锂离子电池运输包装：热失控监测与早期预警技术研究进展

陈鑫; 刘松; 施文; 李金鼎; 袁帅; 袁伟; 苗飞; 程东浩

doi:10.19554/j.cnki.1001-3563.2025.13.006

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包装工程（技术栏目） ›› 2025, Vol. 46 ›› Issue (13) : 48-58. DOI: 10.19554/j.cnki.1001-3563.2025.13.006

锂电池运输防护技术及包装容器

锂离子电池运输包装：热失控监测与早期预警技术研究进展

陈鑫¹, 刘松¹, 施文², 李金鼎², 袁帅², 袁伟¹, 苗飞¹, 程东浩^2,*

作者信息 +

Research Progress on Thermal Runaway Monitoring and Early Warning Technologies for Lithium-ion Battery Transport Packaging

CHEN Xin¹, LIU Song¹, SHI Wen², LI Jinding², YUAN Shuai², YUAN Wei¹, MIAO Fei¹, CHENG Donghao^2,*

Author information +

文章历史 +

摘要

目的为应对锂离子电池在运输过程中日益突出的热失控安全风险,系统梳理当前锂电池热失控监测与预警领域的主要技术路径,并分析其在运输包装场景下的适应性问题。方法本文围绕电学、热学、力学、气体、声学与光学6类预警方法,从其工作原理、技术优劣及适应性方面进行对比分析,并结合危化品运输、冷链物流以及AI赋能的预警技术路径,提出将多源感知与边缘处理集成于运输包装系统的技术框架设想。结论当前监测手段在响应滞后、传感器布设受限及环境适应性等方面存在挑战。未来应加强多模态传感融合、轻量化数据处理与分级响应机制的研究,以推动构建高可靠性、高适配性的锂电池运输安全保障系统。

Abstract

To address the increasing safety risks of thermal runaway in lithium-ion batteries during transportation, the work aims to systematically review the major technological approaches in thermal runaway monitoring and early warning, and analyze their adaptability in transport packaging scenarios. By focusing on six types of early warning methods of electrical, thermal, mechanical, gas, acoustic, and optical fields, their working principles, technical advantages and disadvantages, and adaptability were compared. Additionally, combined with technological paths from dangerous goods transportation, cold chain logistics, and AI-enabled early warning systems, a conceptual framework integrating multi-source sensing and edge processing into the transportation packaging system was proposed. Existing monitoring methods face challenges such as delayed response, sensor deployment limitations, and poor environmental adaptability. Future work should focus on multimodal sensing fusion, lightweight data processing, and hierarchical response mechanisms to support the development of highly reliable and adaptable safety systems for lithium-ion transport.

导出引用

陈鑫, 刘松, 施文, 李金鼎, 袁帅, 袁伟, 苗飞, 程东浩. 锂离子电池运输包装：热失控监测与早期预警技术研究进展[J]. 包装工程（技术栏目）. 2025, 46(13): 48-58 https://doi.org/10.19554/j.cnki.1001-3563.2025.13.006

CHEN Xin, LIU Song, SHI Wen, LI Jinding, YUAN Shuai, YUAN Wei, MIAO Fei, CHENG Donghao. Research Progress on Thermal Runaway Monitoring and Early Warning Technologies for Lithium-ion Battery Transport Packaging[J]. Packaging Engineering. 2025, 46(13): 48-58 https://doi.org/10.19554/j.cnki.1001-3563.2025.13.006

