO Yuying, FAN Min, CHENG Xiaoxiao, LI Li. Hot Pressing Preparation and Properties of Chitosan/Deep Eutectic Solvent Composite Films[J]. Packaging Engineering. 2025, 46(15): 93-99 https://doi.org/10.19554/j.cnki.1001-3563.2025.15.010

References

[1] MENG Q Y, ZHONG S L, WANG J, et al.Advances in Chitosan-Based Microcapsules and Their Applications[J]. Carbohydrate Polymers, 2023, 300: 120265.
[2] NEGM N A, HEFNI H H H, ABD-ELAAL A A A, et al. Advancement on Modification of Chitosan Biopolymer and Its Potential Applications[J]. International Journal of Biological Macromolecules, 2020, 152: 681-702.
[3] GAO Y Y, FAN M, CHENG X X, et al.Deep Eutectic Solvent: Synthesis, Classification, Properties and Application in Macromolecular Substances[J]. International Journal of Biological Macromolecules, 2024, 278: 134593.
[4] ALMEIDA C M R, MAGALHÃES J M C S, SOUZA H K S, et al. The Role of Choline Chloride-Based Deep Eutectic Solvent and Curcumin on Chitosan Films Properties[J]. Food Hydrocolloids, 2018, 81: 456-466.
[5] YU J H, XU S L, GOKSEN G, et al.Chitosan Films Plasticized with Choline-Based Deep Eutectic Solvents: UV Shielding, Antioxidant, and Antibacterial Properties[J]. Food Hydrocolloids, 2023, 135: 108196.
[6] SMIRNOV M A, NIKOLAEVA A L, BOBROVA N V, et al.Self-Healing Films Based on Chitosan Containing Citric Acid/Choline Chloride Deep Eutectic Solvent[J]. Polymer Testing, 2021, 97: 107156.
[7] GALVIS-SÁNCHEZ A C, CASTRO M C R, BIERNACKI K, et al. Natural Deep Eutectic Solvents as Green Plasticizers for Chitosan Thermoplastic Production with Controlled/Desired Mechanical and Barrier Properties[J]. Food Hydrocolloids, 2018, 82: 478-489.
[8] ZHANG W, SHEN J D, GAO P, et al.Sustainable Chitosan Films Containing a Betaine-Based Deep Eutectic Solvent and Lignin: Physicochemical, Antioxidant, and Antimicrobial Properties[J]. Food Hydrocolloids, 2022, 129: 107656.
[9] MOHD F F, MOHD N M.The Formulation and Physicochemical Properties of Betaine-Based Natural Deep Eutectic Solvent[J]. Journal of Molecular Liquids, 2022, 360: 119392.
[10] HU Y, WANG Z X, LIANG P Y, et al.Exploring the Molecular Mechanisms of Isoliquiritin Extraction Using Choline Chloride-Citric Acid Deep Eutectic Solvents[J]. Sustainable Chemistry and Pharmacy, 2023, 33: 101099.
[11] LI Y, CHEN K N, YANG Q F, et al.Development and Characterization of Novel Antioxidant Films Based on Chitosan and Maillard Reaction Products[J]. LWT, 2021, 141: 110886.
[12] JIANG G Y, HE K W, CHEN M R, et al.Development of Multifunctional Chitosan Packaging Film by Plasticizing Novel Essential Oil-Based Hydrophobic Deep Eutectic Solvent: Structure, Properties, and Application[J]. Carbohydrate Polymers, 2025, 347: 122701.
[13] LIM W S, OCK S Y, PARK G D, et al.Heat-Sealing Property of Cassava Starch Film Plasticized with Glycerol and Sorbitol[J]. Food Packaging and Shelf Life, 2020, 26: 100556.
[14] ALVES Z, FERREIRA N M, FERREIRA P, et al.Design of Heat Sealable Starch-Chitosan Bioplastics Reinforced with Reduced Graphene Oxide for Active Food Packaging[J]. Carbohydrate Polymers, 2022, 291: 119517.
[15] LI C C, ZHENG C J, HUANG H H, et al.Preparation and Plasticizing Mechanism of Deep Eutectic Solvent/Lignin Plasticized Chitosan Films[J]. International Journal of Biological Macromolecules, 2023, 240: 124473.
[16] YU J H, XU S L, CHEN R H, et al.A Promising Bioactive Chitosan Film in Strawberry Fresh-Keeping: Plasticized with Tomato Processing By-Product Extract of Deep Eutectic Solvent[J]. Food Hydrocolloids, 2024, 151: 109859.
[17] JIANG G Y, HE K W, CHEN M R, et al.Improvement of Mechanical and Bioactive Properties of Chitosan Films Plasticized with Novel Thymol-Based Deep Eutectic Solvents[J]. Food Hydrocolloids, 2025, 158: 110480.
[18] WEN H T, TANG D B, LIN Y S, et al.Enhancement of Water Barrier and Antimicrobial Properties of Chitosan/Gelatin Films by Hydrophobic Deep Eutectic Solvent[J]. Carbohydrate Polymers, 2023, 303: 120435.
[19] ZHAO P Q, WANG J D, YAN X Y, et al.Functional Chitosan/Zein Films with Rosa Roxburghii Tratt Leaves Extracts Prepared by Natural Deep Eutectic Solvents[J]. Food Packaging and Shelf Life, 2022, 34: 101001.
[20] ROLIŃSKA K, JAKUBOWSKA E, ŻMIEŃKO M, et al. Choline Chloride-Based Deep Eutectic Solvents as Plasticizer and Active Agent in Chitosan Films[J]. Food Chemistry, 2024, 444: 138375.
[21] JAKUBOWSKA E, GIERSZEWSKA M, NOWACZYK J, et al.The Role of a Deep Eutectic Solvent in Changes of Physicochemical and Antioxidative Properties of Chitosan-Based Films[J]. Carbohydrate Polymers, 2021, 255: 117527.
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