上转换发光材料的包装防伪研究进展

张锴洋; 王红蕾; 仲芸芸; 张雪琴; 程峥; 陈国健; 肖乃玉; 肖更生

doi:10.19554/j.cnki.1001-3563.2025.11.007

PDF(7964 KB)

包装工程（技术栏目） ›› 2025, Vol. 46 ›› Issue (11) : 55-69. DOI: 10.19554/j.cnki.1001-3563.2025.11.007

先进材料

上转换发光材料的包装防伪研究进展

张锴洋, 王红蕾, 仲芸芸, 张雪琴, 程峥, 陈国健, 肖乃玉, 肖更生

作者信息 +

Advances in Up-conversion Luminescent Materials for Anti-counterfeiting Packaging

ZHANG Kaiyang, WANG Honglei, ZHONG Yunyun, ZHANG Xueqin, CHENG Zheng, CHEN Guojian, XIAO Naiyu, XIAO Gengsheng

Author information +

文章历史 +

摘要

目的为应对假冒伪劣产品对社会经济和消费者权益造成的严重威胁,开发新型包装防伪技术,总结近年来上转换发光防伪材料研究进展,从而为后续包装防伪技术的开发及应用提供参考。方法首先简述上转换发光防伪技术的背景及防伪原理,并对上转换发光材料的主要制备、表征方式进行介绍,随后详细分类论述稀土类、碳点类、有机类等上转换发光材料的最新研究进展,并一一分析其特点,并进一步讨论上转换发光材料在单模、双模及多模防伪上的应用。结论上转换材料具有多模发光与抗仿制的独特优势,但仍面临成本与环保挑战,未来应在碳点上转换与多模集成上持续突破,以拓展其包装防伪应用基础。

Abstract

In order to cope with the serious threat of fake and shoddy products to the social economy and the consumer rights and interests and develop a novel packaging anti-counterfeiting technology, the work aims to summarize the recent progress of up-conversion luminescent anti-counterfeiting materials and provide reference for the subsequent development and application of packaging anti-counterfeiting technology. The background and mechanisms of up-conversion luminescent anti-counterfeiting technology were briefly introduced, and the main preparation and characterization methods of up-conversion luminescent materials were introduced. Then, the latest research progress of up-conversion luminescent materials such as rare earth, carbon dots and organic materials were classified in detail, and their characteristics were analyzed one by one. The application of up-conversion luminescent materials in single-mode, dual-mode and multi-mode anti-counterfeiting was further discussed. Up-conversion materials have the unique advantages of multi-mode luminescence and anti-counterfeiting, but they still face the challenges of cost and environmental protection. In the future, it is necessary to make continuous breakthroughs in carbon point up-conversion and multi-mode integration to expand its packaging anti-counterfeiting application base.

导出引用

张锴洋, 王红蕾, 仲芸芸, 张雪琴, 程峥, 陈国健, 肖乃玉, 肖更生. 上转换发光材料的包装防伪研究进展[J]. 包装工程（技术栏目）. 2025, 46(11): 55-69 https://doi.org/10.19554/j.cnki.1001-3563.2025.11.007

ZHANG Kaiyang, WANG Honglei, ZHONG Yunyun, ZHANG Xueqin, CHENG Zheng, CHEN Guojian, XIAO Naiyu, XIAO Gengsheng. Advances in Up-conversion Luminescent Materials for Anti-counterfeiting Packaging[J]. Packaging Engineering. 2025, 46(11): 55-69 https://doi.org/10.19554/j.cnki.1001-3563.2025.11.007

