Paper, PE and Al separated from pillow Tetra Pak with formic acid was taken as raw materials. TG-FTIR analysis technique was applied to study the characteristic of single component pyrogenation product and copyrolysis mechanism of multiple components. The results showed that there is synergism between paper and PE during copyrolysis, especially near the weight loss peak; aluminum has the function of catalyst during copyrolysis, which promotes PE pyrogenation. The purpose was to provide reference for resource utilization of waste paper-PE-Al composite packaging material.