高能辐射技术在高分子材料改性中的研究进展

陈捷妤, 罗文翰, 李结瑶, 王梁彬, 蓝碧锋

包装工程(技术栏目) ›› 2026, Vol. 47 ›› Issue (3) : 69-83.

PDF(12531 KB)
PDF(12531 KB)
包装工程(技术栏目) ›› 2026, Vol. 47 ›› Issue (3) : 69-83. DOI: 10.19554/j.cnki.1001-3563.2026.03.008
先进材料

高能辐射技术在高分子材料改性中的研究进展

  • 陈捷妤1, 罗文翰1,*, 李结瑶2, 王梁彬3, 蓝碧锋4
作者信息 +

Research Progress of High-energy Radiation Technology in Modification of Polymer Materials

  • CHEN Jieyu1, LUO Wenhan1,*, LI Jieyao2, WANG Liangbin3, LAN Bifeng4
Author information +
文章历史 +

摘要

针对高能辐射技术在高分子材料改性中存在的机理差异大、适用场景模糊等问题,分析了厘清电子束、γ射线、X射线、紫外及等离子体5种主流技术的异同,为材料的精准改性与工艺选择提供理论依据。基于近十年国内外文献,从辐射能量传递原理出发,系统阐述了辐射交联、接枝、固化及降解等核心机理,重点对比了5种技术在穿透深度、改性效率及装备成本上的差异,并归纳了其在力学增强、阻隔改性及生物相容性调控等方面的应用进展。最后提出未来的研究应聚焦于多技术协同效应(如辐射-化学联用)、改性过程的精准控制以及低成本工业化装备的开发,以拓展其在高附加值领域的应用深度。

Abstract

To address the challenges associated with significant mechanism discrepancies and ambiguous application scenarios of high-energy radiation technologies in polymer modification, the work aims to elucidate the distinctions among five mainstream techniques: electron beam (EB), gamma-ray, X-ray, ultraviolet (UV), and plasma, so as to provide a theoretical basis for precise material modification and optimal process selection. Based on a systematic review of domestic and international literature from the past decade, core mechanisms, including radiation crosslinking, grafting, curing, and degradation, starting from the principles of radiation energy transfer were elaborated. A comparative analysis is conducted regarding the penetration depth, modification efficiency, and equipment costs of the five techniques. Furthermore, their progress in applications such as mechanical reinforcement, barrier property improvement, and biocompatibility regulation is summarized. Finally, it is proposed that future research should focus on multi-technology synergistic effects (e.g., radiation-chemical coupling), precise control of the modification process, and the development of low-cost industrial equipment to expand its depth of application in high-value-added fields.

关键词

高能辐射 / 高分子材料 / 辐射改性

Key words

high-energy radiation / polymer materials / radiation modification

引用本文

导出引用
陈捷妤, 罗文翰, 李结瑶, 王梁彬, 蓝碧锋. 高能辐射技术在高分子材料改性中的研究进展[J]. 包装工程. 2026, 47(3): 69-83 https://doi.org/10.19554/j.cnki.1001-3563.2026.03.008
CHEN Jieyu, LUO Wenhan, LI Jieyao, WANG Liangbin, LAN Bifeng. Research Progress of High-energy Radiation Technology in Modification of Polymer Materials[J]. Packaging Engineering. 2026, 47(3): 69-83 https://doi.org/10.19554/j.cnki.1001-3563.2026.03.008
中图分类号: TB324   