中图分类号： TB484

参考文献

[1] LI J F, XIA D D, GAO M, et al.Invisible Luminescent Inks and Luminescent Films Based on Lanthanides for Anti-Counterfeiting[J]. Inorganica Chimica Acta, 2021, 526: 120541.
[2] DING S, LV X, XIA Y, et al.Fluorescent Materials Based on Spiropyran for Advanced Anti-Counterfeiting and Information Encryption[J]. Molecules, 2024, 29(11): 2536.
[3] WANG Q X, ZHANG X D, ZHOU D, et al.Cholesteric Liquid Crystal Doped with Spiropyran and Zinc Ions for Multi-State Anti-Counterfeiting[J]. Journal of Materials Chemistry C, 2024, 12(20): 7225-7232.
[4] GU H Y, XU X.Multicolor Hybrid Metal Halides and Anti-Counterfeiting[J]. Chinese Journal of Structural Chemistry, 2024, 43(9): 100352.
[5] LI H T, HE X D, KANG Z H, et al.Water-Soluble Fluorescent Carbon Quantum Dots and Photocatalyst Design[J]. Angewandte Chemie International Edition, 2010, 49(26): 4430-4434.
[6] YUAN J P, ZHOU Y M, CHEN G X, et al.Materials vs Digits: A Review of Embedded Anti-Counterfeiting Fingerprints in Three-Dimensional Printing[J]. Materials Science and Engineering: R: Reports, 2024, 160: 100836.
[7] CHENG H D, QU J Y, MAO W Q, et al.Continuous-Wave Pumped Monolayer WS₂ Lasing for Photonic Barcoding[J]. Nanomaterials, 2024, 14(7): 614.
[8] LI T Y, LI L Q, JIANG L, et al.Reconfigurable Hologram Response to Liquid via the Femtosecond Laser Direct Writing of 3D Micropillars[J]. Advanced Optical Materials, 2024, 12(29): 2400612.
[9] ZHAO J H, ZHANG M, GUO Y X, et al.Colorful Cholesteric Liquid Crystal Polymer Network Patterns Prepared Using Cholesteric Liquid Crystal Inks[J]. Giant, 2024, 17: 100244.
[10] CHEN H T, JIN Y, FANG F, et al.Up-Conversion Phosphor Na₂MoO₄: Er³+/Yb³+ for the Optical Temperature Sensing and Anti-Counterfeiting[J]. Journal of Luminescence, 2024, 265: 120244.
[11] STOKES G G. On the Change of Refrangibility of Light[J]. Philosophical Transactions of the Royal Society of London Series I, 1852, 142: 463-562.
[12] BLOEMBERGEN N.Solid State Infrared Quantum Counters[J]. Physical Review Letters, 1959, 2(3): 84-85.
[13] AUZEL F.History of Upconversion Discovery and Its Evolution[J]. Journal of Luminescence, 2020, 223: 116900.
[14] AUZEL F E.Materials and Devices Using Double-Pumped-Phosphors with Energy Transfer[J]. Proceedings of the IEEE, 1973, 61(6): 758-786.
[15] STEPHENS R R, MCFARLANE R A.Diode-Pumped Upconversion Laser with 100-mW Output Power[J]. Optics Letters, 1993, 18(1): 34-36.
[16] DOWNING E A, HESSELINK L, MACFARLANE R M, et al.A Laser-Diode-Driven, Three-Color, Solid-State 3-D Display[C]//Summaries of Papers Presented at the Conference on Lasers and Electro-Optics. Anaheim, CA, USA. IEEE, 1996: 89-90.
[17] 江中. Yb³+/Ln³+掺杂La₂MgTiO₆双钙钛矿荧光粉的制备和性能研究[D]. 赣州: 江西理工大学, 2022: 5-9.
JIANG Z.Study on the Preparation and Properties of Yb³+/Ln³+ Doped La₂MgTiO₆ Double Perovskite Phosphors[D]. Ganzhou: Jiangxi University of Science and Technology, 2022: 5-9.
[18] 孙晶. Er³+/Yb³+掺杂钛酸盐荧光粉的制备和发光性能的研究[D]. 赣州: 江西理工大学, 2023: 5-13.
