Paper, PE and Al were separated from pillow Tetra Pak with formic acid and used as materials for experiment. TG-FTIR analysis technique was applied to study the synergism of components during pyrogenation process, so as to understand the co-pyrolysis behavior, which will provide an experimental basis and scientific reference to achieve resource utilization of abandon Tetra Pak. The results showed that there is synergism between paper and PE during co-pyrolysis, especially near the decomposing peak; the aluminum promotes and restrains the reaction in different stage of co-pyrolysis as catalyst.