茶末-CMC-SiO2电喷雾涂膜工艺优化及其对鸡蛋保鲜效果

陈龙, 柳诚刚, 陈南方, 李建芳, 朱静, 邢淑婕

包装工程(技术栏目) ›› 2025, Vol. 46 ›› Issue (17) : 172-184.

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包装工程(技术栏目) ›› 2025, Vol. 46 ›› Issue (17) : 172-184. DOI: 10.19554/j.cnki.1001-3563.2025.17.019
农产品保鲜与食品包装

茶末-CMC-SiO2电喷雾涂膜工艺优化及其对鸡蛋保鲜效果

  • 陈龙1, 柳诚刚1, 陈南方1, 李建芳1, 朱静1, 邢淑婕2,*
作者信息 +

Optimization of Electrospray Coating Process of Tea Powder·CMC·SiO2 and Preservation of Eggs

  • CHEN Long1, LIU Chenggang1, CHEN Nanfang1, LI Jianfang1, ZHU Jing1, XING Shujie2,*
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摘要

目的 为延缓鸡蛋贮藏期间品质的下降,使用CMC、纳米SiO2、甘油、茶末等成分制备复合膜,研究复合膜对鸡蛋的保鲜效果。方法 以复合膜的透光率、拉伸强度和断裂伸长率为指标,确定最优的纳米SiO2粒径,通过单因素试验(纳米SiO2添加量、CMC添加量、甘油添加量、茶末添加量)确定各因素的最优水平,以拉伸强度、断裂伸长率、透光率为响应值进行响应面试验,并将优化得到的膜用于鸡蛋保鲜,探究保鲜效果。结果 最优水平为纳米SiO2粒径30 nm,纳米SiO2添加量0.3 g,CMC添加量1.5 g,甘油添加量3 mL,茶末添加量1 g,将其应用于鸡蛋保鲜,在16 d内贮藏效果明显提升,鸡蛋的质量损失率上升程度、哈夫值下降程度、气室直径增加程度都有所减轻。结论 利用茶末-CMC-SiO2电喷雾涂膜工艺优化制备的复合膜,该复合膜对延长鸡蛋保质期具有良好效果。

Abstract

The work aims to prepare a composite membrane using CMC, nano-SiO2, glycerol, and tea powder, and to study its preservative effect on eggs, so as to delay the quality deterioration of eggs during storage. The optimal particle size of nano-SiO2 was determined based on the membrane's light transmittance, tensile strength, and elongation at break. Single-factor experiments (nano-SiO2 addition amount, CMC addition amount, glycerol addition amount, tea powder addition amount) were conducted to identify the optimal levels for each factor. Response surface methodology was then applied with tensile strength, elongation at break, and light transmittance as response values. The optimized membrane was subsequently used for egg preservation to evaluate its effectiveness. The results showed that the optimal conditions were: nano-SiO2 particle size of 30 nm, nano-SiO2 addition amount of 0.3 g, CMC addition amount of 1.5 g, glycerol addition amount of 3 mL, and tea powder addition amount of 1 g. When applied to egg preservation, the shelf life was notably extended over the 16-day period. The composite membrane significantly mitigated the increase in weight loss rate, the decline in Haugh unit, and the expansion of air cell diameter, demonstrating its excellent potential in extending the shelf life of eggs.

关键词

可食性复合膜 / 羧甲基纤维素(CMC) / 纳米SiO2 / 茶末 / 鸡蛋保鲜

Key words

edible composite membrane / carboxymethylcellulose (CMC) / nano-SiO2 / tea powder / preservation of eggs

引用本文

导出引用
陈龙, 柳诚刚, 陈南方, 李建芳, 朱静, 邢淑婕. 茶末-CMC-SiO2电喷雾涂膜工艺优化及其对鸡蛋保鲜效果[J]. 包装工程(技术栏目). 2025, 46(17): 172-184 https://doi.org/10.19554/j.cnki.1001-3563.2025.17.019
CHEN Long, LIU Chenggang, CHEN Nanfang, LI Jianfang, ZHU Jing, XING Shujie. Optimization of Electrospray Coating Process of Tea Powder·CMC·SiO2 and Preservation of Eggs[J]. Packaging Engineering. 2025, 46(17): 172-184 https://doi.org/10.19554/j.cnki.1001-3563.2025.17.019
中图分类号: TS205.9   