SUN J.Study on the Preparation and Luminescence Properties of Er³+/Yb³+ Doped Ttitanate Phosphors[D]. Ganzhou: Jiangxi University of Science and Technology, 2023: 5-13.
[19] 林敏, 赵英, 董宇卿, 等. 稀土上转换发光纳米材料的制备及生物医学应用研究进展[J]. 中国材料进展, 2012, 31(1): 36-43.
LIN M, ZHAO Y, DONG Y Q, et al.Progress in Synthesis and Biomedical Applications of Rare Earth Upconversion Luminescent Nano Materials[J]. Materials China, 2012, 31(1): 36-43.
[20] 胡鹤. 稀土上转换发光纳米材料的制备及其在生物医学成像中的应用[D]. 上海: 复旦大学, 2009: 3-20.
HU H.Preparation of Rare Earth Up-Conversion Luminescent Nanomaterials and Its Application in Biomedical Imaging[D]. Shanghai: Fudan University, 2009: 3-20.
[21] HAASE M, SCHÄFER H. Upconverting Nanoparticles[J]. Angewandte Chemie International Edition, 2011, 50(26): 5808-5829.
[22] 杨利文. 高效蓝绿光上转换发光材料的荧光特性与机理研究[D]. 湘潭: 湘潭大学, 2003: 8-21.
YANG L W.The Study of Luminescence Properties and Mechanisms of Up-Conversion Materials with Highly Blue and Green Up-Conversion Efficiency[D]. Xiangtan: Xiangtan University, 2003: 8-21.
[23] ZHENG K Z, LOH K Y, WANG Y, et al.Recent Advances in Upconversion Nanocrystals: Expanding the Kaleidoscopic Toolbox for Emerging Applications[J]. Nano Today, 2019, 29: 100797.
[24] 张伟, 左芳. 上转换发光材料在不同防伪领域的研究进展[J]. 精细化工, 2021, 38(12): 2450-2457.
ZHANG W, ZUO F.Research Progress of Upconversion Luminescent Materials in Different Anti-Counterfeiting Fields[J]. Fine Chemicals, 2021, 38(12): 2450-2457.
[25] ZHOU B, SHI B Y, JIN D Y, et al.Controlling Upconversion Nanocrystals for Emerging Applications[J]. Nature Nanotechnology, 2015, 10(11): 924-936.
[26] 罗娟, 陈世碧, 姚植彩, 等. 稀土离子掺杂荧光材料在防伪技术领域的研究进展[J]. 武汉工程大学学报, 2023, 45(5): 482-489.
LUO J, CHEN S B, YAO Z C, et al.Progress in Rare Earth Ion-Doped Fluorescent Materials in Anti-Counterfeiting Technology[J]. Journal of Wuhan Institute of Technology, 2023, 45(5): 482-489.
[27] 姚伟睛. NaYF₄上转换发光材料的合成、发光机理及印刷防伪应用研究[D]. 武汉: 武汉大学, 2020: 15-51.
YAO W J.Preparation, Photoluminescence Mechanisms of NaYF₄ Upconversion Fluorescence Materials for Printing Anti-Counterfeiting Application[D]. Wuhan: Wuhan University, 2020: 15-51.
[28] KRAEMER K W, BINER D, FREI G, et al.Hexagonal Sodium Yttrium Fluoride Based Green and Blue Emitting Upconversion Phosphors[J]. ChemInform, 2004, 35(26): 1244-1251.
[29] MEI L F, GUAN M, ZHANG K N, et al.Synthesis and Luminescence Property Research of LaInO₃: Er³+/Yb³+ Upconversion Materials[J]. Science of Advanced Materials, 2014, 6(12): 2702-2706.
[30] SU Q Q, HAN S Y, XIE X J, et al.The Effect of Surface Coating on Energy Migration-Mediated Upconversion[J]. Journal of the American Chemical Society, 2012, 134(51): 20849-20857.
[31] BI P Q, ZHANG T, GUO Y Y, et al.Donor-Acceptor Bulk-Heterojunction Sensitizer for Efficient Solid-State Infrared-to-Visible Photon Up-Conversion[J]. Nature Communications, 2024, 15: 5719.
[32] LIU S Y, GAO D, WANG L, et al.Experimental Optimization, Design Synthesis, and Up-Conversion Luminescence Properties of Y₄GeO₈: Er³+/Yb³+ Red Phosphors[J]. Journal of Contemporary Physics (Armenian Academy of Sciences), 2024, 59(1): 58-78.
