基于改性淀粉与壳聚糖/木质素磺酸钠复合涂层的加热卷烟纸研究

李媛; 魏刚; 庄虎; 尹俊平; 邱诗波; 黄远景; 卞喜娇; 雷珊珊; 王磊

doi:10.19554/j.cnki.1001-3563.2025.13.033

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包装工程（技术栏目） ›› 2025, Vol. 46 ›› Issue (13) : 296-303. DOI: 10.19554/j.cnki.1001-3563.2025.13.033

绿色包装与循环经济

基于改性淀粉与壳聚糖/木质素磺酸钠复合涂层的加热卷烟纸研究

李媛¹, 魏刚¹, 庄虎², 尹俊平¹, 邱诗波¹, 黄远景², 卞喜娇³, 雷珊珊³, 王磊^3,*

作者信息 +

Heated Cigarette Paper Based on Modified Starch and Chitosan/Sodium Lignosulfonate Composite Coatings

LI Yuan¹, WEI Gang¹, ZHUANG Hu², YIN Junping¹, QIU Shibo¹, HUANG Yuanjing², BIAN Xijiao³, LEI Shanshan³, WANG Lei^3,*

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文章历史 +

摘要

目的解决加热卷烟复合铝箔纸生物难以降解兼顾加热卷烟纸防水防油性能问题。方法通过烷基烯酮二聚体改性淀粉（AKD-Starch）、3-缩水甘油醚氧基丙基三甲氧基硅烷改性淀粉（GPTMS-Starch）、乙烯基三乙氧基硅烷改性淀粉（VTES-Starch）与壳聚糖/木质素磺酸钠复合涂层制备防水防油加热卷烟纸。结果 VTES-Starch的综合性能最优。当淀粉与改性剂质量比为1∶1.2、喷涂量为1.6 g/m²时加热卷烟纸水接触角达133°,甘油吸收率低至2.17%,防油等级达10级。当涂布厚度为90 μm时,Cobb 60值降至30 g/m²,水蒸气透过率为148 g/(m²·d),同时加热卷烟纸保持了良好的力学性能,15 d降解率为29.02%。结论本研究成功开发了基于VTES-Starch与壳聚糖/木质素磺酸钠复合涂层的高性能加热卷烟纸,为加热卷烟纸的开发提供了理论依据和技术支持。

Abstract

The work aims to address the issues of poor biodegradability of composite aluminum foil paper for heated cigarette paper while maintaining its waterproof and oil-proof properties. A waterproof and oil-proof heated cigarette paper was developed by preparing composite coatings of alkyl ketene dimer-modified starch (AKD-Starch), 3-glycidyloxypropyltrimethoxysilane-modified starch (GPTMS-Starch), vinyltriethoxysilane-modified starch (VTES-Starch), and chitosan/sodium lignosulfonate. VTES-Starch exhibited the best overall performance. When the ratio of starch-to-modifier was 1∶1.2 (w:w) and the spraying amount was 1.6 g/m², the water contact angle of the heated cigarette paper reached 133°, the glycerol absorption rate was as low as 2.17%, and the oil-proof rating reached grade 10. Additionally, when the coating thickness was 90 μm, the Cobb 60 value decreased to 30 g/m², the water vapor transmission rate was only 148 g/(m²·d), and the paper maintained good mechanical properties while demonstrating excellent biodegradability (degradation rate of 29.02% in 15 d). In this study, the high-performance heated cigarette paper has been developed successfully based on VTES-Starch and chitosan/sodium lignosulfonate coatings, which provides a theoretical basis and technical support for the development of heated cigarette paper.

导出引用

李媛, 魏刚, 庄虎, 尹俊平, 邱诗波, 黄远景, 卞喜娇, 雷珊珊, 王磊. 基于改性淀粉与壳聚糖/木质素磺酸钠复合涂层的加热卷烟纸研究[J]. 包装工程（技术栏目）. 2025, 46(13): 296-303 https://doi.org/10.19554/j.cnki.1001-3563.2025.13.033

LI Yuan, WEI Gang, ZHUANG Hu, YIN Junping, QIU Shibo, HUANG Yuanjing, BIAN Xijiao, LEI Shanshan, WANG Lei. Heated Cigarette Paper Based on Modified Starch and Chitosan/Sodium Lignosulfonate Composite Coatings[J]. Packaging Engineering. 2025, 46(13): 296-303 https://doi.org/10.19554/j.cnki.1001-3563.2025.13.033

