目的 有机–无机杂化钙钛矿太阳电池以其优异的光电转换性能和低成本溶液加工等优势受到了科研工作者和产业界人士的广泛关注，文中着眼于解决把实验室的旋涂研发工艺转换为可大规模重复生产的工艺这一直接挑战。方法 印刷制造技术具有低成本、大规模、高产率、适用于柔性基底等优点，是应对该挑战的有效手段。深入梳理和总结印刷制造中钙钛矿薄膜的形核与结晶过程，对于印刷高质量钙钛矿薄膜和实现大面积高效钙钛矿太阳电池制造至关重要。结论 分析了钙钛矿形核结晶的热力学与动力学基本理论，从钙钛矿形核结晶调控这一角度出发，对各类印刷工艺制造大面积钙钛矿薄膜及光伏器件的研究现状做出相应评价，认为“升级制备技术、创新材料体系、改善稳定性能”三步走将掀起钙钛矿产业化的新浪潮。

Organic-inorganic hybrid perovskite solar cells (PSCs) have attracted great attentions from both the researchers and industrial professionals due to the excellent photoelectric conversion performance and low-cost solution processing. The work aims to solve the direct challenge of converting the laboratory spin coating process into a process of large-scale repeated production. Printing manufacturing technology was an effective means to cope with the challenge due to advantages of low cost, large scale, high yield, suitability for flexible substrates, etc. The nucleation and crystallization process of perovskite films was thoroughly sorted out and summarized, which was the prerequisite for printing high-quality perovskite films and fabricating large-area high-performance PSCs. The basic theories of thermodynamics and kinetics of perovskite nucleation and crystallization are analyzed. From the perspective of perovskite nucleation and crystallization regulation, the research status of various printing processes to manufacture large-area perovskite films and photovoltaic devices is evaluated accordingly. It is considered that the three steps of “upgrading preparation technology, innovating material system and improving stability” will set off a new wave of perovskite industrialization.