中图分类号： TB485.3

参考文献

[1] Energy Institute. Statistical Review of World Energy2024[EB/OL]. London: Energy Institute. https://www.energyinst.org/statistical-review/home.
[2] 徐振恒, 周晓燕, 付佳龙, 等. 锂离子电池热失控及其预警方法[J]. 科学通报, 2023, 68(33): 4501-4516.
XU Z H, ZHOU X Y, FU J L, et al.Monitoring and Diagnostic Approaches for Thermal Runaway in Lithium-Ion Batteries[J]. Chinese Science Bulletin, 2023, 68(33): 4501-4516.
[3] 宋婉静, 张晓昱. 锂离子电池产业的成本与前景分析[J]. 电池, 2025, 55(1): 141-145.
SONG W J, ZHANG X Y.Cost and Prospect Analysis of the Li-Ion Battery Industry[J]. Battery Bimonthly, 2025, 55(1): 141-145.
[4] GUO Q Z, LIU S Y, ZHANG J B, et al.Effects of Charging Rates on Heat and Gas Generation in Lithium-Ion Battery Thermal Runaway Triggered by High Temperature Coupled with Overcharge[J]. Journal of Power Sources, 2024, 600: 234237.
[5] BAIRD A R, ARCHIBALD E J, MARR K C, et al.Explosion Hazards from Lithium-Ion Battery Vent Gas[J]. Journal of Power Sources, 2020, 446: 227257.
[6] 刘杨, 张惠忠. 锂电池合规危险品包装的技术要求[J]. 中国包装, 2023, 43(2): 13-17.
LIU Y, ZHANG H Z.Technical Requirements of Lithium Battery Packaging for Compliance with Dangerous Goods[J]. China Packaging, 2023, 43(2): 13-17.
[7] CHOMBO P V, LAOONUAL Y.A Review of Safety Strategies of a Li-Ion Battery[J]. Journal of Power Sources, 2020, 478: 228649.
[8] LI H G, ZHOU D, ZHANG M H, et al.Multi-Field Interpretation of Internal Short Circuit and Thermal Runaway Behavior for Lithium-Ion Batteries under Mechanical Abuse[J]. Energy, 2023, 263: 126027.
[9] LIU Z, GUO X R, MENG N, et al.Study of Thermal Runaway and the Combustion Behavior of Lithium-Ion Batteries Overcharged with High Current Rates[J]. Thermochimica Acta, 2022, 715: 179276.
[10] OUYANG D X, WENG J W, CHEN M Y, et al.Experimental Analysis on the Degradation Behavior of Overdischarged Lithium-Ion Battery Combined with the Effect of High-Temperature Environment[J]. International Journal of Energy Research, 2020, 44(1): 229-241.
[11] CHEN Z Y, ZHANG B, XIONG R, et al.Electro-Thermal Coupling Model of Lithium-Ion Batteries under External Short Circuit[J]. Applied Energy, 2021, 293: 116910.
[12] LI H G, LIU B H, ZHOU D, et al.Coupled Mechanical-Electrochemical-Thermal Study on the Short-Circuit Mechanism of Lithium-Ion Batteries under Mechanical Abuse[J]. Journal of the Electrochemical Society, 2020, 167(12): 120501.
[13] LAI X, YAO J, JIN C Y, et al.A Review of Lithium-Ion Battery Failure Hazards: Test Standards, Accident Analysis, and Safety Suggestions[J]. Batteries, 2022, 8(11): 248.
[14] 张子敬, 原蓓蓓, 李红, 等.锂离子电池热失控气体检测分析及预警研究[J/OL]. 储能科学与技术: 1-14[2025-05-11].https://link.cnki.net/doi/10.19799/j.cnki.2095-4239.2025.0016.
ZHANG Z J, YUAN B B, LI H, et al.Research on Thermal Runaway Gas Detection and Early Warning of Lithium-Ion Batteries[J/OL]. Energy Storage Science and Technology: 1-14 [2025-06-11].https://link.cnki.net/doi/10.19799/j.cnki.2095-4239.2025.0016.
[15] WANG Q S, MAO B B, STOLIAROV S I, et al.A Review of Lithium Ion Battery Failure Mechanisms and Fire Prevention Strategies[J]. Progress in Energy and Combustion Science, 2019, 73: 95-131.
