摘要
采用双螺杆挤出机液体进料工艺,制备了聚乳酸/柠檬酸三丁酯(PLA/TBC)固-液共混材料,表征了其性能。结果表明:双螺杆挤出机液体进料工艺能够精确控制TBC在PLA中的质量分数;傅里叶红外光谱仪微观结构表征了2877 cm-1特征峰的出现、羟基伸缩振动峰红移,证明TBC对PLA起到了增塑作用;当TBC含量为16%(质量分数)时共混材料从脆性材料转变为韧性材料;降解实验显示,这种共混薄膜在6个月内性能基本消失,轻微受力时薄膜粉碎。
Abstract
PLA/TBC solid-liquid blend materials were prepared through liquid feeding process in twin-screw extruder and its performance was characterized. Test results showed that the twin-screw extruder liquid feeding process can precisely control the mass fraction of the PLA in TBC score. 2877 cm-1 the characteristic peak and the emergence of —OH telescopic vibrating peaks red-shift was founded in FT-IR spectrometer inspection, which proved that TBC has the plastic role; when TBC content w=16%, its mechanical performance of materials change from brittle into ductile material; through the degradation test, the mechanical properties of PLA/TBC blend materials disappearance within 180 days and the film changes into pieces form by slightly power.
张 伟, 刘 菲.
聚乳酸/柠檬酸三丁酯固-液共混材料的制备与性能研究[J]. 包装工程(技术栏目). 2012(17): 15-18
ZHANG Wei, LIU Fei.
Preparation and Characterization of Polylactide Acid/Tributyl Citrate Solid-liquid Blend Materials[J]. Packaging Engineering. 2012(17): 15-18
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