LIG/PDMS温度应变传感器制备及解耦研究

顾锦涛, 耿婷, 邓琳, 朱庭璇, 许光毅, 刘富

包装工程(技术栏目) ›› 2026, Vol. 47 ›› Issue (5) : 27-35.

PDF(3845 KB)
PDF(3845 KB)
包装工程(技术栏目) ›› 2026, Vol. 47 ›› Issue (5) : 27-35. DOI: 10.19554/j.cnki.1001-3563.2026.05.004
先进材料

LIG/PDMS温度应变传感器制备及解耦研究

  • 顾锦涛1, 耿婷1, 邓琳2, 朱庭璇1, 许光毅1, 刘富1,*
作者信息 +

Fabrication and Decoupling of LIG/PDMS Temperature Strain Sensors

  • GU Jintao1, GENG Ting1, DENG Lin2, ZHU Tingxuan1, XU Guangyi1, LIU Fu1,*
Author information +
文章历史 +

摘要

目的 针对现有LIG基传感器温度与应变耦合干扰、高温检测范围窄等问题,阐明LIG/PDMS复合材料的温度敏感机理,揭示温度对传感器核心性能的影响规律,建立耦合信号解耦模型,实现宽温域内温度与应变的精准检测。方法 采用激光诱导法制备LIG/PDMS柔性传感器,通过四探针测试、SEM、拉曼光谱表征材料特性,结合温阻测试、应变测试及频率响应测试,系统分析温度对传感器性能的调控作用。结果 确定5 W扫描功率、200 μm扫描间距为最优制备参数,LIG方阻最低达5.56 Ω/sq。复合材料温度响应源于PDMS热膨胀效应,25~214 ℃内ΔR/R₀与温度线性相关(R2=99.24%)。室温下应变灵敏度为83.6,100 ℃时温度对应变灵敏度的影响因子达0.027 8,温度对检测频率影响较小,100 ℃以下迟滞<5%。结论 成功制备高性能LIG/PDMS复合材料,明确了温度对传感器性能的调控机制,建立的解耦模型实现了25~214 ℃温度与0~50%应变的有效分离,为复杂环境下多物理量传感提供了一种方案。

Abstract

To solve the problems of temperature and strain coupling interference and narrow high temperature detection range of the existing LIG based sensor, the work aims to clarify the temperature sensitive mechanism of LIG/PDMS composites, reveal theeffect of temperature on the core performance of the sensor and establish the coupling signal decoupling model to realize the accurate detection of temperature and strain in a wide temperature range. The LIG/PDMS flexible sensor was prepared by laser-induced method. The material properties were characterized by four-point probe measurement, SEM, and Raman spectroscopy. Combined with temperature-resistance test, strain test, and frequency response test, the regulatory effect of temperature on the sensor performance was systematically analyzed.It was determined that 5 W scanning power and 200 μm scanning spacing were the optimal preparation parameters, and the LIG square resistance was the lowest, reaching 5.56 Ω/sq. The temperature response of the composite was due to the thermal expansion effect of PDMS, and ΔR/R0 had a good linear correlation with temperature in the range of 25-214 ℃ (R2=99.24%). When the strain sensitivity of the sensor was 83.6 at room temperature, at 100 ℃, the effect factor of temperature on the strain sensitivity was 0.027 8. The temperature had little effect on the detection frequency, and the hysteresis of the sensor below 100 ℃ was less than 5%. In this study, high-performance LIG/PDMS composites are successfully prepared, and the regulation mechanism of temperature on the sensor performance is clarified. The established decoupling model realizes effective decoupling at the temperature of 25-214 ℃ and the strain of 0-50%, which provides a scheme for multi physical quantity sensing in complex environments.