[33] LIN H, XU D K, TENG D D, et al.Shape-Controllable Synthesis and Enhanced Upconversion Luminescence of Li+ Doped Β-NaLuF4: Yb³+, Ln³+ (Ln = Tm, Ho) Microcrystals[J]. New Journal of Chemistry, 2015, 39(4): 2565-2572.
[34] WANG Q, LIU Y, XU Y S, et al.High-Efficiency Solution-Processed Hyperfluorescent Organic Light-Emitting Diodes Enabled by Novel Triazatruxene-Based Exciplexes with High Up-Conversion Efficiency[J]. Advanced Optical Materials, 2024, 12(10): 2302245.
[35] SRIVASTAVA M, SAHU S K, SINGH A R, et al.Codoping of Yttria (Y₂O₃): Ho-Yb Nanoparticles with Li Increase Emitted Green Light Intensity for Security Ink and Bioimaging[J]. ACS Applied Nano Materials, 2023, 6(22): 20887-20898.
[36] LLANOS J, ESPINOZA D, BRITO I, et al.Polymorphism and Up-Conversion Photoluminescence Properties of Y₂WO₆ Doped with Yb³+/Er³+ under Excitation at 975 nm[J]. Journal of Luminescence, 2023, 263: 120088.
[37] 任仲翾. 稀土掺杂上转换发光材料的制备及防伪技术应用[D]. 西安: 西安邮电大学, 2023.
REN Z X.Synthesis of Rare Earth Doped Upconversion Luminescent Materials and Application of Anticounterfeiting Technology[D]. Xi'an: Xi'an University of Posts and Telecommunications, 2023.
[38] ZHU H T, GUO H R, ZHENG Q J, et al.Synthesis and Up-Conversion Luminescence of Ho³+ and Yb³+ Co-Doped La₇P₃O₁₈ Phosphors[J]. Transactions of Nonferrous Metals Society of China, 2023, 33(4): 1205-1213.
[39] SILVA D L, PUGINA R S, ALMEIDA CAIUT J M. Green, Red, and Near-Infrared Up-Conversion Emission of NaY(MoO4)₂: Er³+ Submicrometric Particles Obtained by One-Step Synthesis, and Its Thermometric Application[J]. Journal of Luminescence, 2022, 243: 118639.
[40] 韩路坤, 张树彪, 贾玉玲, 等. 高温热解法制备NaYF₄: Yb³+, Er³+上转换纳米晶及其发光性质研究[J]. 化学世界, 2018, 59(10): 668-674.
HAN L K, ZHANG S B, JIA Y L, et al.High-Temperature Decomposition Synthesis of NaYF₄: Yb³+, Er³+ Up-Conversion Nano-Materials and Luminescent Properties[J]. Chemical World, 2018, 59(10): 668-674.
[41] KURUCZ M, NIKOLINAKOS I, SOUEITI J, et al.Transparent Near-IR Dye-Sensitized Solar Cells: Ultrafast Spectroscopy Reveals the Effects of Driving Force and Dye Aggregation[J]. ChemPhotoChem, 2024, 8(3): 202300175.
[42] VETRONE F, NACCACHE R, MAHALINGAM V, et al.The Active-Core/Active-Shell Approach: A Strategy to Enhance the Upconversion Luminescence in Lanthanide-Doped Nanoparticles[J]. Advanced Functional Materials, 2009, 19(18): 2924-2929.
[43] 康春杨. 上转换发光材料的制备、性能及应用研究[D]. 兰州: 兰州交通大学, 2022.
KANG C Y.Study on Preparation, Properties and Application of Upconversion Luminescent Materials[D]. Lanzhou: Lanzhou Jiatong University, 2022.
[44] BYEON J Y, JUNG K Y.Dual Luminescence Optimization of Ho³+/Yb³+/Eu³+-Doped Gd₂O₃ Phosphor Prepared by Spray Pyrolysis for Anti-Counterfeiting Application[J]. Ceramics International, 2022, 48(23): 34837-34847.
[45] LI Q B, ZHANG Y Y, WU Z J, et al.Enhancement of Green Upconversion Luminescence of Yb³+/Tb³+ Co-Doped BiOBr Nanosheets and Its Potential Applications in Photocatalysis[J]. Journal of Solid State Chemistry, 2022, 308: 122897.
