针对多糖生物基薄膜在食品包装实际使用过程中,尤其是在高湿或含水环境下易发生力学性能衰减的问题,系统梳理了其力学失稳原因及稳定性调控策略。围绕高湿环境、食品接触、热封处理、弯折变形、搬运挤压及储藏老化等实际使用条件,综述了纤维素、海藻酸盐、壳聚糖、淀粉和卡拉胶等典型多糖基薄膜的结构特征、力学性能变化规律、失稳表现及增强改性方法。糖基薄膜在高湿或含水条件下普遍存在力学性能衰减现象,表现为强度降低、模量下降或韧性变化。其力学稳定性受分子链间相互作用、水分塑化效应、膜层结构完整性、组分界面结合状态及亲水性差异等因素共同影响。化学改性、聚合物共混、纳米填料增强、复合结构设计及加工工艺调控等策略,可通过增强链间约束、优化界面结合、提高膜层致密性并降低水分敏感性,从而延缓力学性能衰减并提高薄膜的力学稳定性。目前,多糖生物基薄膜在食品包装应用中仍面临湿态力学性能保持能力不足、多性能协同调控困难,以及真实包装环境下力学稳定性评价不足等问题。因此,建立面向食品包装高湿、接触及储藏等典型应用环境的力学稳定性评价方法,阐明湿态条件下多糖基薄膜力学性能衰减规律及其调控机制,是提高其包装适用性的重要方向。
Abstract
The work aims to systematically review the causes of mechanical instability and regulation strategies of polysaccharide bio-based films, which are prone to mechanical performance degradation during practical food packaging use, especially in high-humidity or aqueous environments. With consideration of practical use conditions such as high humidity, food contact, heat sealing, bending deformation, handling compression, and storage aging, the structural characteristics, variations in mechanical properties, instability behaviors, and reinforcement modification methods of typical polysaccharide-based films, including cellulose-, alginate-, chitosan-, starch-, and carrageenan-based films, were reviewed. The results showed that polysaccharide-based films generally exhibited mechanical performance degradation under high-humidity or aqueous conditions, mainly manifested as decreased strength, reduced modulus, or changes in toughness. Their mechanical stability was jointly affected by interchain interactions, water plasticization, film structural integrity, interfacial bonding between components, and differences in hydrophilicity. Strategies such as chemical modification, polymer blending, nanofiller reinforcement, composite structural design, and processing regulation could strengthen interchain constraints, optimize interfacial bonding, improve film compactness, and reduce moisture sensitivity, thereby delaying mechanical performance degradation and improving the mechanical stability of the films. At present, polysaccharide bio-based films still face problems in food packaging applications, including insufficient retention of wet-state mechanical properties, difficulty in coordinating multiple properties, and inadequate evaluation of mechanical stability in real packaging environments. Therefore, establishing mechanical stability evaluation methods for typical food packaging application environments involving high humidity, contact, and storage, and clarifying the degradation rules and regulation mechanisms of polysaccharide-based films under wet conditions are important directions for improving their packaging applicability.
关键词
多糖基薄膜 /
食品包装 /
力学稳定性 /
增强改性
Key words
polysaccharide-based film /
food packaging /
mechanical stability /
reinforcement modification
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参考文献
[1] XUE W H, ZHU J X, SUN P D, et al.Permeability of Biodegradable Film Comprising Biopolymers Derived from Marine Origin for Food Packaging Application: A Review[J]. Trends in Food Science & Technology, 2023, 136: 295-307.
[2] LONG J Y, ZHANG W Y, ZHAO M Z, et al.The Reduce of Water Vapor Permeability of Polysaccharide-Based Films in Food Packaging: A Comprehensive Review[J]. Carbohydrate Polymers, 2023, 321: 121267.
[3] JANIK W, JAKUBSKI Ł, KUDŁA S, et al. Modified Polysaccharides for Food Packaging Applications: A Review[J]. International Journal of Biological Macromolecules, 2024, 258: 128916.