参考文献

[1] DE AZEVEDO A M, DA SILVEIRA P H P M, LOPES T J, et al. Ionizing Radiation and Its Effects on Thermoplastic Polymers: An Overview[J]. Polymers, 2025, 17(8): 1110.
[2] FIFIELD L S, PHARR M, STAACK D, et al.Direct Comparison of Gamma, Electron Beam and X-Ray Irradiation Doses on Characteristics of Low-Density Polyethylene, Polypropylene Homopolymer, Polyolefin Elastomer and Chlorobutyl Rubber Medical Device Polymers[J]. Radiation Physics and Chemistry, 2021, 186: 109505.
[3] PATIL R S, THOMAS J, PATIL M, et al.To Shed Light on the UV Curable Coating Technology: Current State of the Art and Perspectives[J]. Journal of Composites Science, 2023, 7(12): 513.
[4] PRIMC G, MOZETIČ M.Surface Modification of Polymers by Plasma Treatment for Appropriate Adhesion of Coatings[J]. Materials, 2024, 17(7): 1494.
[5] 杨莹雪, 杜中贺, 杨博, 等. 辐射技术对聚酯改性研究进展[J]. 化工新型材料, 2020, 48(5): 20-25.
YANG Y X, DU Z H, YANG B, et al.Research Progress in Modification of Polyester by Radiation Technology[J]. New Chemical Materials, 2020, 48(5): 20-25.
[6] ZHOU P G, LIAO Z Q, RU X, et al.Study on Preparation of Metal Ion Adsorbent by Grafting Binary Monomer on Alkali Wood Fiber with Γ-Ray Co-Irradiation[J]. Journal of Applied Polymer Science, 2025, 142(27): e57135.
[7] MOHITE P, PURI A, SINGH S, et al.Graft Copolymers for Biomedical and Tissue Engineering Applications[M]. New York: Apple Academic Press, 2025: 277-341.
[8] ALIM A A A, BAHARUM A, SHIRAJUDDIN S S M, et al. Modification of Low-Density Polyethylene/Poly(butylene succinate)/Polyethylene-Graft-Maleic Anhydride (LDPE/ PBS/PE-g-MA) Polymer Blends via Electron Beam Irradiation[J]. Journal of Applied Polymer Science, 2026, 143(3): e58058.
[9] CHULIKOVA N, IPATOVA V, MALYUGA A, et al.Comparing the Impact of Pre-Planting Irradiation with Electron Beam and X-Rays on Potato Tuber Yield and Quality[J]. The European Physical Journal Special Topics, 2025, 5: 1-14.
[10] AHMED J, MUSHTAQ S.Bridging the Future: Unveiling the Latest Innovations in Ethylene Vinyl Acetate Blends and Composites through Electron Beam Irradiation—A Comprehensive Review[J]. Macromolecular Research, 2024, 32(11): 1049-1063.
[11] MARBACH L, MÖRBITZ P. Electron Beam-Induced Compatibilization of PLA/PBAT Blends in Presence of Epoxidized Soybean Oil[J]. Polymers, 2023, 15(15): 3265.
[12] GROSVENOR E C, HUGHES J C, STANFIELD C W, et al.On the Mechanism of Electron Beam Radiation-Induced Modification of Poly(lactic acid) for Applications in Biodegradable Food Packaging[J]. Applied Sciences, 2022, 12(4): 1819.
[13] 方洋, 张志洋. 强流脉冲电子束改性粘结层温度场研究[J]. 材料保护, 2024, 57(2): 92-97.
FANG Y, ZHANG Z Y.Research on Temperature Field of Adhesive Layer Modified by High-Current Pulsed Electron Beams[J]. Materials Protection, 2024, 57(2): 92-97.
[14] 赵康, 高俊娜, 束兴娟, 等. 电子束辐射接枝丙烯酸改性聚四氟乙烯[J]. 辐射研究与辐射工艺学报, 2021, 39(4): 11-16.
ZHAO K, GAO J N, SHU X J, et al.Electron Beam Radiation Grafting Acrylic Acid Modified Polytetrafluoroethylene[J]. Journal of Radiation Research and Radiation Processing, 2021, 39(4): 11-16.
[15] ZHOU X, YE X J, HE J, et al.Effects of Electron Beam Irradiation on the Properties of Waxy Maize Starch and Its Films[J]. International Journal of Biological Macromolecules, 2020, 151: 239-246.
[16] NAVARRO R, RUBIO HERNÁNDEZ-SAMPELAYO A, ADEM E, et al. Effect of Electron Beam Irradiation on the Properties of Poly(tetramethylene oxide) and a Poly(tetramethylene oxide)-Based Polyurethane[J]. Radiation Physics and Chemistry, 2020, 174: 108905.
[17] CHOI H I, HAN S M, JO Y D, et al.Effects of Acute and Chronic Gamma Irradiation on the Cell Biology and Physiology of Rice Plants[J]. Plants, 2021, 10(3): 439.