[16] FINEGAN D P, SCHEEL M, ROBINSON J B, et al.In-Operando High-Speed Tomography of Lithium-Ion Batteries during Thermal Runaway[J]. Nature Communications, 2015, 6: 6924.
[17] LYU N W, JIN Y, XIONG R, et al.Real-Time Overcharge Warning and Early Thermal Runaway Prediction of Li-Ion Battery by Online Impedance Measurement[J]. IEEE Transactions on Industrial Electronics, 2022, 69(2): 1929-1936.
[18] LI Y X, JIANG L H, ZHANG N J, et al.Early Warning Method for Thermal Runaway of Lithium-Ion Batteries under Thermal Abuse Condition Based on Online Electrochemical Impedance Monitoring[J]. Journal of Energy Chemistry, 2024, 92: 74-86.
[19] LI L Y, REN Y X, O’REGAN K, et al. Lithium-Ion Battery Cathode and Anode Potential Observer Based on Reduced-Order Electrochemical Single Particle Model[J]. Journal of Energy Storage, 2021, 44: 103324.
[20] ZHANG W F, LYU N W, JIN Y.Internal Short Circuit Warning Method of Parallel Lithium-Ion Module Based on Loop Current Detection[J]. Journal of Energy Storage, 2023, 72: 108796.
[21] MAO B B, HUANG P F, CHEN H D, et al.Self-Heating Reaction and Thermal Runaway Criticality of the Lithium Ion Battery[J]. International Journal of Heat and Mass Transfer, 2020, 149: 119178.
[22] 刘同宇, 李师, 付卫东, 等. 大容量磷酸铁锂动力电池热失控预警策略研究[J]. 中国安全科学学报, 2021, 31(11): 120-126.
LIU T Y, LI S, FU W D, et al.Study on Early Warning Strategy of Large LFP Traction Battery’s Thermal Runaway[J]. China Safety Science Journal, 2021, 31(11): 120-126.
[23] 李钊, 陈才星, 牛慧昌, 等. 锂离子电池热失控早期预警特征参数分析[J]. 消防科学与技术, 2020, 39(2): 146-149.
LI Z, CHEN C X, NIU H C, et al.Characteristic Parameter Analysis of Thermal Runaway Early Warning of Lithium-Ion Battery[J]. Fire Science and Technology, 2020, 39(2): 146-149.
[24] CHEN S Q, WEI X Z, ZHANG G X, et al.Mechanical Strain Signal Based Early Warning for Failure of Different Prismatic Lithium-Ion Batteries[J]. Journal of Power Sources, 2023, 580: 233397.
[25] LI J L, GU X, GENG H, et al.Thermal Runaway Early Warning for Lithium-Ion Batteries Upon Strain Perspective[J]. IEEE Transactions on Industrial Electronics, 2025(99): 1-10.
[26] TAN K, WANG S, JIANG J F, et al.Operando Monitoring Gas Pressure for Accurate Early Warning of Thermal Runaway in Lithium-Ion Batteries Induced by Overheating Based on an Optical Fiber Fabry-Perot Interferometer[J]. Journal of Power Sources, 2024, 615: 235096.
[27] 庄春吉, 黄辉, 胡敏杰, 等. 热失控数据采集实验系统设计与实验研究[J]. 实验室科学, 2022, 25(2): 14-18.
ZHUANG C J, HUANG H, HU M J, et al.Design and Experimental Study on Thermal Runaway Data Acquisition Experiment System[J]. Laboratory Science, 2022, 25(2): 14-18.
[28] LIAO Z H, ZHANG J G, GAN Z Y, et al.Thermal Runaway Warning of Lithium-Ion Batteries Based on Photoacoustic Spectroscopy Gas Sensing Technology[J]. International Journal of Energy Research, 2022, 46(15): 21694-21702.
[29] JIN Y, ZHENG Z K, WEI D H, et al.Detection of Micro-Scale Li Dendrite via H₂ Gas Capture for Early Safety Warning[J]. Joule, 2020, 4(8): 1714-1729.
[30] APPLEBERRY M C, KOWALSKI J A, AFRICK S A, et al.Avoiding Thermal Runaway in Lithium-Ion Batteries Using Ultrasound Detection of Early Failure Mechanisms[J]. Journal of Power Sources, 2022, 535: 231423.