参考文献

[1] 谢枫, 金玲莉, 涂娟, 等. 茶废弃物综合利用研究进展[J]. 中国农学通报, 2015, 31(1): 140-145.
XIE F, JIN L L, TU J, et al.Comprehensive Utilization of Tea Waste: A Review[J]. Chinese Agricultural Science Bulletin, 2015, 31(1): 140-145.
[2] 田玥, 徐昊洋, 康晓鸥, 等. 二醛基纤维素/羧甲基纤维素复合薄膜的制备及在鸡蛋保鲜中的应用[J]. 食品与发酵工业, 2022, 48(17): 207-213.
TIAN Y, XU H Y, KANG X O, et al.Preparation of Dialdehyde Cellulose/Carboxymethyl Cellulose Composite Film and Its Application in Egg Preservation[J]. Food and Fermentation Industries, 2022, 48(17): 207-213.
[3] 赵亚丽, 杜健, 王海松. 羧甲基纤维素基薄膜的制备及其在食品包装中的应用[J]. 包装学报, 2023, 15(1): 12-20.
ZHAO Y L, DU J, WANG H S.Preparation of Carboxymethyl Cellulose-Based Film and Its Application in Food Packaging[J]. Packaging Journal, 2023, 15(1): 12-20.
[4] 罗爱国, 庆祎帆, 胡变芳, 等. 纳米二氧化硅改性藻多糖与壳聚糖复合膜的性能研究[J]. 食品工业科技, 2022, 43(9): 243-250.
LUO A G, QING Y F, HU B F, et al.Properties of Nano-Silica Modified Spirulina Platensis Polysaccharide and Chitosan Composite Film[J]. Science and Technology of Food Industry, 2022, 43(9): 243-250.
[5] 梁艳文, 严文静, 赵见营, 等. 纳米SiO2改性PVDC涂膜材料的制备及其对鸡蛋保鲜效果的研究[J]. 保鲜与加工, 2019, 19(2): 22-28.
LIANG Y W, YAN W J, ZHAO J Y, et al.Preparation of Nano-SiO2 Modified PVDC Coating Material and Its Preservation Effect on Clean Eggs[J]. Storage and Process, 2019, 19(2): 22-28.
[6] UMARAW P, MUNEKATA P E S, VERMA A K, et al. Edible Films/Coating with Tailored Properties for Active Packaging of Meat, Fish and Derived Products[J]. Trends in Food Science & Technology, 2020, 98: 10-24.
[7] SANYANG M L, SAPUAN S M, JAWAID M, et al.Effect of Plasticizer Type and Concentration on Physical Properties of Biodegradable Films Based on Sugar Palm (Arenga Pinnata) Starch for Food Packaging[J]. Journal of Food Science and Technology, 2016, 53(1): 326-336.
[8] ZHANG R F, WANG X Y, CHENG M, et al.Ultrasonic Preparation of Nano-SiO2-Potato Starch Composite Films by Spray Coating[J]. Food Science, 2019, 40(18): 302-311.
[9] 赵小永. 人工神经导管的压制卷曲成型工艺研究[D]. 乌鲁木齐: 新疆大学, 2020.
ZHAO X Y.Research on Pressing and Crimping Process of Artificial Nerve Conduit[D]. Urumqi: Xinjiang University, 2020.
[10] 孙小斌, 李婉君, 孙宝忠, 等. 响应面法优化牛皮胶原蛋白复合膜的制备工艺研究[J]. 食品科技, 2022, 47(4): 143-151.
SUN X B, LI W J, SUN B Z, et al.Optimization of Preparation Technology Process of Cowhide Collagen Composite Membrane by Ultrasound-Assisted Response Surface Methodology[J]. Food Science and Technology, 2022, 47(4): 143-151.
[11] 成刚刚. 出芽短梗霉普鲁兰多糖提取工艺优化及食品保鲜膜开发[D]. 天津: 天津科技大学, 2022.