[18] ASHFAQ A, CLOCHARD M C, COQUERET X, et al.Polymerization Reactions and Modifications of Polymers by Ionizing Radiation[J]. Polymers, 2020, 12(12): 2877.
[19] HASE Y, SATOH K, SEITO H, et al.Genetic Consequences of Acute/Chronic Gamma and Carbon Ion Irradiation of Arabidopsis Thaliana[J]. Frontiers in Plant Science, 2020, 11: 336.
[20] CASIMIRO M H, GOMES S R, RODRIGUES G, et al.Chitosan/Poly(Vinylpyrrolidone) Matrices Obtained by Gamma-Irradiation for Skin Scaffolds: Characterization and Preliminary Cell Response Studies[J]. Materials, 2018, 11(12): 2535.
[21] LIM D, KIM Y, KWON S, et al.Effect of Gamma Irradiation on the Mechanical and Thermal Properties of Biodegradable Packaging Materials[J]. Korean Journal of Packaging Science and Technology, 2021, 27(2): 85-90.
[22] ISLAM M M, CHOWDHURY M A, TALUKDER A, et al.Enhancement of Moisture and Water Resistance in Chemically Treated and Gamma Irradiated Jute Fibers[J]. Fibers and Polymers, 2025, 26(2): 639-656.
[23] ZHANG H, WANG Y N, WU J J, et al.Migration Testing of Metallized Polypropylene Films Treated with Ionizing Radiation[J]. Food Packaging and Shelf Life, 2022, 31: 100799.
[24] BUSTAMANTE-TORRES M, PINO-RAMOS V H, ROMERO-FIERRO D, et al. Synthesis and Antimicrobial Properties of Highly Cross-Linked pH-Sensitive Hydrogels through Gamma Radiation[J]. Polymers, 2021, 13(14): 2223.
[25] ELSAWY M A, FEKRY M, SAYED A M, et al.Physico-Chemical Characteristics of Biodegradable Poly(lactic acid) and Poly(lactic acid)/Chitosan Nano-Composites under the Influence ofGamma Irradiation[J]. Journal of Polymers and the Environment, 2023, 31(6): 2705-2714.
[26] QIU L, LUO Q H, BAI C, et al.Preparation and Characterization of a Biodegradable Film Using Irradiated Chitosan Incorporated with Lysozyme and Carrageenan and Its Application in Crayfish Preservation[J]. Foods, 2023, 12(14): 2642.
[27] PARIDA C, MOHANTA K L, PATRA S.Study of Thermal Behaviour of Poly(Lactic) Acid Composites with Gamma Irradiated Luffa Fiber[J]. Proceedings of the National Academy of Sciences, India Section A: Physical Sciences, 2021, 91(3): 597-603.
[28] XIA X L, SHI X Y, LIU W T, et al.Effects of Gamma Irradiation on Properties of PLA/Flax Composites[J]. Iranian Polymer Journal, 2020, 29(7): 581-590.
[29] KRUG N, ZARGES J C, HEIM H P.Influence of Ethylene Oxide and Gamma Irradiation Sterilization Processes on the Properties of Poly-L-Lactic-Acid (PLLA) Materials[J]. Polymers, 2023, 15(16): 3461.
[30] MARTÍNEZ-BARRERA G, GENCEL O, MARTÍNEZ- LÓPEZ M. Polyester Polymer Concrete Modified by Polyester Fibers and Gamma Rays[J]. Construction and Building Materials, 2022, 356: 129278.
[31] BAKEER D E, ALSOMALI F, YAJZEY R, et al.Effect of Gamma Radiation on the Optical and Color Properties of Makrolon/Pocan/ZnS-NiO Nanocomposite Films[J]. Radiation Effects and Defects in Solids, 2024, 179(1/2): 227-246.
[32] MAHAJAN P, SARDANA S, MAHAJAN A.1D Graphene Nanoribbons-Mediated Defect Engineering in 2D MXene for High-Performance Supercapacitors[J]. Applied Physics Letters, 2024, 124(11): 111602.
[33] TAKEUCHI M, KINOSHITA A, YAMAGUCHI A, et al.Molecular Structure Evaluation of Bulk Polytetrafluoroethylene Modified by X-Ray Irradiation[J]. Journal of Photopolymer Science and Technology, 2020, 33(3): 295-299.
[34] LI B, YANG B, ZHANG H, et al.Giant Negative Electrocaloric Effect Measured by Indirect Method in X-Ray Irradiated P(VDF-TrFE) Films[J]. Journal of Materiomics, 2024, 10(3): 624-631.
