纸浆模塑用无氟防油剂的研究进展

韦长河, 龙攀峰

包装工程(技术栏目) ›› 2025, Vol. 46 ›› Issue (11) : 1-10.

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PDF(4861 KB)
包装工程(技术栏目) ›› 2025, Vol. 46 ›› Issue (11) : 1-10. DOI: 10.19554/j.cnki.1001-3563.2025.11.001
先进材料

纸浆模塑用无氟防油剂的研究进展

  • 韦长河, 龙攀峰
作者信息 +

Research Progress on Non-fluorine Oil Repellent for Pulp Molding

  • WEI Changhe, LONG Panfeng
Author information +
文章历史 +

摘要

目的 应对传统含氟防油剂在纸浆模塑中的生物积累性等弊端,推动绿色无氟防油剂的开发以满足可持续包装材料需求。方法 通过文献调研,总结纸浆模塑行业多糖类、蛋白质类、纳米二氧化硅、有机硅类等无氟防油剂的发展趋势及应用现状。结论 无氟防油剂可提升纸浆模塑产品的防油性能,并避免含氟防油剂的安全风险,在食品包装材料中展现出良好的应用潜力,但仍存在耐高温性差、防油耐久性差等问题。未来需聚焦于新型无氟防油剂结构设计、工艺优化、协同效应以突破其局限性,从而提高其性能和市场竞争力。

Abstract

The work aims to deal with the disadvantages of traditional fluorinated oil repellents in pulp molding, such as bioaccumulation, and promote the development of green non-fluorine oil repellents to meet the demand of sustainable packaging materials. Through literature research, the development trend and application status of non-fluorine oil repellents such as polysaccharide, protein, nano silica dioxide and organic silicon in pulp molding industry were summarized. The non-fluorine oil repellent can improve the oil repellent performance of pulp molding products, and avoid the safety risk of fluorine-containing oil repellent. It shows good application potential in food packaging materials, but there are still some problems such as poor high temperature resistance and poor oil resistance. In the future, it is necessary to focus on the design of new non-fluorine oil repellent structure, process optimization and synergistic effect to break through its limitations, so as to improve its performance and market competitiveness.

关键词

纸浆模塑 / 食品包装 / 无氟防油剂

Key words

pulp molding / food packing / non-fluorine oil repellent

引用本文

导出引用
韦长河, 龙攀峰. 纸浆模塑用无氟防油剂的研究进展[J]. 包装工程(技术栏目). 2025, 46(11): 1-10 https://doi.org/10.19554/j.cnki.1001-3563.2025.11.001
WEI Changhe, LONG Panfeng. Research Progress on Non-fluorine Oil Repellent for Pulp Molding[J]. Packaging Engineering. 2025, 46(11): 1-10 https://doi.org/10.19554/j.cnki.1001-3563.2025.11.001
中图分类号: TB484.1   