[31] LIU H K, WANG Y, WANG T, et al.A Dual-Stage Thermal Runaway Early Warning Strategy for Lithium-Ion Batteries Based on Multi-Domain Acoustic Signal Fusion[J]. Energy, 2025, 322: 135748.
[32] 唐文杰, 姜欣, 刘昊琰, 等. 基于气液逸出物图像识别的锂离子电池火灾早期预警[J]. 高电压技术, 2022, 48(8): 3295-3304.
TANG W J, JIANG X, LIU H Y, et al.Early Warning of Lithium-Ion Battery Fire Based on Image Recognition of Gas-Liquid Escape[J]. High Voltage Engineering, 2022, 48(8): 3295-3304.
[33] 张青松, 杨铠宾, 赵洋. 纳米纤维材料对锂电池热失控传播影响研究[J]. 消防科学与技术, 2023, 42(10): 1322-1327.
ZHANG Q S, YANG K B, ZHAO Y.Effect of Nanofiber Material on Thermal Runaway Propagation of Lithium Battery[J]. Fire Science and Technology, 2023, 42(10): 1322-1327.
[34] 伊笑莹, 李泽锟, 刘全义, 等. 气凝胶毡对锂离子电池热失控传播的阻隔有效性分析[J]. 山东科技大学学报(自然科学版), 2021, 40(6): 43-51.
YI X Y, LI Z K, LIU Q Y, et al.Effectiveness of Aerogel Blanket in Blocking Thermal Runaway Propagation of Lithium Ion Batteries[J]. Journal of Shandong University of Science and Technology (Natural Science), 2021, 40(6): 43-51.
[35] 张青松, 郭超超, 姜乃文, 等. 包装性能对空运锂电池热失控影响的定量研究[J]. 安全与环境学报, 2018, 18(2): 518-522.
ZHANG Q S, GUO C C, JIANG N W, et al.Quantitative Trace Study of the Effects of the Packaging Quality on the Thermorunaway of the Air-Transported Lithium-Ion Batteries[J]. Journal of Safety and Environment, 2018, 18(2): 518-522.
[36] 梁沁宜, 郑涛, 拜雪玲, 等. 安全监测系统在液化天然气运输装备上的应用[J]. 铁道车辆, 2023, 61(6): 155-158.
LIANG Q Y, ZHENG T, BAI X L, et al.Application of the Safety Monitoring System in the LNG Transport Equipment[J]. Rolling Stock, 2023, 61(6): 155-158.
[37] 葛浩, 潘芳, 毛益佳, 等. 一种危险品运输车辆货物安全监测装置: 中国, CN207809197U[P].2018-09-04.
GE H, PAN F, MAO Y J, et al. Dangerous Goods Transport Vehicle Goods Safety Monitoring Device: China, CN207809197U[P].2018-09-04.
[38] 庄学强, 尹自斌, 高亚丽, 等. 液态危险品船舶的远程监视报警系统设计[J]. 集美大学学报(自然科学版), 2021, 26(1): 50-55.
ZHUANG X Q, YIN Z B, GAO Y L, et al.Research and Development of Remote Monitoring and Alarm System for Liquid Dangerous Goods Ship[J]. Journal of Jimei University (Natural Science), 2021, 26(1): 50-55.
[39] 孙远强, 段雅静, 杨冉. 一种用于冷链物流智能监测的时间和温度双功能指示器: 中国, CN116046204A[P].2023-05-02.
SUN Y Q, DUAN Y J, YANG R. Time and Temperature Dual-Function Indicator for Intelligent Monitoring of Cold-Chain Logistics: China, CN116046204A[P].2023-05-02.
[40] 蔡梦琪, 李琳, 俞朱敏, 等. 时间-温度指示器在冷链运输中的应用进展[J]. 包装工程, 2022, 43(19): 1-10.
CAI M Q, LI L, YU Z M, et al.Application of Time-Temperature Indicator in Cold Chain Transportation[J]. Packaging Engineering, 2022, 43(19): 1-10.
[41] SCHÖTTLE M, TRAN T, FELLER T, et al. Time-Temperature Integrating Optical Sensors Based on Gradient Colloidal Crystals[J]. Advanced Materials, 2021, 33(40): 2101948.
[42] 王天辉, 刘颜星, 张超, 等. 一种带监测功能的运输保温箱: 中国, CN221368670U[P].2024-07-19.
WANG T H, LIU Y X, ZHANG C, et al. Transportation Heat Preservation Box with Monitoring Function: China, CN221368670U[P].2024-07-19.
[43] DURLIK I, MILLER T, KOSTECKA E, et al.Artificial Intelligence in Maritime Transportation: A Comprehensive Review of Safety and Risk Management Applications[J]. Applied Sciences, 2024, 14(18): 8420.
[44] DASH A, BANDOPADHAY S, SAMAL S R, et al.AI-Enabled IoT Framework for Leakage Detection and Its Consequence Prediction during External Transportation of LPG[J]. Sensors, 2023, 23(14): 6473.