鲜切水果表面原位成形涂层创制及保鲜应用研究

李智信, 赵以勒, 郭晓宏, 陈晨, 姜爱丽, 李江阔, 吴迪, 陈昆松

包装工程(技术栏目) ›› 2025, Vol. 46 ›› Issue (23) : 171-180.

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包装工程(技术栏目) ›› 2025, Vol. 46 ›› Issue (23) : 171-180. DOI: 10.19554/j.cnki.1001-3563.2025.23.018
农产品保鲜与食品包装

鲜切水果表面原位成形涂层创制及保鲜应用研究

  • 李智信1a, 赵以勒1a, 郭晓宏1b, 陈晨2, 姜爱丽2, 李江阔3, 吴迪1a,*, 陈昆松1a
作者信息 +

Preparation of In-situ Formed Coating on the Surface of Fresh-cut Fruit and Its Application in Freshness Preservation

  • LI Zhixin1a, ZHAO Yile1a, GUO Xiaohong1b, CHEN Chen2, JIANG Aili2, LI Jiangkuo3, WU Di1a,*, CHEN Kunsong1a
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文章历史 +

摘要

目的 针对鲜切水果贮藏过程中的失水软化问题,制备一种在鲜切水果表面原位成形的涂层,保持鲜切水果的品质。方法 以脱乙酰魔芋葡甘聚糖(DKGM)、羧基化纤维素纳米纤维(CCNF)和海藻酸钠(SA)为原料,采用浸涂工艺,通过Ca²⁺交联作用,开发一种仅需30 s就可直接在鲜切水果表面原位成形的涂层,进一步在涂层中负载表没食子儿茶素没食子酸酯(EGCG)和谷胱甘肽(GSH)。对DKGM/CCNF/SA原位涂层的结构、力学性能和细胞毒性进行表征,并对其在鲜切水果中的保鲜性能进行研究。结果 当DKGM/CCNF混合溶液和SA溶液的体积比为1︰1时,原位涂层具有更强的力学性能(压缩模量为(1.10±0.14) MPa)和更好的热稳定性。原位涂层具有良好的生物安全性和低细胞毒性。鲜切苹果保鲜试验结果显示,在4 ℃下贮藏7 d后,E/G-DKGM/CCNF/SA原位涂层处理的鲜切苹果的硬度(7.71 N)显著高于未经涂层处理的对照组(6.10 N)。与对照组相比,E/G-DKGM/CCNF/SA原位涂层处理组的质量损失率减少4.61%,褐变指数下降19.62%。结论 DKGM/CCNF/SA原位涂层能显著抑制质量损失率上升、硬度下降和果肉褐变。该研究为鲜切水果表面原位涂层快速成形及失水软化抑制提供了新思路。

Abstract

The work aims to prepare a coating formed in-situ on the surface of fresh-cut fruits to solve the problem of water loss and softening of fresh-cut fruits during storage and to maintain their quality. By using deacetylated konjac glucomannan (DKGM), carboxylated cellulose nanofibers (CCNF), and sodium alginate (SA) as raw materials, and adopting a dip-coating process, a coating was developed, which could be directly molded in-situ on the surface of fresh-cut fruits in only 30 s by Ca2+ cross-linking. Furthermore, epigallocatechin gallate (EGCG) and glutathione (GSH) were loaded into the coating. The structure, mechanical properties, and cytotoxicity of the DKGM/CCNF/SA in-situ coating were characterized, and its preservation performance in fresh-cut fruits was investigated. When the volume ratio of the DKGM/CCNF mixed solution to the SA solution was 1:1, the in-situ coating exhibited stronger mechanical properties (compressive modulus of (1.10±0.14) MPa) and better thermal stability, and it also demonstrated good biosafety and low cytotoxicity. Fresh-cut apple preservation experiments showed that after 7 days of storage at 4 °C, the firmness of fresh-cut apples treated with the E/G-DKGM/CCNF/SA in-situ coating was 7.71 N, which was significantly higher than that of the untreated control group (6.10 N). Compared with the control group, the E/G-DKGM/CCNF/SA in-situ coating group reduced the water loss rate by 4.61% and the browning index by 19.62%. Overall, the DKGM/CCNF/SA in-situ coating can significantly inhibit the increase of the weight loss rate, decrease of firmness, and browning of the fruit flesh. This study provides a new approach for the rapid in-situ formation of surface coatings on fresh-cut fruits and the inhibition of water loss and softening.