中图分类号： TB33

参考文献

[1] 杨建礼, 吴成春, 宋祖国. 加热不燃烧卷烟加热技术探究[J]. 轻工科技, 2023, 39(5): 23-26.
YANG J L, WU C C, SONG Z G.Research on Heating Technology of Heating Non-Combustible Cigarettes[J]. Light Industry Science and Technology, 2023, 39(5): 23-26.
[2] 马科, 裴安然, 刘文召, 等. 烟碱负载MOF@BC复合材料的制备及在加热卷烟薄片中的应用[J]. 中国造纸, 2024, 43(12): 68-76.
MA K, PEI A R, LIU W Z, et al.Nicotine Loading MOF@BC Preparation of Composite Materials and Their Application in Heating Cigarette Flakes[J]. China Pulp & Paper, 2024, 43(12): 68-76.
[3] 张亮, 刘显军, 王颖, 等. 两种抽吸模式下加热不燃烧卷烟和传统卷烟酚类释放量研究[J]. 湖南文理学院学报(自然科学版), 2024, 36(4): 36-39.
ZHANG L, LIU X J, WANG Y, et al.A Study on Phenols Release from HNBS and Traditional Cigarettes under ISO and HCI Smoking Methods[J]. Journal of Hunan University of Arts and Science (Science and Technology), 2024, 36(4): 36-39.
[4] 苏鑫, 庞永强, 李翔宇, 等. 加热卷烟芯基材料热性能及气溶胶释放特性分析研究进展[J]. 中国造纸, 2024, 43(2): 82-90.
SU X, PANG Y Q, LI X Y, et al.Research Progress on Thermogravimetry and Pyrolysis Behavior and Aerosol Release Characteristics of Heated-Not-Burn Cigarette Tobacco Material[J]. China Pulp & Paper, 2024, 43(2): 82-90.
[5] 高峄涵, 李祥林, 冯智渊, 等. 3种电加热卷烟专用再造烟叶的甘油饱和吸附特性[J]. 烟草科技, 2022, 55(5): 41-49.
GAO Y H, LI X L, FENG Z Y, et al.Saturated Glycerol Adsorption Characteristics of Three Reconstituted Tobacco Samples for Electrically Heated Tobacco Products[J]. Tobacco Science & Technology, 2022, 55(5): 41-49.
[6] 邬宪娜, 张兆琳. 加热不燃烧卷烟用纸趋势分析[J]. 黑龙江造纸, 2021, 49(2): 6-8.
WU X N, ZHANG Z L.Trend Analysis of Paper Used in Heat-Not-Burn Tobacco Products[J]. Heilongjiang Pulp & Paper, 2021, 49(2): 6-8.
[7] 郭俊成, 吴达, 程晓蕾, 等. 保润剂对烟草吸湿特性的影响研究[J]. 中国烟草学报, 2013, 19(4): 22-27.
GUO J C, WU D, CHENG X L, et al.The Influence of Humectants on Tobacco Hygroscopic Characteristics[J]. Acta Tabacaria Sinica, 2013, 19(4): 22-27.
[8] 苏林林, 何邦贵, 王诗琪, 等. 生物质胶黏剂在烟包内衬纸纸铝复合的可行性研究[J]. 包装工程, 2020, 41(15): 149-154.
SU L L, HE B G, WANG S Q, et al.Feasibility Study on Biomass Adhesive in the Paper-Aluminum Compounding of Cigarette Packet Lining Paper[J]. Packaging Engineering, 2020, 41(15): 149-154.
[9] 陈洋, 陈然. 真空喷铝纸转移涂层性能研究[J]. 包装工程, 2022, 43(13): 94-99.
CHEN Y, CHEN R.Transfer Coating Properties of Vacuum Transfer Metalized Paper[J]. Packaging Engineering, 2022, 43(13): 94-99.
[10] 崔聿亮, 孙金芬, 穆广伟, 等. 防渗透烟用接装纸印制工艺研究[J]. 广东印刷, 2023(6): 31-34.
CUI Y L, SUN J F, MU G W, et al.Study on Printing Technology of Tipping Paper for Permeation-Proof Cigarettes[J]. Guangdong Print, 2023(6): 31-34.
[11] 赵文杰. 环保型材料在卷烟包装印刷中应用的研究[J]. 工业设计, 2017(4): 104-105.
ZHAO W J.Application of Environmental Protection Material in Cigarette Packaging Printing[J]. Industrial Design, 2017(4): 104-105.
[12] 黄靖煊. 烷基烯酮二聚体改性生物质防水剂的制备及其在纸浆模塑中的应用[D]. 福州: 福州大学, 2022.