[46] MENG M Z, ZHANG R, FA X M, et al.Preparation of Core-Shell Structured NaYF₄: Yb³+/Tm³+@NaYF₄: Yb³+/Er³+ Nanoparticles with High Sensitivity, Low Resolution and Good Reliability and Application of Their Fluorescence Temperature Properties[J]. CrystEngComm, 2022, 24(9): 1752-1763.
[47] 刘碧蕊, 伏振兴, 申学鹏. 六方相LaF₃纳米晶体的水热合成法制备及结构表征[J]. 宁夏师范学院学报, 2019, 40(10): 40-44.
LIU B R, FU Z X, SHEN X P.Structure Characterization and Hydrothermal Synthesis of Rhombohedral LaF₃ Nanocrystals[J]. Journal of Ningxia Normal University, 2019, 40(10): 40-44.
[48] JUNG J Y, PARK J Y, YI S S, et al.Barium Molybdate Up-Conversion Nanoscale Particles with IR-LED Chip, Temperature Sensing, and Anti-Counterfeiting Applications[J]. Nanoscale, 2024, 16(21): 10292-10305.
[49] 王科秀. Er³+/Yb³+掺杂上转换发光性质的调控和测温研究[D]. 长春: 中国科学院大学(中国科学院长春光学精密机械与物理研究所), 2021.
WANG K X.Upconversion Luminescence Regulation and Temperature Measurement of Er³+/Yb³+ Doped Materials[D]. Changchun: Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, 2021.
[50] 杨霖. Ho³+/Yb³+掺杂NaYF₄纳米晶上转换发光热增强机理和性质的研究[D]. 长春: 中国科学院大学(中国科学院长春光学精密机械与物理研究所), 2022.
YANG L.Upconversion Luminescence Thermal Enhancement Mechanism and Property of Ho³+/Yb³+ Doped NaYF₄ Nanocrystals[D]. Changchun: Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, 2022.
[51] 韩欣欣. Mn²+掺杂氟化物ABF₃(A=K, Rb;B=Ca, Zn, Cd)的长寿命上转换发光[D]. 广州: 华南理工大学, 2020.
HAN X X.Long-Lived Upconversion Luminescence of Mn²+-Doped Fluoride ABF₃(A=K, Rb;B=Ca, Zn, Cd)[D]. Guangzhou: South China University of Technology, 2020.
[52] 黄蕊. 980nm激发下稀土离子敏化的Mn⁴+的上转换发光[D]. 湘潭: 湘潭大学, 2020.
HUANG R.Up-conversion Luminescence of Mn⁴+ Sensitized by Rare Earth Ions under 980 nm Excitation[D]. Xiangtan: Xiangtan University, 2020.
[53] GRUZINTSEV A N.Optical Modulation of Anti-Stokes Luminescence in CaF₂: Er Crystals[J]. Inorganic Materials, 2020, 56(7): 759-764.
[54] 文东平. 上转换荧光激发偏振的调控及其多重防伪显示应用[D]. 南宁: 广西大学, 2023: 57-62.
WEN D P.Regulated Excitation Polarized of Upconversion Luminescence and Multiple Anti-Counterfeit Display Applications[D]. Nanning: Guangxi University, 2023: 57-62.
[55] 高忆欣. 基于NaErF₄核壳材料的可控制备及上转换发光性能研究[D]. 吉林: 吉林化工学院, 2022.
GAO Y X.Controllable Preparation and Upconversion Luminescence Properties of NaErF₄ Core-Shell Materials[D]. Jilin: Jilin Institute of Chemical Technology, 2022.
[56] MA Y H, WEI Y C, JIANG F L, et al.Photon Upconversion of All-Inorganic CsPbX₃ Quantum Dots Based on Fluorescence Resonance Energy Transfer in Hetero-Structured Perovskite/Upconversion Nanocomposites[J]. Journal of Luminescence, 2022, 242: 118565.
[57] XIAO T Z, LI Y J, WANG T H, et al.Enhanced Upconversion Luminescence of BiOCl: Yb³+, Er³+ Nanosheets via Carbon Dot Modification and Their Optical Temperature Sensing[J]. Materials Chemistry Frontiers, 2021, 5(11): 4280-4290.
[58] XIE Y, SUN G T, MANDL G A, et al.Upconversion Luminescence through Cooperative and Energy-Transfer Mechanisms in Yb³+-Metal-Organic Frameworks[J]. Angewandte Chemie International Edition, 2023, 62(4): e202216269.
[59] ALMEIDA R M, ALVES E, SANTOS L F.Up-Conversion Materials for Solid-State Lighting[J]. Journal of Sol-Gel Science and Technology, 2025, 113(1): 56-62.