关键词

原位成形涂层 / 鲜切苹果 / 失水软化 / 脱乙酰魔芋葡甘聚糖 / Ca2+交联 / 保鲜

Key words

in-situ formed coating / fresh-cut apples / water loss and softening / deacetylated konjac glucomannan / Ca2+ cross-linking / preservation

引用本文

导出引用
李智信, 赵以勒, 郭晓宏, 陈晨, 姜爱丽, 李江阔, 吴迪, 陈昆松. 鲜切水果表面原位成形涂层创制及保鲜应用研究[J]. 包装工程. 2025, 46(23): 171-180 https://doi.org/10.19554/j.cnki.1001-3563.2025.23.018
LI Zhixin, ZHAO Yile, GUO Xiaohong, CHEN Chen, JIANG Aili, LI Jiangkuo, WU Di, CHEN Kunsong. Preparation of In-situ Formed Coating on the Surface of Fresh-cut Fruit and Its Application in Freshness Preservation[J]. Packaging Engineering. 2025, 46(23): 171-180 https://doi.org/10.19554/j.cnki.1001-3563.2025.23.018
中图分类号: TB484   

参考文献

[1] 李雨奇. 鲜切水果加工工艺及保鲜技术的研究[J]. 轻纺工业与技术, 2021, 50(3): 4-6.
[2] LI Y Q.Study on Processing Technology and Preservation Technology of Fresh-Cut Fruit[J]. Light and Textile Industry and Technology, 2021, 50(3): 4-6.
[3] MA L, ZHANG M, BHANDARI B, et al.Recent Developments in Novel Shelf Life Extension Technologies of Fresh-Cut Fruits and Vegetables[J]. Trends in Food Science & Technology, 2017, 64: 23-38.
[4] LIU Z Y, LI M N, LI G J, et al.Strategies for Fresh-Cut Apple Preservation: Recent Advances and Future Prospects[J]. Comprehensive Reviews in Food Science and Food Safety, 2025, 24(6): e70300.
[5] FIRDOUS N, MORADINEZHAD F, FAROOQ F, et al.Advances in Formulation, Functionality, and Application of Edible Coatings on Fresh Produce and Fresh-Cut Products: A Review[J]. Food Chemistry, 2023, 407: 135186.
[6] ZHAO Y L, WU Z, CHEN C, et al.Deacetylated Konjac Glucomannan Films Functionalised with Carboxylated Cellulose Nanofiber and Anti-Browning Components for Fresh-Cut Apple Preservation[J]. Food Packaging and Shelf Life, 2024, 46: 101389.
[7] 李家琪, 张东红, 韩爱云. 鲜切苹果保鲜技术研究进展[J]. 保鲜与加工, 2023, 23(3): 75-80.
[8] LI J Q, ZHANG D H, HAN A Y.Research Progress on Preservation of Fresh-Cut Apples[J]. Storage and Process, 2023, 23(3): 75-80.
[9] GUERREIRO A C, GAGO C M L, FALEIRO M L, et al. The Effect of Edible Coatings on the Nutritional Quality of 'Bravo de Esmolfe' Fresh-Cut Apple through Shelf-Life[J]. LWT, 2017, 75: 210-219.
[10] YANG T, ZHOU D D, WU C E, et al.Structural Characterization of Modified Soy Protein Isolate Composite Coatings and Its Application on Fresh-Cut Cantaloupe (Cucumis Melo Cv. Xiaomi)[J]. Food Bioscience, 2024, 60: 104361.
[11] ZHOU C M, BAI J R, ZHANG F T, et al.Development of Mussel-Inspired Chitosan-Derived Edible Coating for Fruit Preservation[J]. Carbohydrate Polymers, 2023, 321: 121293.
[12] GIDADO M J, GUNNY A A N, GOPINATH S C B, et al. Challenges of Postharvest Water Loss in Fruits: Mechanisms, Influencing Factors, and Effective Control Strategies—A Comprehensive Review[J]. Journal of Agriculture and Food Research, 2024, 17: 101249.
[13] XIN Y, YANG C H, ZHANG J H, et al.Application of Whey Protein-Based Emulsion Coating Treatment in Fresh-Cut Apple Preservation[J]. Foods, 2023, 12(6): 1140.
[14] QIU W Y, WANG Y H, LI W X, et al.Nanocomposite Coating Based on Nitrogen-Doped Carbon Dots in Extending Shelf Life of Fresh-Cut Pears from the Perspective of Microorganism[J]. Food Bioscience, 2024, 61: 104598.