CHENG G G.Optimization of Extraction Process of Glomus Prunellae Polysaccharide and Development of Food Packaging Film[D]. Tianjin: Tianjin University of Science & Technology, 2022.
[12] 李悦, 李晓娇, 张云娟, 等. 葛根淀粉可食膜的制备及其性能研究[J]. 食品研究与开发, 2021, 42(12): 108-115.
LI Y, LI X J, ZHANG Y J, et al.Preparation and Physical Properties of Pueraria Lobata Starch Edible Film[J]. Food Research and Development, 2021, 42(12): 108-115.
[13] 杨洁茹, 刘海波, 张雯雯, 等. 漂白紫胶/海藻酸钠复合膜的制备及其在冷鲜肉保鲜中的应用[J]. 食品工业科技, 2023, 44(18): 407-414.
YANG J R, LIU H B, ZHANG W W, et al.Preparation of Bleached Shellac/Sodium Alginate Composite Film and Its Application in Chilled Fresh Meat Preservation[J]. Science and Technology of Food Industry, 2023, 44(18): 407-414.
[14] 余芳, 汪洪涛, 郑梦瑶, 等. 辣木茶多酚提取工艺优化及其体外抗氧化活性[J]. 农产品加工, 2022(7): 24-28.
YU F, WANG H T, ZHENG M Y, et al.Optimization of Extraction of Moringa Oleifera Tea Polyphenols and in Vitro Antioxidant Activities[J]. Farm Products Processing, 2022(7): 24-28.
[15] 卢俊宇, 朱芮, 吴贺君, 等. 茶多酚对可食性马铃薯淀粉/海藻酸钠复合膜性能影响及表征[J]. 核农学报, 2020, 34(10): 2226-2234.
LU J Y, ZHU R, WU H J, et al.Effect of Tea Polyphenols on the Properties of Edible Potato Starch/Sodium Alginate Composite Films[J]. Journal of Nuclear Agricultural Sciences, 2020, 34(10): 2226-2234.
[16] 梁杰, 赵晓旭, 刘涛, 等. 茶多酚-壳聚糖复合膜的制备及保鲜效果研究[J]. 热带作物学报, 2022, 43(6): 1267-1279.
LIANG J, ZHAO X X, LIU T, et al.Preparation and Fresh-Keeping Effect of Tea Polyphenol-Chitosan Composite Film[J]. Chinese Journal of Tropical Crops, 2022, 43(6): 1267-1279.
[17] 韦燕文, 蔡文韬, 袁学文, 等. 不同涂膜保鲜法对鸡蛋保鲜效果的研究[J]. 食品与发酵工业, 2021, 47(22): 221-226.
WEI Y W, CAI W T, YUAN X W, et al.The Effect of Different Coating Preservation Methods on Eggs[J]. Food and Fermentation Industries, 2021, 47(22): 221-226.
[18] 戴妍, 杨兵, 蒋文明, 等. 贮藏温度-时间变化对壳蛋新鲜度影响研究[J]. 食品工业科技, 2022, 43(18): 359-364.
DAI Y, YANG B, JIANG W M, et al.Study on the Effect of Storage Temperature-Time Changes on Shell Egg Freshness[J]. Science and Technology of Food Industry, 2022, 43(18): 359-364.
[19] 杨威, 徐本梁, 严顺洪, 等. 纳米二氧化硅粒径尺寸调控及其对表面化学修饰的影响研究[J]. 硅酸盐通报, 2020, 39(7): 2321-2325.
YANG W, XU B L, YAN S H, et al.Regulation of Nano SiO2 and the Effect of Particle Size on Surface Modification[J]. Bulletin of the Chinese Ceramic Society, 2020, 39(7): 2321-2325.
[20] 冯江波, 王景平, 苑慧莹, 等. 不同粒径PANI/SiO2对环氧涂层防腐性能的影响[J]. 材料导报, 2021, 35(24): 24182-24188.
FENG J B, WANG J P, YUAN H Y, et al.Effect of PANI/SiO2 Particle Size on Anti-Corrosion Properties of Epoxy Coating[J]. Materials Reports, 2021, 35(24): 24182-24188.