[4] 韩春然, 杨鑫, 修伟业, 等. 多糖类可食膜的研究进展[J]. 包装工程, 2025, 46(9): 43-51.
HAN C R, YANG X, XIU W Y, et al.Research Progress of Polysaccharide Edible Films[J]. Packaging Engineering, 2025, 46(9): 43-51.
[5] YAO Q B, HUANG F, LU Y H, et al.Polysaccharide-Based Food Packaging and Intelligent Packaging Applications: A Comprehensive Review[J]. Trends in Food Science & Technology, 2024, 147: 104390.
[6] ROY S, MALIK B, CHAWLA R, et al.Biocompatible Film Based on Protein/Polysaccharides Combination for Food Packaging Applications: A Comprehensive Review[J]. International Journal of Biological Macromolecules, 2024, 278: 134658.
[7] RAMAKRISHNAN R, KIM J T, ROY S, et al.Recent Advances in Carboxymethyl Cellulose-Based Active and Intelligent Packaging Materials: A Comprehensive Review[J]. International Journal of Biological Macromolecules, 2024, 259: 129194.
[8] AHANKARI S S, SUBHEDAR A R, BHADAURIA S S, et al.Nanocellulose in Food Packaging: A Review[J]. Carbohydrate Polymers, 2021, 255: 117479.
[9] 徐玉洁, 梁旭茹, 黄文艺, 等. 植物纤维素基阻隔性改性材料在食品包装上的应用研究进展[J]. 食品科学, 2024, 45(17): 306-315.
XU Y J, LIANG X R, HUANG W Y, et al.Application of Plant Cellulose-Based Materials with Improved Barrier Property in Food Packaging[J]. Food Science, 2024, 45(17): 306-315.
[10] SHEN Y H, SEIDI F, AHMAD M, et al.Recent Advances in Functional Cellulose-Based Films with Antimicrobial and Antioxidant Properties for Food Packaging[J]. Journal of Agricultural and Food Chemistry, 2023, 71(44): 16469-16487.
[11] SENTURK PARREIDT T, MÜLLER K, SCHMID M. Alginate-Based Edible Films and Coatings for Food Packaging Applications[J]. Foods, 2018, 7(10): 170.
[12] LI H, WANG Z J, ZHU F, et al.Alginate-Based Active and Intelligent Packaging: Preparation, Properties, and Applications[J]. International Journal of Biological Macromolecules, 2024, 279: 135441.
[13] 吕瑞, 陈菊, 矫芮文, 等. 海藻酸钠包装膜的性能提升研究进展[J]. 食品安全质量检测学报, 2024, 15(15): 72-82.
LYU R, CHEN J, JIAO R W, et al.Research Progress on the Performance Improvement of Sodium Alginate Packaging Film[J]. Journal of Food Safety & Quality, 2024, 15(15): 72-82.
[14] JIN J, LUO B D, XUAN S M, et al.Degradable Chitosan-Based Bioplastic Packaging: Design, Preparation and Applications[J]. International Journal of Biological Macromolecules, 2024, 266: 131253.
[15] SABERI RISEH R, VATANKHAH M, HASSANISAADI M, et al.Chitosan-Based Nanocomposites as Coatings and Packaging Materials for the Postharvest Improvement of Agricultural Product: A Review[J]. Carbohydrate Polymers, 2023, 309: 120666.
[16] PEI J J, PALANISAMY C P, SRINIVASAN G P, et al.A Comprehensive Review on Starch-Based Sustainable Edible Films Loaded with Bioactive Components for Food Packaging[J]. International Journal of Biological Macromolecules, 2024, 274: 133332.
[17] SABU MATHEW S, JAISWAL A K, JAISWAL S.Carrageenan-Based Sustainable Biomaterials for Intelligent Food Packaging: A Review[J]. Carbohydrate Polymers, 2024, 342: 122267.