[15] DAS K, SHARMA S, KUMAR S, et al.Chitosan Nanoparticles and Neem Essential Oil Functionalized Pullulan/Gum Arabic Active Edible Biocomposites for Fresh-Cut Guava Preservation[J]. International Journal of Biological Macromolecules, 2024, 283: 136936.
[16] SHI S, HUANG H Y, DUAN L H, et al.Konjac Glucomannan-Based Films and Coatings for Food Packaging: Advances, Applications, and Future Perspectives[J]. Carbohydrate Polymers, 2025, 357: 123474.
[17] KALITA P, ROY P K, BHATTACHARJEE B, et al.Alginate-Based Coating in Post-Harvest Fruits Preservation: A Comprehensive Review[J]. International Journal of Biological Macromolecules, 2025, 320: 145799.
[18] DENG P P, ZHANG Y S, NIU Z Y, et al.Multifunctional Konjac Glucomannan/Xanthan Gum Self-Healing Coating for Bananas Preservation[J]. International Journal of Biological Macromolecules, 2024, 270: 132287.
[19] CHEN K, TIAN R M, XU G J, et al.Characterizations of Konjac Glucomannan/Curdlan Edible Coatings and the Preservation Effect on Cherry Tomatoes[J]. International Journal of Biological Macromolecules, 2023, 232: 123359.
[20] DUONG N T C, UTHAIRATANAKIJ A, LAOHAKUNJIT N, et al. Cross-Linked Alginate Edible Coatings Incorporated with Hexyl Acetate: Film Characteristics and Its Application on Fresh-Cut Rose Apple[J]. Food Bioscience, 2023, 52: 102410.
[21] PREETHI R, MOSES J A, ANANDHARAMAKRISHNAN C.Development of Anacardic Acid Incorporated Biopolymeric Film for Active Packaging Applications[J]. Food Packaging and Shelf Life, 2021, 28: 100656.
[22] DONG L J, JIAO Q B, GAO J, et al.Effects of Zein-Lecithin-EGCG Nanoparticle Coatings on Postharvest Quality and Shelf Life of Loquat (Eriobotrya Japonica)[J]. LWT, 2023, 182: 114918.
[23] YIN C, SUN Z F, YANG Y F, et al.Rapid in Situ Formation of Κ-Carrageenan-Carboxymethyl Chitosan- Kaolin Clay Hydrogel Films Enriched with Arbutin for Enhanced Preservation of Cherry Tomatoes[J]. International Journal of Biological Macromolecules, 2024, 273: 132957.
[24] QIAO D L, LU J Y, SHI W J, et al.Deacetylation Enhances the Properties of Konjac Glucomannan/Agar Composites[J]. Carbohydrate Polymers, 2022, 276: 118776.
[25] YU K J, YANG L N, ZHANG S Y, et al.Soy Hull Nanocellulose Enhances the Stretchability, Transparency and Ionic Conductance of Sodium Alginate Hydrogels and Application in Beef Preservation[J]. Food Hydrocolloids, 2024, 152: 109938.
[26] WEI H Z, LIU F, CHIOU B S, et al.Enhancing Wet Strength of Konjac Glucomannan/Calcium Alginate Films via Deacetylation[J]. Food Hydrocolloids, 2026, 172: 111890.
[27] ZHANG Y W, ZHAO W X, LIN Z H, et al.Carboxymethyl Chitosan/Sodium Alginate Hydrogel Films with Good Biocompatibility and Reproducibility by in Situ Ultra-Fast Crosslinking for Efficient Preservation of Strawberry[J]. Carbohydrate Polymers, 2023, 316: 121073.
[28] ZENG Y B, WANG Y, TANG J H, et al.Preparation of Sodium Alginate/Konjac Glucomannan Active Films Containing Lycopene Microcapsules and the Effects of these Films on Sweet Cherry Preservation[J]. International Journal of Biological Macromolecules, 2022, 215: 67-78.