[60] 刘鑫纹, 梅炳初, 谭国龙. Er: Sr₅(PO₄)₃F透明陶瓷的制备和上转换光学性能[J]. 硅酸盐学报, 2024, 52(3): 874-881.
LIU X W, MEI B C, TAN G L.Preparation and Up-Conversion Luminescent Properties of Er: Sr₅(PO₄)₃F Transparent Ceramics[J]. Journal of the Chinese Ceramic Society, 2024, 52(3): 874-881.
[61] 程田田. 荧光碳量子点的制备表征及其生物应用的研究[D]. 东营: 中国石油大学(华东), 2016: 3-10.
CHENG T T.Preparation of Fluorescent Carbon Quantum Dots for Biological Application[D]. Dongying: China University of Petroleum (Huadong), 2016: 3-10.
[62] LI H T, KANG Z H, LIU Y, et al.Carbon Nanodots: Synthesis, Properties and Applications[J]. Journal of Materials Chemistry, 2012, 22(46): 24230-24253.
[63] ARCUDI F, ĐORĐEVIĆ L, PRATO M. Synthesis, Separation, and Characterization of Small and Highly Fluorescent Nitrogen-Doped Carbon NanoDots[J]. Angewandte Chemie International Edition, 2016, 55(6): 2107-2112.
[64] JIA X F, LI J, WANG E K.One-Pot Green Synthesis of Optically PH-Sensitive Carbon Dots with Upconversion Luminescence[J]. Nanoscale, 2012, 4(18): 5572-5575.
[65] 李欣彤, 吴晶, 张德蒙, 等. 新型水溶性多色荧光碳点的制备及细胞成像研究[J]. 分析测试学报, 2014, 33(4): 380-386.
LI X T, WU J, ZHANG D M, et al.Preparation of Novel Water Soluble Multicolor Carbon Dots for Cell Imaging[J]. Journal of Instrumental Analysis, 2014, 33(4): 380-386.
[66] 高薇, 吕功煊. 碳量子点上转换材料的制备及其应用研究进展[J]. 分子催化, 2020, 34(2): 150-164.
GAO W, LYU G X.The Preparation of Carbon Quantum Dots Up-Conversion Materials and Its Application[J]. Journal of Molecular Catalysis (China), 2020, 34(2): 150-164.
[67] YANG S T, WANG X, WANG H F, et al.Carbon Dots as Nontoxic and High-Performance Fluorescence Imaging Agents[J]. The Journal of Physical Chemistry C, Nanomaterials and Interfaces, 2009, 113(42): 18110-18114.
[68] ZHENG X, WEN Y, ZHONG J, et al.Upconversion Luminescence via Anion Exchange in Perovskite Quantum Dots for Anticounterfeiting Inkjet Printing[J]. ACS Omega, 2022, 7(44): 40596-40602.
[69] WANG Q X, WEE A T S. Upconversion Photovoltaic Effect of WS₂/2D Perovskite Heterostructures by Two-Photon Absorption[J]. ACS Nano, 2021, 15(6): 10437-10443.
[70] 邵山, 徐帆, 曹丙强. 利用短支链表面配体修饰提升Cs₂AgInCl₆量子点稳定性和荧光性能[J]. 中国粉体技术, 2024, 30(3): 139-149.
SHAO S, XU F, CAO B Q.Utilizing Short-Chain Surfactants for Enhancing the Stability and Fluorescence Performance of Cs₂AgInCl₆ Quantum Dots[J]. China Powder Science and Technology, 2024, 30(3): 139-149.
[71] 范春英, 伍晚花, 杨成. 聚集体中的三重态-三重态湮灭上转换[J]. 有机化学, 2018, 38(6): 1377-1393.
FAN C Y, WU W H, YANG C.Triplet-Triplet Annihilation Upconversion in Molecular Aggregation Systems[J]. Chinese Journal of Organic Chemistry, 2018, 38(6): 1377-1393.
[72] 曹哲勇. 双光子吸收碳量子点薄膜的制备及其光限幅性能的调控[D]. 太原: 太原理工大学, 2022: 11-33.
CAO Z Y.Preparation and Optical Limiting Performance Regulation of Two-Photon Absorption Carbon Quantum Dot Films[D]. Taiyuan: Taiyuan University of Technology, 2022: 11-33.
[73] 杨娟. 基于金属有机框架材料的电化学发光共振能量转移生物传感器的构建与应用[D]. 桂林: 广西师范大学, 2023.
YANG J.Construction of Electrochemiluminescence Resonance Energy Transfer Biosensors Based on Metal-Organic Framework Materials and Their Applications[D]. Guilin: Guangxi Normal University, 2023.
