目的 建立同时测定现代溶剂型油墨中22种溶剂残留量的检测方法，为溶剂型油墨溶剂残留量的监管提供技术支持。方法 通过优化混合标准工作溶液的配制，采用优化的色谱条件，用HP-INNOWAX毛细管柱分离待测化合物、外标法定量的顶空气相色谱方式检测溶剂型油墨的22种溶剂残留量。 结果 22种溶剂均能较好的分离，且呈现良好的线性关系;相关系数均在0.999以上，检出限为0.000 21～0.000 55 mg/m²，回收率为85.92%～102.51%，精密度为0.46%～5.73%。结论 该方法分离度好、灵敏度高、精密度好、准确度高，在实际样品检测中，取得了良好的效果，可为溶剂型油墨溶剂残留量的监管提供技术支持。

The purpose is to establish a detection method for simultaneous determination of 22 residual solvents in modern solvent-based inks, so as to provide technical support for the supervision of solvent residues in solvent-based inks. By optimizing the preparation of mixed standard working solution and adopting the optimized chromatographic conditions, the compounds to be tested were separated by HP-INNOWAX capillary column, and 22 solvent residues of solvent-based ink were detected by headspace-gas chromatography with external standard method. The 22 solvents were well separated and showed good linear relationship. The correlation coefficient was above 0.999, the detection limit was 0.000 21~0.000 55 mg/m2, the recovery rate was 85.92%~102.51%, and the precision was 0.46%~5.73%. The method has good separation, high sensitivity, good precision and high accuracy. It has achieved good results in the detection of actual samples, and can provide technical support for the supervision of solvent residue in solvent based ink.