关键词

激光诱导石墨烯 / 柔性应变传感器 / 温度应变解耦 / 灵敏度 / 频率 / 迟滞效应

Key words

laser-induced graphene / flexible strain sensor / temperature strain decoupling / sensitivity / frequency / hysteresis effect

引用本文

导出引用
顾锦涛, 耿婷, 邓琳, 朱庭璇, 许光毅, 刘富. LIG/PDMS温度应变传感器制备及解耦研究[J]. 包装工程. 2026, 47(5): 27-35 https://doi.org/10.19554/j.cnki.1001-3563.2026.05.004
GU Jintao, GENG Ting, DENG Lin, ZHU Tingxuan, XU Guangyi, LIU Fu. Fabrication and Decoupling of LIG/PDMS Temperature Strain Sensors[J]. Packaging Engineering. 2026, 47(5): 27-35 https://doi.org/10.19554/j.cnki.1001-3563.2026.05.004
中图分类号: TB34   

参考文献

[1] QIU J L, LIU S M, GUO Y J, et al.Anisotropic Flexible Pressure/Strain Sensors: Recent Advances, Fabrication Techniques, and Future Prospects[J]. Chemical Engineering Journal, 2025, 504: 158799.
[2] MEI S X, YI H K, ZHAO J, et al.High-Density, Highly Sensitive Sensor Array of Spiky Carbon Nanospheres for Strain Field Mapping[J]. Nature Communications, 2024, 15: 3752.
[3] 杨平安, 刘中邦, 李锐, 等. 电阻式柔性触觉传感器的研究进展[J]. 材料导报, 2023, 37(9): 32-45.
[4] YANG P A, LIU Z B, LI R, et al.Recent Progress in the Development of Resistive Flexible Tactile Sensors[J]. Materials Reports, 2023, 37(9): 32-45.
[5] MATHEW S, CHINTAGUMPALA K.A Review of Recent Progress in Flexible Capacitance Pressure Sensors: Materials Design, Printing Methods, and Applications[J]. Advanced Composites and Hybrid Materials, 2025, 8(3): 236.
[6] TANG J Y, LI Y H, YU Y R, et al.Recent Progress in Flexible Piezoelectric Tactile Sensors: Materials, Structures, Fabrication, and Application[J]. Sensors, 2025, 25(3): 964.
[7] 张文博, 李雯, 梁慧媛, 等. 生物质材料在摩擦电柔性传感器中的研究进展[J]. 复合材料学报, 2025, 42(3): 1272-1287.
[8] ZHANG W B, LI W, LIANG H Y, et al.Progress of Biomass Materials in Triboelectric Flexible Sensors[J]. Acta Materiae Compositae Sinica, 2025, 42(3): 1272-1287.
[9] LIU X, WEI L S, WANG X Y, et al.Flexible Strain Sensors Based on Gold Nanowire Dominoes for Human Motion Detection[J]. Materials Today Communications, 2023, 35: 105703.
[10] 高晗, 顾锋. 银纳米线基柔性应变传感器气溶胶喷射打印制备及性能[J]. 微纳电子技术, 2024, 61(6): 68-74.
[11] GAO H, GU F.Aerosol Jet Printing and Performance of Silver Nanowire-Based Flexible Strain Sensors[J]. Micronanoelectronic Technology, 2024, 61(6): 68-74.
[12] VILLAFUERTE J, ZHANG X T, SARIGIANNIDOU E, et al.Boosting the Piezoelectric Coefficients of Flexible Dynamic Strain Sensors Made of Chemically-Deposited ZnO Nanowires Using Compensatory Sb Doping[J]. Nano Energy, 2023, 114: 108599.
[13] 毕淑敏, 孙蕴菡, 李秋宇, 等. PEDOT: PSS/PET织物传感器的制备及其衰变行为研究[J]. 北京服装学院学报(自然科学版), 2023, 43(4): 20-28.
[14] BI S M, SUN Y H, LI Q Y, et al.Preparation and Decay Behavior of PEDOT: PSS/PET Fabric Sensor[J]. Journal of Beijing Institute of Fashion Technology (Natural Science Edition), 2023, 43(4): 20-28.
[15] YANG C Q, ZHANG D Z, WANG D Y, et al.In Situ Polymerized MXene/Polypyrrole/Hydroxyethyl Cellulose-Based Flexible Strain Sensor Enabled by Machine Learning for Handwriting Recognition[J]. ACS Applied Materials & Interfaces, 2023, 15(4): 5811-5821.
