The work aims to study the effects of the abrasion-proof additive (polyethylene wax) on the performances of non-benzene gravure ink and discuss the effects of the mass fraction of polyethylene wax on the wear resistance of ink film and the adhesion of QR code. The gravure white ink was prepared by changing the amount of polyethylene wax used in non-benzene gravure white ink, and the printed samples were prepared to test the wear resistance and adhesion of QR code. The results showed that the wear resistance of the ink film could be improved by polyethylene wax, while the adhesion of the ink film and QR code would decrease when the mass fraction of polyethylene wax exceeded 3%. The wear resistance of the ink prints prepared and the adhesion of UV QR code had the best overall performance when the mass fraction of polyethylene wax was 2%. The non-benzene gravure ink which has good wear resistance of ink film and QR code adhesion can be obtained by controlling the mass fraction of polyethylene wax.