[21] KAMIYA H, MITSUI M, TAKANO H, et al.Influence of Particle Diameter on Surface Silanol Structure, Hydration Forces, and Aggregation Behavior of Alkoxide-Derived Silica Particles[J]. Journal of the American Ceramic Society, 2000, 83(2): 287-293.
[22] 王晗. 肉桂精油-羧甲基纤维素复合膜的制备、表征及其在羊肉保鲜的应用[D]. 保定: 河北农业大学, 2020.
WANG H.Preparation, Characterization of Cinnamon Oil-Carboxymethyl Cellulose Composite Film and Its Application in Fresh Meat Preservation[D]. Baoding: Hebei Agricultural University, 2020.
[23] 孙婷婷, 李志明, 宋雪健, 等. 玉米醇溶蛋白/淀粉基包装膜的性能表征及其对生菜保鲜效果研究[J]. 食品科技, 2024, 49(1): 33-40.
SUN T T, LI Z M, SONG X J, et al.Characterization of Zein/Starch-Based Packaging Films and Their Effect on Lettuce Preservation[J]. Food Science and Technology, 2024, 49(1): 33-40.
[24] 江爱莲, 李建民, 张鸣明, 等. 一种复合可食膜的制备及在烤羊肉中的应用[J]. 包装与食品机械, 2023, 41(5): 57-63.
JIANG A L, LI J M, ZHANG M M, et al.Preparation of a Composite Edible Film and Its Application in Roasted Mutton[J]. Packaging and Food Machinery, 2023, 41(5): 57-63.
[25] BEHERA B, SAGIRI S S, SINGH V K, et al.Mechanical Properties and Delivery of Drug/Probiotics from Starch and Non-Starch Based Novel Bigels: A Comparative Study[J]. Starch - Stärke, 2014, 66(9/10): 865-879.
[26] 何韵晴. 羧甲基纤维素钠复合膜的制备及其在食品保鲜中的应用[D]. 昆明: 昆明理工大学, 2020.
HE Y Q.Preparation of Sodium Carboxymethyl Cellulose Composite Membrane and Its Application in Food Preservation[D]. Kunming: Kunming University of Science and Technology, 2020.
[27] RAHMAN I A, VEJAYAKUMARAN P, SIPAUT C S, et al.Size-Dependent Physicochemical and Optical Properties of Silica Nanoparticles[J]. Materials Chemistry and Physics, 2009, 114(1): 328-332.
[28] 黄超凡, 陈虎剑, 郑科旺, 等. 可食性淀粉复合膜的制备及性能[J]. 食品科技, 2019, 44(6): 92-96.
HUANG C F, CHEN H J, ZHENG K W, et al.Preparation and Property of Edible Starch Composite Films[J]. Food Science and Technology, 2019, 44(6): 92-96.
[29] 郑稳, 庄文静, 宫萱, 等. 普鲁兰多糖/壳聚糖/黄原胶/胶原蛋白复合膜的制备及保鲜效果研究[J]. 食品与发酵工业, 2023, 49(22): 156-164.
ZHENG W, ZHUANG W J, GONG X, et al.Preparation and Preservation Effect of Pullulan Polysaccharide/Chitosan/Xanthan Gum/Collagen Composite Coating[J]. Food and Fermentation Industries, 2023, 49(22): 156-164.
[30] 谷芳, 马嘉欣, 车春波, 等. 低成本羧甲基纤维素保鲜膜的制备及性能[J]. 食品研究与开发, 2023, 44(12): 122-128.
GU F, MA J X, CHE C B, et al.Preparation and Properties of Low-Cost Carboxymethyl Cellulose Preservative Film[J]. Food Research and Development, 2023, 44(12): 122-128.