[18] XIE H Y, LI S T, TIAN H H, et al.Modifying Polysaccharides to Realized Advanced Function of Novel Food Packaging Materials[J]. Trends in Food Science & Technology, 2025, 163: 105195.
[19] WANG B, WANG X Z, MA H X, et al.Enhancing the Mechanical and Barrier Properties of Starch-Based Green Packaging Films via Acetalization Reaction and Hydrogen Bond Dual Crosslinking[J]. Carbohydrate Polymers, 2025, 364: 123787.
[20] YU J, XU X B, ZHUANG Z C, et al.Double-Crosslinked Polyvinyl Alcohol/Starch Bioplastic with Superior Water-Resistance and Flame Retardancy[J]. International Journal of Biological Macromolecules, 2024, 281: 136139.
[21] AROOJ A, KHAN M, MUNAWAR K S.Preparation and Physicochemical Characterization of Starch/Pectin and Chitosan Blend Bioplastic Films as Future Food Packaging Materials[J]. Journal of Environmental Chemical Engineering, 2024, 12(1): 111825.
[22] ZHOU Y F, LIU R Q, ZHOU C M, et al.Dynamically Crosslinked Chitosan/Cellulose Nanofiber-Based Films Integrated with γ-Cyclodextrin/Curcumin Inclusion Complex as Multifunctional Packaging Materials for Perishable Fruit[J]. Food Hydrocolloids, 2023, 144: 108996.
[23] YU J H, XU S L, GOKSEN G, et al.Chitosan Films Plasticized with Choline-Based Deep Eutectic Solvents: UV Shielding, Antioxidant, and Antibacterial Properties[J]. Food Hydrocolloids, 2023, 135: 108196.
[24] CUI T Q, WU Y, NI C L, et al.Rheology and Texture Analysis of Gelatin/Dialdehyde Starch Hydrogel Carriers for Curcumin Controlled Release[J]. Carbohydrate Polymers, 2022, 283: 119154.
[25] LIANG W, ZHENG J Y, SALEH A S M, et al. Fabrication of Biodegradable Blend Plastic from Konjac Glucomannan/Zein/PVA and Understanding Its Multi-Scale Structure and Physicochemical Properties[J]. International Journal of Biological Macromolecules, 2023, 225: 172-184.
[26] LIU X Z, XU F F, YONG H M, et al.Recent Advances in Chitosan-Based Active and Intelligent Packaging Films Incorporated with Flavonoids[J]. Food Chemistry: X, 2025, 25: 102200.
[27] RASHID A, LI M Y, GAO S, et al.Starch-Based Food Packaging Films from Fundamental Challenges to Intelligent Applications[J]. Food Chemistry, 2026, 515: 149279.
[28] WEI H N, LIU X Y, WANG C C, et al.Characteristics of Corn Starch/Polyvinyl Alcohol Composite Film with Improved Flexibility and UV Shielding Ability by Novel Approach Combining Chemical Cross-Linking and Physical Blending[J]. Food Chemistry, 2024, 456: 140051.
[29] ASHRAF J, ISMAIL N, TUFAIL T, et al.Fabrication of Novel Pullulan/Carboxymethyl Chitosan-Based Edible Film Incorporated with Ultrasonically Equipped Aqueous Zein/Turmeric Essential Oil Nanoemulsion for Effective Preservation of Mango Fruits[J]. International Journal of Biological Macromolecules, 2025, 294: 139330.
[30] ZHANG X C, JIAN J H, LUO Z S, et al.Fabrication of Edible Nanocellulose Chitosan Bi-Component Film Based on a Novel “Swell-Permeate” Approach[J]. Carbohydrate Polymers, 2024, 346: 122632.
[31] ZHANG H L, ZOU P Q, YUAN F Y, et al.Ginger Residue-Derived Nanocellulose as a Sustainable Reinforcing Agent for Composite Films[J]. International Journal of Biological Macromolecules, 2025, 308: 142754.
