混合多元醇对无溶剂聚氨酯覆膜胶性能的影响

陈双莲, 陈广学, 陈奇峰, 贾春江, 王 青

包装工程(技术栏目) ›› 2012 ›› Issue (7) : 40-43.

包装工程(技术栏目) ›› 2012 ›› Issue (7) : 40-43.

混合多元醇对无溶剂聚氨酯覆膜胶性能的影响

  • 陈双莲, 陈广学, 陈奇峰, 贾春江, 王 青
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Effects of Mixed-polyols on Properties of Solvent-free Polyurethane Laminating Adhesives

  • CHEN Shuang-lian, CHEN Guang-xue, CHEN Qi-feng, JIA Chun-jiang, WANG Qing
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摘要

以聚己二酸-1,4-丁二醇酯(PBA)、植物油多元醇、异弗尔酮二异氰酸酯(IPDI)和小分子多元醇为主要原料,制备了一种双组分无溶剂型聚氨酯胶粘剂。研究了双组分的配比R′和混合多元醇组分对聚氨酯胶粘剂固化速率、固化后胶膜的热稳定性和吸水率的影响,并测试了覆膜样品的T剥离强度。结果表明:当双组分配比R′=1.3时,胶粘剂综合性能最佳;添加小分子多元醇并不能提高胶粘剂的固化速率和耐热性,但能显著改善胶粘剂的粘结性能,并且选择性添加适量的小分子二醇,还能增强其耐水性。

Abstract

Two-component solvent-free polyurethane adhesive was prepared with PBA, vegetable oil polyols, IPDI and several different small molecular alcohols as main raw materials. The influences of two-components ratio R′ and mixed polyols components on curing speed, heat resistance, water absorption, and T-peel strength were studied. The results showed that the adhesives showed the best comprehensive properties when the two-components ratio R′ is 1.3; addition of small molecular alcohols can not increase the curing speed and heat resistance, however, it can significantly improve the peel strength of the adhesive; adding appropriate amount of small molecules alcohols selectively can enhance its water resistance.

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陈双莲, 陈广学, 陈奇峰, 贾春江, 王 青. 混合多元醇对无溶剂聚氨酯覆膜胶性能的影响[J]. 包装工程(技术栏目). 2012(7): 40-43
CHEN Shuang-lian, CHEN Guang-xue, CHEN Qi-feng, JIA Chun-jiang, WANG Qing. Effects of Mixed-polyols on Properties of Solvent-free Polyurethane Laminating Adhesives[J]. Packaging Engineering. 2012(7): 40-43

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