紫外荧光剂Eu-xGd-(1-x)(BZA)-3Phen发光性质及机理研究

孟 婕, 孙 诚, 柴三中, 王建清

包装工程(技术栏目) ›› 2012 ›› Issue (19) : 108-112116.

包装工程(技术栏目) ›› 2012 ›› Issue (19) : 108-112116.

紫外荧光剂Eu-xGd-(1-x)(BZA)-3Phen发光性质及机理研究

  • 孟 婕1, 孙 诚1, 柴三中1, 王建清2
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Luminescent Properties and Mechanism of UV Fluorescent Agent Eu-xGd-(1-x)(BZA)-3Phen

  • MENG Jie1, SUN Cheng1, CHAI San-zhong1, WANG Jian-qing2
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摘要

选用β-二酮配体苯甲酰丙酮(BZA)作为第一配体,再选用适当的协同配体邻菲咯啉(Phen),掺杂惰性稀土离子钆(Gd3+),合成了Eu-xGd-(1-x)(BZA)-3Phen红色荧光剂。通过元素组成、红外光谱、紫外光谱、热性能、荧光性能对其进行了表征,并研究了该掺杂配合物体系的发光机理,利用分子间能量传递模式解释了惰性稀土离子对Eu-xGd-(1-x)(BZA)-3Phen的“共发光效应”。结果表明,这是一类性能优良、成本较低的铕配合物。

Abstract

Red fluorescent agent Eu-xGd-(1-x)(BZA)-3Phen were synthesized by using low cost, good stability β-diketones ligands benzoylacetone (BZA) as the first ligand, and phenanthroline (Phen) as appropriate synergistic ligand, and doped inert rare earth ions gadolinium(Gd3+). The agent was characterized by elemental composition, IR, UV spectra, thermal properties, and fluorescence properties. The light-emitting mechanism of doped complex was studied. The inert rare earth ions co-fluorescence effect on Eu-xGd-(1-x)(BZA)-3Phen was explained by intermolecular energy transfer model. The results showed that this is an excellent performance and low cost europium complex.

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孟 婕, 孙 诚, 柴三中, 王建清. 紫外荧光剂Eu-xGd-(1-x)(BZA)-3Phen发光性质及机理研究[J]. 包装工程(技术栏目). 2012(19): 108-112116
MENG Jie, SUN Cheng, CHAI San-zhong, WANG Jian-qing. Luminescent Properties and Mechanism of UV Fluorescent Agent Eu-xGd-(1-x)(BZA)-3Phen[J]. Packaging Engineering. 2012(19): 108-112116

基金

天津自然科学基金项目(09JCYBJC02700)

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