参考文献

[1] FARHAT W, VENDITTI R A, HUBBE M, et al.A Review of Water-Resistant Hemicellulose-Based Materials: Processing and Applications[J]. ChemSusChem, 2017, 10(2): 305-323.
[2] WANG C L, YAO A K, ZHANG Z, et al.Synthesis and Application of Fluorine-Free Waterborne Polyurethane-Acrylate Water-Repellent Finishing Agent[J]. Fibers and Polymers, 2023, 24(5): 1585-1593.
[3] 黄品歌, 张艳, 孟毅, 等. 生物质基天然纤维包装材料的研究现状及发展趋势[J]. 包装学报, 2022, 14(5): 66-74.
HUANG P G, ZHANG Y, MENG Y, et al.Biomass-Derived Nature Fibers for Packaging Materials: The State-of-the-Art and Future[J]. Packaging Journal, 2022, 14(5): 66-74.
[4] 王飞杰, 王利强, 张新昌. 防油纸在食品包装中的研究进展[J]. 包装工程, 2020, 41(21): 138-144.
WANG F J, WANG L Q, ZHANG X C.Research Progress of Oil-Proof Packaging Paper Based on Plant Fiber[J]. Packaging Engineering, 2020, 41(21): 138-144.
[5] 宋金星, 乐翔, 陈八斤, 等. 氟系防水防油剂整理效果及影响因素分析[J]. 印染助剂, 2020, 37(1): 54-57.
SONG J X, LE X, CHEN B J, et al.Finishing Effect and Influencing Factors of Fluorine-Based Waterproof and Oil-Repellency Agent[J]. Textile Auxiliaries, 2020, 37(1): 54-57.
[6] ZAHID M, MAZZON G, ATHANASSIOU A, et al.Environmentally Benign Non-Wettable Textile Treatments: A Review of Recent State-of-the-Art[J]. Advances in Colloid and Interface Science, 2019, 270: 216-250.
[7] 刘遥. 基于长链烷烃的无氟拒水剂试制及其性能评价[D]. 武汉: 武汉纺织大学, 2018.
LIU Y.The Trial-Manufacture And Performance Evaluation of Fluorine-Free Water Repellent based on Long Chain Alkanes[D]. Wuhan: Wuhan Textile University, 2018.
[8] GLENN G, SHOGREN R, JIN X, et al.Per- and Polyfluoroalkyl Substances and Their Alternatives in Paper Food Packaging[J]. Comprehensive Reviews in Food Science and Food Safety, 2021, 20(3): 2596-2625.
[9] ZHANG Y L, LIN X, CHEN X X, et al.Strategies to Regulate the Degradation and Clearance of Mesoporous Silica Nanoparticles: A Review[J]. International Journal of Nanomedicine, 2024, 19: 5859-5878.
[10] LI H, HE Y Q, YANG J, et al.Fabrication of Food-Safe Superhydrophobic Cellulose Paper with Improved Moisture and Air Barrier Properties[J]. Carbohydrate Polymers, 2019, 211: 22-30.
[11] QIU X Z, LI J W, WANG J C, et al.A Robust Superhydrophobic and Oleophobic Coating with Short Chain Perfluoroalkyl Group and Flower-Shaped SiO2 Nanoparticles[J]. Surface and Coatings Technology, 2022, 447: 128810.
[12] LO T N H, PARK I. Unprecedented Superoleophobicity Achieved with Fluorinated Wrinkle Mesoporous Silica[J]. Surfaces and Interfaces, 2024, 46: 104090.
[13] MLALILA N, HILONGA A, SWAI H, et al.Antimicrobial Packaging Based on Starch, Poly(3-hydroxybutyrate) and Poly(Lactic-Co-Glycolide) Materials and Application Challenges[J]. Trends in Food Science & Technology, 2018, 74: 1-11.
[14] KANSAL D, HAMDANI S S, PING R Q, et al.Starch and Zein Biopolymers as a Sustainable Replacement for PFAS, Silicone Oil, and Plastic-Coated Paper[J]. Industrial & Engineering Chemistry Research, 2020, 59(26): 12075-12084.
[15] NI S Z, ZHANG H, DAI H Q, et al.Starch-Based Flexible Coating for Food Packaging Paper with Exceptional Hydrophobicity and Antimicrobial Activity[J]. Polymers, 2018, 10(11): 1260.
[16] ZHONG L, DING Y J, ZHANG B, et al.Effect of Octenylsuccinylation of Oxidized Cassava Starch on Grease Resistance and Waterproofing of Food Wrapping Paper[J]. Starch - Stärke, 2019, 71(7/8): 1800284.
[17] CHENG L, HAO Y L, SONG X S, et al.Effects of Chitosan and Nano Titanium Dioxide on the Mechanical, Physicochemical and Antibacterial Properties of Corn Starch Films[J]. Journal of Macromolecular Science, Part B, 2021, 60(8): 616-630.
[18] DENG X X, UNIVERSITY N F, YAN X X, et al.Effect of Sodium Periodate Oxidation of Cassava Starch on Grease Resistance and Waterproofing of Food Wrapping Paper[J]. ACS Sustainable Chemistry & Engineering, 2025, 13(18): 6801-6812.