[32] YANG W J, ZHANG S K, HU Y N, et al.Pectin-Based Film Activated with Carboxylated Cellulose Nanocrystals-Stabilized Oregano Essential Oil Pickering Emulsion[J]. Food Hydrocolloids, 2024, 151: 109781.
[33] PAVLATKOVA L, SOGUT E, SEDLARIKOVA J, et al.Zein/Chitosan/Cellulose Nanocrystal Based Active Food Contact Layer: Unlocking the Interrelations between Release Behavior, Mechanical Stability, and Hydrolysis[J]. Food Hydrocolloids, 2025, 166: 111316.
[34] HOYOS-MERLANO N T, BORRONI V, RODRIGUEZ-BATILLER M J, et al. Nanoreinforcement as a Strategy to Improve Physical Properties of Biodegradable Composite Films Based on Biopolymers[J]. Food Research International, 2022, 162: 112178.
[35] 陈欢, 钟洪浩, 王鲁峰. TEMPO氧化-高压均质联用制备柑橘纳米纤维素及其性质表征[J]. 食品科学技术学报, 2022, 40(4): 35-44.
CHEN H, ZHONG H H, WANG L F.Preparation of Citrus Nanofibers by TEMPO Oxidation-High Pressure Homogenization and Its Characterization[J]. Journal of Food Science and Technology, 2022, 40(4): 35-44.
[36] PATIL S, BHARIMALLA A K, NADANATHANGAM V, et al.Nanocellulose Reinforced Corn Starch-Based Biocomposite Films: Composite Optimization, Characterization and Storage Studies[J]. Food Packaging and Shelf Life, 2022, 33: 100860.
[37] ZHANG L H, ZHANG M, MUJUMDAR A S, et al.Novel Multilayer Chitosan/Emulsion-Loaded Syringic Acid Grafted Apple Pectin Film with Sustained Control Release for Active Food Packaging[J]. Food Hydrocolloids, 2023, 142: 108823.
[38] WU Q, ZHANG J Y, MAO S, et al.An Intelligent Bilayer Film Incorporating Anthocyanin Sensitized TiO2 and Salicylic Acid with Ethylene Scavenging and Antibacterial Properties for Perishable Food Preservation[J]. Food Chemistry, 2026, 498: 147117.
[39] BAO Y W, WANG M S, LI J X, et al.A Starch-Based 3D Printed Intelligent Colorimetric Film Co-Loaded Natural Pigments for Visualizing Food Freshness: Effect of Nozzle Size on Gel Structure Formation[J]. Food Hydrocolloids, 2024, 155: 110218.
[40] DONG J L, YU D W, ZHANG L M, et al.Chitosan/Alginate Dialdehyde Trilayer Films with Cinnamaldehyde Nanoemulsions for Grass Carp Preservation[J]. Food Hydrocolloids, 2024, 147: 109413.
[41] XIE Z Y, WEN H, CHEN Z Y, et al.Natural Pollen Microspheres Structured into Leaf-Inspired Channels: Janus Biomimetic Film for Adjustable Gas Permeation[J]. Chemical Engineering Journal, 2026, 538: 176834.
[42] LIU Y F, XIA Y, DAI Y Q, et al.Design of Structurally Enhanced Dual-Network High Internal Phase Emulsion Gels for 3D-Printable Plant-Based Fat Substitutes Using Carboxymethyl Cellulose/Heat-Treated Soy Protein Isolate and K-Carrageenan[J]. Food Chemistry, 2026, 502: 147611.
[43] LI M Y, LUO X Q, ZHU R X, et al.Development and Characterization of Active Bilayer Film Incorporated with Dihydromyricetin Encapsulated in Hydroxypropyl-β-Cyclodextrin for Food Packaging Application[J]. Food Hydrocolloids, 2022, 131: 107834.