[74] SAIDI L, SAMET A, DAMMAK T, et al.Down and up Conversion Luminescence of the Lead-Free Organic Metal Halide Material: (C₉H₈NO)₂SnCl₆·2H₂O[J]. Physical Chemistry Chemical Physics, 2021, 23(29): 15574-15581.
[75] KOHATA S, NAKANOTANI H, CHITOSE Y, et al.Anti-Stokes Luminescence in Multi-Resonance-Type Thermally-Activated Delayed Fluorescence Molecules[J]. Angewandte Chemie, 2023, 135(44): e202312326.
[76] GANGWAR A K, BHARTI D K.Highly Luminescent Upconversion Material for Anti-Counterfeiting Application[J]. Bulletin of Materials Science, 2023, 46(4): 224.
[77] 白广耀. 基于稀土离子发光的防伪标签制作及应用研究[D]. 长春: 吉林建筑大学, 2023.
BAI G Y.Study on the Fabrication and Application of Anti-Counterfeit Label Based on Rare Earth Ion Luminescence[D]. Changchun: Jilin Jianzhu University, 2023.
[78] 朱也莉. 上转换发光纳米ZrO₂的制备及在红外防伪油墨中的应用[D]. 北京: 北京化工大学, 2006: 35-50.
ZHU Y L.Studies on Preparation of Nano-ZrO₂ with Upconversion Luminescence and Its Application in Infrared Stealth Falsification Resistant Ink[D]. Beijing: Beijing University of Chemical Technology, 2006: 35-50.
[79] 杨玲, 朱锋利, 谭海湖, 等. 高性能水性上转换荧光油墨的制备及包装防伪应用[J]. 包装学报, 2021, 13(5): 16-26.
YANG L, ZHU F L, TAN H H, et al.Preparation of High-Performance Waterborne Up-Conversion Fluorescent Inks for Packaging Anti-Counterfeiting Application[J]. Packaging Journal, 2021, 13(5): 16-26.
[80] YOU M L, LIN M, WANG S R, et al.Three-Dimensional Quick Response Code Based on Inkjet Printing of Upconversion Fluorescent Nanoparticles for Drug Anti-Counterfeiting[J]. Nanoscale, 2016, 8(19): 10096-10104.
[81] CAO T M D, LE T TG, TURRELL S, et al. Luminescent Ink Based on Upconversion of NaYF4: Er, Yb@MA Nanoparticles: Environmental Friendly Synthesis and Structural and Spectroscopic Assessment[J]. Molecules, 2021, 26(4): 1041.
[82] 邵国伟. 瑞士新版钞票设计解读[J]. 中国钱币, 2019(3): 68-76.
SHAO G W.Interpretation of the New Swiss Banknote Design[J]. China Numismatics, 2019(3): 68-76.
[83] 佚名. Sun Chemical推出新型红外防伪油墨用于钞票纸印刷[J]. 中华纸业, 2018, 39(18): 72.
ANON. Sun Chemical Introduced a New Infrared Anti-Counterfeiting Ink for Banknote Paper Printing[J]. China Pulp & Paper Industry, 2018, 39(18): 72.
[84] 陈健. 钞票印刷光变图文检测方法及装置[J]. 电子世界, 2021(11): 137-139.
CHEN J.Method and Device for Detect Optically Variable Graphics and Text in Banknote Printing[J]. Electronics World, 2021(11): 137-139.
[85] 姚瑞刚. 票据防伪油墨和防伪纸张[J]. 印刷杂志, 2005(12): 7-10.
YAO R G.Bill Anti-Counterfeiting Ink and Anti-Counterfeiting Paper[J]. Printing Field, 2005(12): 7-10.
[86] 姚瑞刚. 票据防伪油墨和防伪纸张的发展方向[J]. 印刷工业, 2006, 1(3): 75-77.
YAO R G.Development Direction of Bill Anti-Counterfeiting Ink and Anti-Counterfeiting Paper[J]. Print China, 2006, 1(3): 75-77.
[87] 黄晓东, 田志广. 再谈票据防伪印刷[J]. 印刷技术, 2009(13): 18-20.
HUANG X D, TIAN Z G.Re-Discussion on Anti-Counterfeiting Printing of Bills[J]. Printing Technology, 2009(13): 18-20.
[88] 张凡. 稀土上转换光学编码技术开发及其在国家公共证件防伪产业化应用[Z]. 上海市: 复旦大学, 2011: 1-2.
ZHANG F.Development of Rare Earth Up-conversion Optical Encoding Technology and Its Industrial Application in National ID Document Anti-Counterfeiting[Z]. Shanghai: Fudan University, 2011: 1-2.