[19] 徐冰冰, 杨国超, 张求慧. 纸质食品包装材料防水防油改性的研究进展[J]. 包装工程, 2021, 42(3): 107-115.
XU B B, YANG G C, ZHANG Q H.Research Progress of Water-Proof and Oil-Proof Modification of Paper Food Packaging Materials[J]. Packaging Engineering, 2021, 42(3): 107-115.
[20] BORDENAVE N, GRELIER S, COMA V.Hydrophobization and Antimicrobial Activity of Chitosan and Paper-Based Packaging Material[J]. Biomacromolecules, 2010, 11(1): 88-96.
[21] KORUMILLI T, TEOTIA A, ABDULLAHI A, et al.Hydrophobic, Oil-Repellent, and Antimicrobial Guar Gum-Chitosan Composite Paper Coating for Sustainable Food Packaging[J]. Journal of Applied Polymer Science, 2024, 141(40): 56020-56026.
[22] ROMAN (IANA-ROMAN) M, NECHITA P, VASILE M A, et al. Barrier and Antimicrobial Properties of Coatings Based on Xylan Derivatives and Chitosan for Food Packaging Papers[J]. Coatings, 2023, 13(10): 1761.
[23] VRABIČ BRODNJAK U, TIHOLE K.Chitosan Solution Containing Zein and Essential Oil as Bio Based Coating on Packaging Paper[J]. Coatings, 2020, 10(5): 497.
[24] YI C F, YUAN T Z, REN H, et al.Fabrication of Food-Safe, Degradable and High-Barrier Air Frying Paper by Chitosan, Zein and LCNF Coatings[J]. Cellulose, 2023, 30(4): 2441-2452.
[25] SHI B Y, XIE S Q, HUANG D Y, et al.Fully Bio-Based Grease Resistant Composite Coating: Chitosan-Genipin- Microfibrillated Cellulose for Sustainable Paper Food Packaging[J]. International Journal of Biological Macromolecules, 2025, 311: 143660.
[26] JING X, LI X, JIANG Y F, et al.Excellent Coating of Collagen Fiber/Chitosan-Based Materials that Is Water- and Oil-Resistant and Fluorine-Free[J]. Carbohydrate Polymers, 2021, 266: 118173.
[27] SHEN Z W, HU S F, ZENG C, et al.A Low Cost, Green Sustainable and Biodegradable Biomass-Based Fluorine-Free Water and Oil Repellent[J]. Chinese Journal of Polymer Science, 2024, 42(4): 480-491.
[28] YI K, FU S Y, YI Z D, et al.Nanocellulose and Polysiloxane Coatings for Strength Enhancement and Oil-Proof and Hydrophobicity Improvement of Recycled Pulp Sheets[J]. BioResources, 2023, 18(2): 2826-2841.
[29] YI K, FU S Y, ZHANG H, et al.Cellulose Nanofibrils/ Polydimethylsiloxane Double-Layer Coating for Fabrication of High Barrier and Excellent Water- and Oil-Resistance Paper[J]. Progress in Organic Coatings, 2022, 172: 107123.
[30] ZHU R F, HE Z B, SUN C, et al.Fabrication of Recyclable High-Barrier Water- and Oil-Proof Paper by Sodium Alginate/Cellulose Nanofiber/Ethyl Cellulose/ Polyvinyl Butyral[J]. Industrial Crops and Products, 2023, 203: 117084.
[31] DU P, DING Q J, ZHAO C S, et al.The Fluorine-Free Coating Has Excellent Hydrophobic and Oleophobic Properties for Porous Cellulose-Based Materials[J]. Cellulose, 2021, 28(10): 6133-6146.
[32] WANG S D, PEI L H, WEI J C, et al.Preparation of Environmentally Friendly Oil- and Water-Resistant Paper Using Holo-Lignocellulosic Nanofibril (LCNF)- Based Composite Coating[J]. Polymers, 2024, 16(8): 1078.
[33] ZHU R F, FU X T, JIN S N, et al.Water and Oil-Resistant Paper Materials Based on Sodium Alginate/Hydroxypropyl Methylcellulose/Polyvinyl Butyral/ Nano-Silica with Biodegradable and High Barrier Properties[J]. International Journal of Biological Macromolecules, 2023, 225: 162-171.
[34] CHEN X Q, ZHU Q M, WEN Y S, et al.Chemical Modification of Alginate via the Oxidation-Reductive Amination Reaction for the Development of Alginate Derivative Electrospun Composite Nanofibers[J]. Journal of Drug Delivery Science and Technology, 2022, 68: 103113.
[35] MA L Y, LIU S, SHI J H, et al.Recyclable Oil Resistant Paper with Enhanced Water Resistance Based on Alkyl Ketene Dimer Modified Sodium Alginate[J]. Nordic Pulp & Paper Research Journal, 2023, 38(4): 533-543.
[36] SHENG J J, LI J R, ZHAO L H.Fabrication of Grease Resistant Paper with Non-Fluorinated Chemicals for Food Packaging[J]. Cellulose, 2019, 26(10): 6291-6302.