[44] WEI Z C, XUE W H, CHAI X H, et al.Development and Preservative Applications of Polysaccharide-Based Bilayer Packaging Films: Enhanced Functional Properties through Metal-Phenolic Network-Coated Zein Nanoparticles and Biomimetic Hydrophobic Surfaces[J]. Food Hydrocolloids, 2025, 160: 110726.
[45] UREÑA M, FOURNIER P, PHÙNG T T, et al. Potential of Polysaccharides for Food Packaging Applications. Part 2/2: An Experimental Review of the Effect of Aging Conditions on the Functional Properties of Polysaccharide Films[J]. Food Hydrocolloids, 2023, 144: 108954.
[46] UYARCAN M, GÜNGÖR S C. Improving Functional Properties of Starch-Based Films by Ultraviolet (UV-C) Technology: Characterization and Application on Minced Meat Packaging[J]. International Journal of Biological Macromolecules, 2024, 282: 137085.
[47] HAMED Y S, HASSAN K R, SALEM M E, et al.Gamma Rays Irradiated Polysaccharides: A Review of the Structure, Physicochemical Properties, Biological Activities Alteration, and Future Food Applications[J]. Carbohydrate Polymers, 2025, 354: 123326.
[48] 刘毅, 朱晶玉, 程宇航, 等. 干燥条件对魔芋葡甘聚糖基乳液膜成膜过程、膜结构与膜性能的影响[J]. 食品与机械, 2025, 41(7): 248-256.
[49] JI Q H, SU L X, BOATENG I D, et al.Preparation of Chitosan/Peanut Shell Nano-Lignocellulose (CS/NLC) Composite Film and Its Preservation Effect on Cherry Tomato and Blueberry[J]. Industrial Crops and Products, 2025, 228: 120881.
[50] LIU B Z, WANG K, SUN F F, et al.Carbon Dots and Cellulose Nanocrystal-Incorporated Chitosan Composite Films with Enhanced Gas Selectivity and Photodynamic Antibacterial Properties for Fruit Preservation[J]. Carbohydrate Polymers, 2025, 356: 123413.
[51] WANG J D, YANG S L, LIU G S, et al.A Degradable Multi-Functional Packaging Based on Chitosan/Silk Fibroin via Incorporating Cellulose Nanocrystals-Stabilized Cinnamon Essential Oil Pickering Emulsion[J]. Food Hydrocolloids, 2024, 153: 109978.
[52] DONG S Y, ZHANG Y Q, LU D, et al.Multifunctional Intelligent Film Integrated with Purple Sweet Potato Anthocyanin and Quercetin-Loaded Chitosan Nanoparticles for Monitoring and Maintaining Freshness of Shrimp[J]. Food Packaging and Shelf Life, 2023, 35: 101022.
[53] 谢建华, 谢丙清, 郭巧玲, 等. 魔芋葡甘聚糖-乳清蛋白复合膜在琯溪蜜柚中的应用[J]. 食品科学技术学报, 2017, 35(1): 76-81.
XIE J H, XIE B Q, GUO Q L, et al.Konjac Glucomannan and Whey Protein Composite Coating Application on Preservation of Guanxi Honey Pummelo[J]. Journal of Food Science and Technology, 2017, 35(1): 76-81.
[54] 雷桥, 张文惠. 负载天然色素的生物基智能包装指示器研究进展[J]. 食品科学技术学报, 2024, 42(1): 20-31.
LEI Q, ZHANG W H.Research Progress of Bio-Based Intelligent Packaging Indicator Loaded with Natural Pigments[J]. Journal of Food Science and Technology, 2024, 42(1): 20-31.
基金
江苏省食品先进制造装备技术重点实验室课题(FMZ202306);中央高校基本科研计划(JUSPR124012);国家大学生创新创业训练计划项目(项目编号202510295043Z)