[16] 谢金林, 顾鹏, 邱华. 铂修饰碳纳米管纱线在柔性传感器上的应用[J]. 丝绸, 2025, 62(3): 65-73.
[17] XIE J L, GU P, QIU H.Application of Platinum-Modified Carbon Nanotube Yarns on Flexible Sensors[J]. Silk, 2025, 62(3): 65-73.
[18] ZHOU X, HUI Y P, YANG N, et al.Affordable High-Sensitivity Flexible Strain Sensor Integrated with Machine Learning for Tracking In-Air Handwriting and Leg Motion[J]. ACS Applied Electronic Materials, 2025, 7(9): 3725-3736.
[19] 张俊杰, 蓝沛盛, 陈建昊, 等. 石墨烯导电碳浆的制备及其柔性压力传感器的应用[J]. 材料研究与应用, 2025, 19(4): 675-683.
[20] ZHANG J J, LAN P S, CHEN J H, et al.Preparation of Graphene Conductive Carbon Paste and Application in Flexible Pressure Sensors[J]. Materials Research and Application, 2025, 19(4): 675-683.
[21] LIN J, PENG Z W, LIU Y Y, et al.Laser-Induced Porous Graphene Films from Commercial Polymers[J]. Nature Communications, 2014, 5: 5714.
[22] 李晨. 基于木材上激光诱导石墨烯集成传感器的研究[D]. 西安: 陕西科技大学, 2022.
[23] LI C.Integrated Sensor Based on Laser-Induced Graphene on Wood[D]. Xi'an: Shaanxi University of Science & Technology, 2022.
[24] 郑广浩. 基于激光诱导石墨烯的室温柔性NOx气体传感器研究[D]. 天津: 河北工业大学, 2022.
[25] ZHENG G H.Research of Flexible NOx Gas Sensor Based on Laser-Induced Graphene at Room Temperature[D]. Tianjin: HebeiUniversity of Technology, 2022.
[26] YANG L, ZHENG G H, CAO Y Q, et al.Moisture-Resistant, Stretchable NOx Gas Sensors Based on Laser-Induced Graphene for Environmental Monitoring and Breath Analysis[J]. Microsystems & Nanoengineering, 2022, 8: 78.
[27] ABU BAKER A, BOLTAEV G, ALI A, et al.High Sensitivity Low-Temperature Ethanol and Acetone Gas Sensors Based on Silver/Titanium Oxide Decorated Laser-Induced Graphene[J]. Journal of Materials Science, 2024, 59(10): 4198-4208.
[28] 杨雪琼. 纳米酶型电化学传感器的构建及尿糖即时检测应用研究[D]. 重庆: 重庆医科大学, 2024.
[29] YANG X Q.Construction of Nano-Enzyme Electrochemical Sensor and Its Application in Real-Time Detection of Urine Glucose[D]. Chongqing: Chongqing Medical University, 2024.
[30] 张文娜, 孙秋. 激光诱导石墨烯基电化学传感器的制备与有机磷检测研究[J]. 哈尔滨工业大学学报,2023, 55(5): 1-15.
[31] ZHANG W N, SUN Q.Preparation of Laser-Induced Graphene-Based Electrochemical Sensor and Detection of Organophosphorus[J]. Journal of Harbin Institute of Technology, 2023, 55(5): 1-15.
[32] PARK C, RHYU H, JO S, et al.Electrochemical Sensor Based on Laser-Induced Graphene and CeO2 for Sensitive and Selective Dopamine Detection[J]. Journal of Electroanalytical Chemistry, 2025, 977: 118865.
[33] SHI A N, SINGH A, WILLIAMS L O, et al.Nanometer-Scale Precision Polymer Patterning of PDMS: Multiscale Insights into Patterning Efficiency Using Alkyldiynamines[J]. ACS Applied Materials & Interfaces, 2022, 14(19): 22634-22642.
[34] DENG B W, WANG Z Y, LIU W G, et al.Multifunctional Motion Sensing Enabled by Laser-Induced Graphene[J]. Materials, 2023, 16(19): 6363.
[35] ZOU Y, ZHONG M, LI S C, et al.Flexible Wearable Strain Sensors Based on Laser-Induced Graphene for Monitoring Human Physiological Signals[J]. Polymers, 2023, 15(17): 3553.
