The work aims to employ scientific analysis methods to provide decision-making reference for degradable films selection and packaging process upgradation in tobacco commercial logistics with consideration to environmental impact and economic benefits. Based on the matching of film mechanical properties and packaging ways, the environmental performance measurement and redundancy analysis of degradable film packaging were carried out with a non-radial and non-angular SBM-DEA model based on relaxation measurement, using the environmental impact potential via life cycle inventory and related economic indicators as basic data. The results indicated that three packing manners were determined for eight kinds of degradable films according to mechanical properties. The total environmental impact potential of different packaging films followed a descending order of C, D, E, LDPE, A, B, G, F and H. In addition, the wrapping packaging I of film A and wrapping packaging I of film G were preferable with effective environmental performance. It is concluded that life cycle environmental impact assessment contributes to a comprehensive analysis of the environmental friendliness of degradable films. Wrapping packaging of degradable films has outstanding environmental performance advantages. The upgrading of packing technology and the enhancement of packaging efficiency are the starting points to improve environmental performance of degradable film packaging.