基于响应面法的卷烟纸污染物成分P&#x00026;T-GC-MS分析方法优化

张峻松; 向科宇; 侯世聪; 王光耀; 杨铖铖; 王嘉奇; 梁淼; 王仰勋

doi:10.19554/j.cnki.1001-3563.2026.03.019

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包装工程（技术栏目） ›› 2026, Vol. 47 ›› Issue (3) : 178-188. DOI: 10.19554/j.cnki.1001-3563.2026.03.019

自动化与智能化技术

基于响应面法的卷烟纸污染物成分P&T-GC-MS分析方法优化

张峻松¹, 向科宇¹, 侯世聪², 王光耀^2,*, 杨铖铖², 王嘉奇¹, 梁淼¹, 王仰勋^2,*

作者信息 +

Optimization of the P&T-GC-MS Analysis Method for Cigarette Paper Pollutants Based on the Response Surface Methodology

ZHANG Junsong¹, XIANG Keyu¹, HOU Shicong², WANG Guangyao^2,*, YANG Chengcheng², WANG Jiaqi¹, LIANG Miao¹, WANG Yangxun^2,*

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文章历史 +

摘要

目的优化确定卷烟纸斑点污染物中挥发性成分的吹扫捕集气质联用（Purge and trap gas chromatography-mass spectrometry,P&T-GC-MS）分析方法。方法采用单因素实验、Plackett-Burman设计及Box-Behnken响应面优化研究吹扫捕集方法对挥发性成分富集及分析效果的影响。结果通过针对萃取液体积、吹扫流量、样品杯温度、吹扫温度及解吸温度的单因素实验确定了较优水平,Plackett-Burman实验筛选出吹扫温度（B）、解吸温度（C）和吹扫流量（E）等3个对斑点成分富集效果影响显著的因素,最陡爬坡实验和响应面优化分析确定了3个主要因素与挥发性成分检测总峰面积间的模型。各因素的最佳水平为吹扫温度24.286 ℃,解吸温度228.576 ℃,吹扫流量43.196 mL/min,验证性实验表明最佳条件下卷烟纸斑点中挥发性成分检测效果较好。结论通过响应面法优化建立的P&T-GC-MS分析方法能够实现卷烟纸斑点污染物挥发性成分的高效富集鉴定,为卷烟纸污染源物质识别与溯源提供了方法借鉴。

Abstract

The work aims to optimize the Purge and Trap Gas Chromatography-Mass Spectrometry (P&T-GC-MS) analysis method for determining volatile components in pollutants present as spots on cigarette paper. Single-factor experiment, Plackett-Burman design and Box-Behnken response surface optimization were used to study the effect of purge and trap method on the enrichment and analysis of volatile components. The optimal level was determined by single-factor experiments on extraction liquid volume, purging flow, sample cup temperature, purging temperature and decomposition temperature. The Plackett-Burman experiment was carried out to identify three significant factors that affected the enrichment effect of spot components, namely purging temperature (B), decomposition temperature (C), and purging flow (E). Through the steepest ascent experiment coupled with response surface optimization analysis, a model relating three primary factors to the total peak area detected for volatile components was identified. The optimal levels for each factor were as follows: a purging temperature of 24.286 ℃, a decomposition temperature of 228.576 ℃, and a purging flow of 43.196 mL/min. Confirmatory experiments demonstrated that the detection of volatile components in cigarette paper spots yielded better results under optimal conditions. The P&T-GC-MS analysis method, optimized through the response surface methodology, enables efficient enrichment and identification of volatile components in spot pollutants on cigarette paper, offering a valuable methodological reference for the identification and tracing of pollution sources in cigarette paper.

导出引用

张峻松, 向科宇, 侯世聪, 王光耀, 杨铖铖, 王嘉奇, 梁淼, 王仰勋. 基于响应面法的卷烟纸污染物成分P&T-GC-MS分析方法优化[J]. 包装工程. 2026, 47(3): 178-188 https://doi.org/10.19554/j.cnki.1001-3563.2026.03.019

ZHANG Junsong, XIANG Keyu, HOU Shicong, WANG Guangyao, YANG Chengcheng, WANG Jiaqi, LIANG Miao, WANG Yangxun. Optimization of the P&T-GC-MS Analysis Method for Cigarette Paper Pollutants Based on the Response Surface Methodology[J]. Packaging Engineering. 2026, 47(3): 178-188 https://doi.org/10.19554/j.cnki.1001-3563.2026.03.019

中图分类号： TB487

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