[36] YANG J, WU S C, YU J J, et al.Flexible Micro-Strain Graphene Sensors Enhanced by Laser-Induced Cracks for Health Monitoring[J]. Diamond and Related Materials, 2024, 148: 111401.
[37] LI Y P, NAKAMURA H, LEE D H, et al.Temperature Coefficient of Resistance of Transferred Laser-Induced Graphene[J]. ACS Applied Electronic Materials, 2024, 6(6): 4630-4634.
[38] PARK S H, PAK J J.LIG-Based High-Sensitivity Multiplexed Sensing System for Simultaneous Monitoring of Metabolites and Electrolytes[J]. Sensors, 2024, 24(21): 6945.
[39] NANKALI M, SOLEIMANI M, ENRIQUE P, et al.Direct Laser Synthesis, Tuning, and Patterning of Metal Nanoparticles-Decorated Graphene for Flexible Temperature Sensors[J]. Materials Today Nano, 2025, 30: 100617.
[40] ZHENG L, LIU D, DAI J W, et al.Flexible Antibacterial Strain Sensor with Low Electrical Hysteresis, Ultralow Detection Limit, and Wide Linear Sensing Range for Human Motion Monitoring and Human-Machine Interaction[J]. Chemical Engineering Journal, 2024, 500: 157289.
[41] WANG Q, YAO Z W, ZHANG C C, et al.A Selective-Response Hypersensitive Bio-Inspired Strain Sensor Enabled by Hysteresis Effect and Parallel Through-Slits Structures[J]. Nano-Micro Letters, 2023, 16(1): 26.
[42] DONG T Y, ZHANG C J, ZHAO J W, et al.Comparison of Flexible Strain Sensors Based on Liquid Metals with Different Microchannel Structures[J]. Measurement Science and Technology, 2025, 36(2): 025112.
[43] LIU Y X, CHEN Y R, WANG Z B, et al.Enhanced Electrical Conductivity in Laser-Induced Graphene-Silicon Carbide Laminated Nanosheets for Flexible Strain Sensors and Pulse Wave Velocity Assessment[C]//2024 IEEE 37th International Conference on Micro Electro Mechanical Systems (MEMS). Austin, TX, USA. IEEE, 2024: 919-922.
[44] QIN H T, HAJIAGHAJANI A, ESCOBAR A R, et al.Laser-Induced Graphene-Based Smart Textiles for Wireless Cross-Body Metrics[J]. ACS Applied Nano Materials, 2023, 6(20): 19158-19167.
[45] LIU Y X, LI H Z, ZHANG M.Wireless Battery-Free Broad-Band Sensor for Wearable Multiple Physiological Measurement[J]. ACS Applied Electronic Materials, 2021, 3(4): 1681-1690.
[46] KAIDAROVA A, KHAN M A, MARENGO M, et al.Wearable Multifunctional Printed Graphene Sensors[J]. npj Flexible Electronics, 2019, 3: 15.
[47] JACQUIN T, WANSTALL S, PARK I, et al.Wearable, near Temperature Insensitive Laser-Induced GrapheneNanocomposite Strain Sensors[J]. Journal of Materials Chemistry C, 2025, 13(39): 20000-20012.
[48] ZHANG S P, CHHETRY A, ABU ZAHED M, et al.On-Skin Ultrathin and Stretchable Multifunctional Sensor for Smart Healthcare Wearables[J]. npj Flexible Electronics, 2022, 6: 11.
[49] ZHANG H, YANG H Z, XIN M Y, et al.Thermoelectric Composites Based on Porous Laser-Induced Graphene and Ion Hydrogel[J]. ACS Applied Materials & Interfaces, 2025, 17(14): 21773-21784.
[50] ZHANG Y, LI Y, LIU W W, et al.Laser-Induced Graphene and Laser-Induced Graphene/Carbon Nanotube-Based Sensors for Temperature and Strain Sensing[J]. Flexible and Printed Electronics, 2025, 10(1): 015009.

PDF(3845 KB)

Accesses

Citation

Detail

段落导航
相关文章

/