HUANG J X.Preparation of Alkyl Ketene Dimer Modified Biomass Waterproofing Agent and Its Application In Pulp Molding[D]. Fuzhou: Fuzhou University, 2022.
[13] 陈昆, 黄福利, 吴承澄, 等. 高发射率发热针对加热卷烟温度及气溶胶释放的影响[J]. 轻工学报, 2024, 39(6): 108-115.
CHEN K, HUANG F L, WU C C, et al.The Impact of High-Emissivity Heating Pins on Temperature and Aerosol Emission in Heated Tobacco Products[J]. Journal of Light Industry, 2024, 39(6): 108-115.
[14] WANG Q S, DUAN Y J, HUANG Y, et al.Multifunctional Soybean Protein Isolate-Graft-Carboxymethyl Cellulose Composite as All-Biodegradable and Mechanically Robust Mulch Film for "Green" Agriculture[J]. Carbohydrate Polymers, 2024, 323: 121410.
[15] CLASEN S H, MÜLLER C M O, PARIZE A L, et al. Synthesis and Characterization of Cassava Starch with Maleic Acid Derivatives by Etherification Reaction[J]. Carbohydrate Polymers, 2018, 180: 348-353.
[16] XU T, ZHONG Y H, CHEN Q, et al.Modulating the Digestibility of Cassava Starch by Esterification with Phenolic Acids[J]. Food Hydrocolloids, 2022, 127: 107432.
[17] LONG Z M, WANG W J, ZHOU Y, et al.Effect of Polybutylene Adipate Terephthalate on the Properties of Starch/Polybutylene Adipate Terephthalate Shape Memory Composites[J]. International Journal of Biological Macromolecules, 2023, 240: 124452.
[18] CHEN Q, YU H J, WANG L, et al.Recent Progress in Chemical Modification of Starch and Its Applications[J]. RSC Advances, 2015, 5(83): 67459-67474.
[19] LIU X W, CHEN C, CAO Y H, et al.Effect and Enhancement Mechanism of Sodium Lignosulfonate on the Chitosan-Based Composite Film[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2023, 678: 132505.
[20] 龚淑果, 黄平, 谢圣林, 等. 细支低温加热卷烟雾化剂的选择与应用[J]. 中国烟草学报, 2024, 30(3): 19-25.
GONG S G, HUANG P, XIE S L, et al.Selection and Application of Atomizing Agents for Slim Low Temperature Heated Cigarettes[J]. Acta Tabacaria Sinica, 2024, 30(3): 19-25.
[21] ISSA A A, LUYT A S.Kinetics of Alkoxysilanes and Organoalkoxysilanes Polymerization: A Review[J]. Polymers, 2019, 11(3): 537.
[22] RAWAT R, SAINI C S.A Novel Biopolymeric Composite Edible Film Based on Sunnhemp Protein Isolate and Potato Starch Incorporated with Clove Oil: Fabrication, Characterization, and Amino Acid Composition[J]. International Journal of Biological Macromolecules, 2024, 268: 131940.
[23] CHEN K X, LI L.Ordered Structures with Functional Units as a Paradigm of Material Design[J]. Advanced Materials, 2019, 31(32): 1901115.
[24] OYMACI P, ALTINKAYA S A.Improvement of Barrier and Mechanical Properties of Whey Protein Isolate Based Food Packaging Films by Incorporation of Zein Nanoparticles as a Novel Bionanocomposite[J]. Food Hydrocolloids, 2016, 54: 1-9.
[25] SHAH Y A, BHATIA S, AL-HARRASI A, et al.Mechanical Properties of Protein-Based Food Packaging Materials[J]. Polymers, 2023, 15(7): 1724.