[37] LI C J, LI X, WANG L, et al.Preparation of High-Barrier Performance Paper-Based Materials from Biomass-Based Silicone-Modified Acrylic Polymer Emulsion[J]. Polymer Engineering & Science, 2024, 64(7): 3348-3362.
[38] KOPACIC S, WALZL A, ZANKEL A, et al.Alginate and Chitosan as a Functional Barrier for Paper-Based Packaging Materials[J]. Coatings, 2018, 8(7): 235.
[39] 朱瑞丰. 海藻酸钠基防水防油包装纸制备及性能研究[D]. 无锡: 江南大学, 2023.
ZHU R F.Preparation and Performance Study of Sodium Alginate-Based Water-and Oil-Resistant Packaging Paper[D]. Wuxi: Jiangnan University, 2023.
[40] CHEN H X, ZHOU Z Y, ZHENG B D, et al.Development and Characterization of Biodegradable Water- and Oil-Resistant Coatings Based on Derivatized Cellulose, Sodium Alginate, and Shellac for Paper-Based Packaging[J]. International Journal of Biological Macromolecules, 2025, 303: 140490.
[41] LI P Y, ZHOU X Y, JIAN B X, et al.Facile Preparation of Soybean Protein-Based Oil-Resistant Paper for Food Packaging[J]. Industrial Crops and Products, 2024, 222: 119431.
[42] JEONG S, YOO S.Whey Protein Concentrate-Beeswax- Sucrose Suspension-Coated Paperboard with Enhanced Water Vapor and Oil-Barrier Efficiency[J]. Food Packaging and Shelf Life, 2020, 25: 100530.
[43] JING X, LI X, JIANG Y F, et al.Degradable Collagen/Sodium Alginate/Polyvinyl Butyral High Barrier Coating with Water/Oil-Resistant in a Facile and Effective Approach[J]. Carbohydrate Polymers, 2022, 278: 118962.
[44] ZHU W X, ZHAO J, WANG X F, et al.Facile Fabrication of Fluorine-Free Breathable Poly(Methylhydrosiloxane)/ Polyurethane Fibrous Membranes with Enhanced Water-Resistant Capability[J]. Journal of Colloid and Interface Science, 2019, 556: 541-548.
[45] KASAPGIL E, ANAC I, ERBIL H Y. Transparent, Fluorine-Free, Heat-Resistant, Water Repellent Coating by Infusing Slippery Silicone Oil on Polysiloxane Nanofilament Layers Prepared by Gas Phase Reaction of N-Propyltrichlorosilane and Methyltrichlorosilane[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2019, 560: 223-232.
[46] HE B B, HOU X, LIU Y F, et al.Design of Fluorine-Free Waterborne Fabric Coating with Robust Hydrophobicity, Water-Resistant and Breathability[J]. Separation and Purification Technology, 2023, 311: 123308.
[47] LEI W W, SUN Y F, HUANG B, et al.Synthesis and Application of Polyurethane-Modified Silicone as Finishing Agent for Cotton Fabric[J]. Fibers and Polymers, 2018, 19(5): 1024-1031.
[48] SUN Y F, ZHAO J Y, GUO Y X, et al.Synthesis and Application of Silicone Modified Flame Retardant for Polyester Fabric[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2024, 680: 132679.
[49] LI Z, RABNAWAZ M, SARWAR M G, et al.A Closed-Loop and Sustainable Approach for the Fabrication of Plastic-Free Oil- and Water-Resistant Paper Products[J]. Green Chemistry, 2019, 21(20): 5691-5700.
[50] NAIR A, KANSAL D, KHAN A, et al.Oil- and Water-Resistant Paper Substrate Using Blends of Chitosan-Graft-Polydimethylsiloxane and Poly(vinyl alcohol)[J]. Journal of Applied Polymer Science, 2021, 138(21): 50494-50505.
[51] 张海艳, 张红杰, 程芸, 等. 无氟有机硅乳液改善纸浆模塑包装材料防水防油性能研究[J]. 中国造纸学报, 2022, 37(3): 94-101.
ZHANG H Y, ZHANG H J, CHENG Y, et al.Study on Improving Water and Oil Resistance of Molded Pulp Packaging Materials with Organic Fluorine-Free Silicone Emulsion[J]. Transactions of China Pulp and Paper, 2022, 37(3): 94-101.
[52] JI Y Z, XU Q H, JIN L Q, et al.Cellulosic Paper with High Antioxidative and Barrier Properties Obtained through Incorporation of Tannin into Kraft Pulp Fibers[J]. International Journal of Biological Macromolecules, 2020, 162: 678-684.

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广西科技计划项目(AD23026140)

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