[31] XING Y G, YANG H, GUO X L, et al.Effect of Chitosan/Nano-TiO2 Composite Coatings on the Postharvest Quality and Physicochemical Characteristics of Mango Fruits[J]. Scientia Horticulturae, 2020, 263: 109135.
[32] 张荣飞, 王相友, 程萌. 超声波制备纳米SiO2-马铃薯淀粉复合膜性能优化及结构表征[J]. 食品科学, 2019, 40(18): 302-311.
ZHANG R F, WANG X Y, CHENG M.Optimization of Ultrasonic-Assisted Preparation and Structural Characterization of Potato Starch Nanocomposite Films[J]. Food Science, 2019, 40(18): 302-311.
[33] SUDERMAN N, ISA M I N, SARBON N M. The Effect of Plasticizers on the Functional Properties of Biodegradable Gelatin-Based Film: A Review[J]. Food Bioscience, 2018, 24: 111-119.
[34] BALLESTEROS-MÁRTINEZ L, PÉREZ-CERVERA C, ANDRADE-PIZARRO R. Effect of Glycerol and Sorbitol Concentrations on Mechanical, Optical, and Barrier Properties of Sweet Potato Starch Film[J]. NFS Journal, 2020, 20: 1-9.
[35] 江东阳, 李楠楠, 黄海源, 等. 淀粉/羧甲基纤维素/甘油可降解复合膜的制备及性能研究[J]. 林产化学与工业, 2024, 44(2): 94-102.
JIANG D Y, LI N N, HUANG H Y, et al.Preparation and Properties of Starch/Carboxymethyl Cellulose/Glycerol Degradable Composite Films[J]. Chemistry and Industry of Forest Products, 2024, 44(2): 94-102.
[36] 张昊, 刘叶, 张毅, 等. L-精氨酸改性淀粉的制备及其抗菌薄膜的性能[J]. 精细化工, 2018, 35(2): 303-311.
ZHANG H, LIU Y, ZHANG Y, et al.Preparation of L-Arginine Modified Starch and Properties of Its Antibacterial Films[J]. Fine Chemicals, 2018, 35(2): 303-311.
[37] MARTINS C, VILARINHO F, SANCHES SILVA A, et al.Active Polylactic Acid Film Incorporated with Green Tea Extract: Development, Characterization and Effectiveness[J]. Industrial Crops and Products, 2018, 123: 100-110.
[38] 张金凤, 王艳文, 范恒军, 等. 茶多酚-玉米胚芽粕蛋白膜制备及性能研究[J]. 粮食与饲料工业, 2023(3): 46-51.
ZHANG J F, WANG Y W, FAN H J, et al.Preparation and Property Study of Tea Polyphenols and Corn Germ Meal Protein-Membrane[J]. Cereal & Feed Industry, 2023(3): 46-51.
[39] CANTATORE A, RANDALL S D, TRAUM D, et al.Effect of Black Tea Extract on Herpes Simplex Virus-1 Infection of Cultured Cells[J]. BMC Complementary and Alternative Medicine, 2013, 13(1): 139.
[40] WILHELM H M, SIERAKOWSKI M R, SOUZA G P, et al.Starch Films Reinforced with Mineral Clay[J]. Carbohydrate Polymers, 2003, 52(2): 101-110.
[41] YAN Z M, ZHONG Y Z, DUAN Y H, et al.Antioxidant Mechanism of Tea Polyphenols and Its Impact on Health Benefits[J]. Animal Nutrition, 2020, 6(2): 115-123.

基金

河南省重点研发专项(231111312800); 河南省重点研发与推广专项(科技攻关)项目(242102110090); 河南省高等学校重点科研项目计划(24B550017,24B180016,25B550014); 信阳农林学院科技创新团队(XNKJTD-001)

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