[35] ADIKARY S U, CHAN H L W, CHOY C L, et al. Characterisation of Proton Irradiated Ba0.65Sr0.35TiO3/ P(VDF-TrFE) Ceramic-Polymer Composites[J]. Composites Science and Technology, 2002, 62(16): 2161-2167.
[36] GIRARD-PERIER N, MARQUE S R A, DUPUY N, et al. Gamma, E-Beam and X-Ray Irradiations on PE/EVOH/PE Multilayer Film: An Industrial Point of View Regarding the Impact on Mechanical Properties[J]. Polymers, 2023, 15(13): 2799.
[37] PATIL A, SOMVANSHI S B, SAWALE M, et al.Advances in Microbubble Technologies for Food Sanitization: A Comprehensive Review[J]. Comprehensive Reviews in Food Science and Food Safety, 2025, 24(4): e70230.
[38] DUYMAZ D, KARAOĞLU İ C, KIZILEL S. Effect of Photoinitiation Process on Photo-Crosslinking of Gelatin Methacryloyl Hydrogel Networks[J]. Macromolecular Rapid Communications, 2025, 46(20): e00376.
[39] BODILY M J.UV-A Light and Heat-Activated Antimicrobial and Biodegradable Materials for Food Packaging and Preservation[D]. Logan: Utah State University, 2025.
[40] WANG G, ZHOU Z X, CHEN M Y, et al.UV-Curable Polyurethane Acrylate Pressure-Sensitive Adhesives with High Optical Clarity for Full Lamination of TFT-LCD[J]. ACS Applied Polymer Materials, 2023, 5(3): 2051-2061.
[41] SHARIF A, ISLAM M M.Engineering Antiviral Properties in Cotton: Agents, Methods, and Future Directions[J]. Next Materials, 2025, 9: 101263.
[42] SHEN J C, WU T Q, ZOU J, et al.Development of Deep Ultraviolet LED Packaging[J]. Journal of Optics and Photonics Research, 2025, 2(1): 1-10.
[43] FAZULLIN D D, MAVRIN G V, SHAIKHIEV I G.Impact of Ultraviolet Irradiation on the Performance Characteristics of Polymeric Microfiltration Membranes[J]. Surface Engineering and Applied Electrochemistry, 2022, 58(1): 94-99.
[44] VESEL A, ZAPLOTNIK R, PRIMC G, et al.Evolution of the Surface Wettability of PET Polymer Upon Treatment with an Atmospheric-Pressure Plasma Jet[J]. Polymers, 2020, 12(1): 87.
[45] FAWZY Y H A, ABDEL-HAMID H M, EL-OKR M M, et al. Structural, Optical and Electrical Properties of Pet Polymer Films Modified by Low Energy Ar+ Ion Beams[J]. Surface Review and Letters, 2018, 25(3): 1850066.
[46] ATTA A, ALTHUBITI N A, ALTHUBITI S.Oxygen Plasma Irradiation-Induced Surface Modifications on HDPE and PET Polymeric Films[J]. Journal of the Korean Physical Society, 2021, 79(4): 386-394.
[47] ABDELTWAB E, ATTA A.Plasma-Induced Modifications on High Density Polyethylene and Polyethylene Terephthalate[J]. ECS Journal of Solid State Science and Technology, 2022, 11(4): 043012.
[48] 徐文倩, 栾欣昱, 李一冰, 等. 电晕放电等离子体辐射对紫花苜蓿种子的影响[J]. 辐射研究与辐射工艺学报, 2021, 39(2): 45-54.
XU W Q, LUAN X Y, LI Y B, et al.Effects of Corona Discharge Plasma Radiation on Alfalfa Seeds[J]. Journal of Radiation Research and Radiation Processing, 2021, 39(2): 45-54.
[49] BRAŞOVEANU M, SABBAGHI H, TICOȘ D, et al. Enhancing Starch Functionality through Synergistic Modification via Sequential Treatments with Cold Plasma and Electron Beam Irradiation[J]. International Journal of Biological Macromolecules, 2024, 270(Pt 1): 132346.
[50] ROUT S, SRIVASTAV P P.Modification of Soy Protein Isolate and Pea Protein Isolate by High Voltage Dielectric Barrier Discharge (DBD) Atmospheric Cold Plasma: Comparative Study on Structural, Rheological and Techno-Functional Characteristics[J]. Food Chemistry, 2024, 447: 138914.
[51] SAWANGRAT C, THIPCHAI P, KAEWAPAI K, et al.Surface Modification and Mechanical Properties Improvement of Bamboo Fibers Using Dielectric Barrier Discharge Plasma Treatment[J]. Polymers, 2023, 15(7): 1711.

基金

非均相PLA反应性增塑及分子动力学模拟(B32320740); 广东省科协青年科技人才培育计划(SKXRC2025297)

PDF(12531 KB)

Accesses

Citation

Detail

段落导航
相关文章

/