In order to enhance the antistatic performance of Poly (3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBH) packaging film and broaden the application in packaging field, RGO/PHBH packaging film was prepared by the reduction of graphene oxide using ascorbic acid (Vc). The structure and properties of the reduced packaging film were tested. The results showed that the oxygen transmittance of RGO/PHBH packaging film could reach 20 cm3/(cm2.d.Pa). And the UV transmittance was less than 40%. More importantly, the surface resistivity decreased from 29 GΩ to 0.25 MΩ, which proved the excellent antistatic electricity of RGO/PHBH packaging film.