[29] YUE C, ZHANG G W.Calcium Ion Crosslinked Sodium Alginate Coated PVDF Membrane for Improved Smart pH-Responsive Properties[J]. Journal of Environmental Chemical Engineering, 2022, 10(6): 108684.
[30] JIANG Z W, FENG J D, DAI Y D, et al.Preparation of a Biodegradable Packaging Film by Konjac Glucomannan/ Sodium Alginate Reinforced with Nitrogen-Doped Carbon Quantum Dots from Crayfish Shell for Crayfish Meat Preservation[J]. International Journal of Biological Macromolecules, 2025, 297: 139596.
[31] LI H C, TAN W T, HOU M X, et al.Multi-Strategy Dynamic Cross-Linking to Prepare EGCG-Loaded Multifunctional Pickering Emulsion/α-Cyclodextrin/ Konjac Glucomannan Composite Films for Ultra-Durable Preservation of Perishable Fruits[J]. Carbohydrate Polymers, 2024, 338: 122205.
[32] WANG X N, SONG Y Q, WANG X X, et al.An All-Natural Sustainable Packaging Strategy Driven by Hydrogen Bond Self-Assembly for the Fresh-Cut Apple and Perishable Grape Preservation[J]. Food Research International, 2025, 220: 117145.
[33] WANG J X, QIN M, WANG W, et al.Konjac Glucomannan/Carboxylated Cellulose Nanofiber-Based Edible Coating with Tannic Acid Maintains Quality and Prolongs Shelf-Life of Mango Fruit[J]. Food Chemistry, 2025, 478: 143750.
[34] SUN J S, JIANG H X, LI M W, et al.Preparation and Characterization of Multifunctional Konjac Glucomannan/ Carboxymethyl Chitosan Biocomposite Films Incorporated with Epigallocatechin Gallate[J]. Food Hydrocolloids, 2020, 105: 105756.
[35] LIU Y P, QIN Y, BAI R Y, et al.Preparation of pH-Sensitive and Antioxidant Packaging Films Based on Κ-Carrageenan and Mulberry Polyphenolic Extract[J]. International Journal of Biological Macromolecules, 2019, 134: 993-1001.
[36] RUAN C C, ZHANG Y M, WANG J J, et al.Preparation and Antioxidant Activity of Sodium Alginate and Carboxymethyl Cellulose Edible Films with Epigallocatechin Gallate[J]. International Journal of Biological Macromolecules, 2019, 134: 1038-1044.
[37] YU K J, YANG L N, ZHANG S Y, et al.Strong, Tough, High-Release, and Antibacterial Nanocellulose Hydrogel for Refrigerated Chicken Preservation[J]. International Journal of Biological Macromolecules, 2024, 264: 130727.
[38] LIU G C, LIU R, FU C Y, et al.Protein/Polysaccharide Composite Nanocoating Based on Amyloid-Like Aggregation for Fresh-Cut Fruits Preservation[J]. Chemical Engineering Journal, 2025, 519: 165048.
[39] GUO Q, QING Y D, QIANG L Y, et al.Improving Microbiological and Physicochemical Properties of Fresh-Cut Apples Using Carvacrol Emulsions[J]. Food Bioscience, 2023, 52: 102450.
[40] ZHANG C C, YANG Z K, SHI J Y, et al.Physical Properties and Bioactivities of Chitosan/Gelatin-Based Films Loaded with Tannic Acid and Its Application on the Preservation of Fresh-Cut Apples[J]. LWT, 2021, 144: 111223.
[41] YOUSUF B, WU S M, SIDDIQUI M W.Incorporating Essential Oils or Compounds Derived Thereof into Edible Coatings: Effect on Quality and Shelf Life of Fresh/Fresh-Cut Produce[J]. Trends in Food Science & Technology, 2021, 108: 245-257.

基金

山东省重点研发计划课题(2022TZXD0022); 浙江省属高校基本科研业务费专项资金(226-2024-00084)

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